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Novel Cr-Y-O nanocluster oxide dispersion strengthening reduced activation steel

A low-activation steel, dispersion-strengthening technology, applied in the field of anti-irradiation metal materials, can solve the problem that it is easy to be adsorbed on the surface of powder particles, the oxygen content of the oxide dispersion-strengthened low-activation steel matrix cannot be effectively controlled, and the specific surface area of ​​powder particles cannot be effectively controlled. It can achieve low activation performance, good anti-irradiation swelling ability, and the effect of reducing oxygen content

Active Publication Date: 2016-01-13
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Currently, this direct addition of lazy Y 2 o 3 There is a big weakness in the method of preparing oxide dispersion strengthened low-activation steel by particles, that is, the oxygen content in the oxide dispersion strengthened low-activation steel matrix cannot be effectively controlled
During the preparation of oxide dispersion strengthened low-activation steel, although the original alloy powder and the mixed powder after ball milling are stored in a vacuum glove box to isolate the air to prevent oxidation, the mixed powder is often exposed to the In the air, the specific surface area of ​​powder particles is large, and the gas is easily adsorbed on the surface of powder particles

Method used

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  • Novel Cr-Y-O nanocluster oxide dispersion strengthening reduced activation steel
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  • Novel Cr-Y-O nanocluster oxide dispersion strengthening reduced activation steel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The mass percent of the alloying elements of the oxide dispersion strengthened steel is: 0.041%C, 13.88%Cr, 1.35%W, 0.19%V, 0.07%Ta, 0.41%Mn, 0.10%Si, 0.74%Y, 73(ppm ) N, 64 (ppm) Al, 48 (ppm) Ni, 48 (ppm) Mo, 65 (ppm) Nb, Cu<0.010%, P<0.005%, S<0.005%, and the matrix is ​​Fe.

[0033] Preparation method: First, prepare Cr-Y ball mill powder (the mass ratio of Cr-Y pure metal powder is Cr:Y=9:1, the ball milling medium is Φ6 hard steel balls, the ball milling atmosphere is 99.99% argon, and the mass ratio of ball to material is is 10:1, the ball milling time is 4h, and the rotating speed is 1425r / min), and then the Cr-Y ball mill powder (the scanning electron microscope photo is shown in figure 2 As shown) is added to Fe-C-Cr-W-V-Ta-Mn-Si steel powder for high-energy ball milling (the ball milling medium is Φ6 and Φ10 mixed hard steel balls, the ball milling atmosphere is 99.99% argon, and the mass ratio of balls to materials is 10 : 1, ball milling time 70h, rotating...

Embodiment 2

[0035] The alloy element content of the oxide dispersion strengthened steel is the same as that of the steel of Example 1.

[0036] Preparation method: First, prepare Cr-Y ball mill powder (the mass ratio of Cr-Y pure metal powder is Cr:Y=9:1, the ball milling medium is Φ6 hard steel balls, the ball milling atmosphere is 99.99% argon, and the mass ratio of ball to material is 10:1, ball milling time 4h, rotating speed 1425r / min), then add Cr-Y ball mill powder into Fe-C-Cr-W-V-Ta-Mn-Si steel powder for high-energy ball milling (ball milling medium is Φ6 and Φ10 Mix hard steel balls, the ball milling atmosphere is 99.99% argon, the mass ratio of balls to material is 10:1, the ball milling time is 70h, and the rotating speed is 450r / min). Secondly, the mixed powder is first packed into a bag and evacuated (vacuum degree 10 -1 Pa, temperature 450°C, time 4h), and then cured by hot isostatic pressing (pressure 130MPa, temperature 1050°C, holding time 3h). Finally, after preparin...

Embodiment 3

[0038] The difference from Example 1 is that the heat treatment system is different: normalizing at 1150-1200°C / 50min / air cooling + tempering at 820°C / 90min / air cooling, finally obtaining oxide dispersion strengthened low activation steel.

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Abstract

The invention aims to provide novel Cr-Y-O nanocluster oxide dispersion strengthening reduced activation steel applicable to a fusion reactor. According to the composition proportion of the oxide dispersion strengthening reduced activation steel, Fe serves as a substrate; C is larger than or equal to 0.04% and smaller than or equal to 0.14%; Cr is larger than or equal to 10.0% and smaller than or equal to 14.0%; W is larger than or equal to 1.1% and smaller than or equal to 1.50%; V is larger than or equal to 0.15% and smaller than or equal to 0.35%; Ta is larger than or equal to 0.03% and smaller than or equal to 0.19%; Mn is larger than or equal to 0.2% and smaller than or equal to 0.6%; Si is larger than or equal to 0.05% and smaller than or equal to 0.15%; Y is larger than or equal to 0.20% and smaller than or equal to 0.75%; a small quantity of impurities are unavoidably mixed in the manufacturing process. The contents of impurity elements and easily activating elements which can generate radionuclides after neutron irradiation are strictly controlled, wherein N is smaller than 0.010%; Al is smaller than 0.010%; Ni is smaller than 0.005%; Mo is smaller than 0.005%; Nb is smaller than 0.010%; Cu is smaller than 0.010%; P is smaller than 0.005%; S is smaller than 0.005%. The oxide dispersion strengthening reduced activation steel is uniform in structure, oxide nanocluster is in dispersion distribution, the excellent mechanical properties are achieved, and moreover the low activation property and the good irradiation swelling resistance are also achieved.

Description

technical field [0001] The invention belongs to the field of radiation-resistant metal materials, in particular to an oxide dispersion-strengthened low-activation steel for fusion reactors, which can resist strong neutron radiation and has excellent mechanical properties. Background technique [0002] China currently consumes 47-50 trillion kilowatt-hours of electricity per year. If all electricity is produced by supercritical thermal power units, the annual coal consumption will be 14-18 billion tons, which is very important for my country's coal resources and natural environment. huge challenge. Therefore, from the perspectives of environment and energy, it is imperative to develop nuclear energy. In the process of nuclear fusion power generation, not only can zero pollution discharge be achieved, but also the energy conversion rate is high and the power generation efficiency is high. However, whether the fusion reactor can be successfully built and run smoothly depends o...

Claims

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Application Information

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IPC IPC(8): C22C38/24C22C38/26C22C38/48C21D6/00C21D1/28
Inventor 单以银胡雪黄礼新严伟王威杨柯
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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