A loofah zeolite molecular sieve for adsorption and separation of water turbidity and its preparation method

A zeolite molecular sieve, adsorption and separation technology, applied in the field of molecular sieves, can solve the problems of large dust, reduced effective surface area, easy deactivation, etc., and achieve the effect of increasing surface area ratio, not easy to deactivate, and increasing adsorption

Active Publication Date: 2017-08-11
上海熙如材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Generally, the directly synthesized zeolite molecular sieve is a loose crystal powder, which is easy to be deactivated and aggregated into agglomerates during the actual storage process. During the application process, the dust is large, and a binder needs to be added to form it, so that the effective surface area of ​​​​the material is significantly reduced.

Method used

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  • A loofah zeolite molecular sieve for adsorption and separation of water turbidity and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1: a loofah zeolite molecular sieve used for adsorption and separation of water turbidity, the composition includes the following raw materials in parts by weight: loofah fiber 120, zinc chloride 2, potassium hydroxide 3, sulfuric acid 8, silica gel 40 , water glass 50, sodium silicate 25, aluminum phosphite 40, aluminum sulfate 40, hydrochloric acid 10, chitosan 25, appropriate amount of deionized water.

[0015] A preparation method for a loofah zeolite molecular sieve used for adsorption and separation of water body turbidity, comprising the following steps:

[0016] (1) Pretreatment of loofah: mix loofah fiber, zinc chloride, and potassium hydroxide, add 2-3 times the total weight of deionized water, heat and stir at 120°C for 12 hours, filter, dry, and put Put it into a horse boiling furnace and carbonize at 600°C for 3 hours in an inert gas environment to obtain loofah fibers with strong activated adsorption capacity;

[0017] (2) Mix silica gel, water...

Embodiment 2

[0019] Embodiment 2: A kind of loofah zeolite molecular sieve used for adsorption and separation of water body turbidity, the composition comprises the following raw materials by weight: loofah fiber 130, zinc chloride 3.5, potassium hydroxide 4.5, sulfuric acid 7, silica gel 30 , water glass 40, sodium silicate 20, aluminum phosphite 35, aluminum sulfate 30, hydrochloric acid 10, chitosan 25, appropriate amount of deionized water.

[0020] A preparation method for a loofah zeolite molecular sieve used for adsorption and separation of water body turbidity, comprising the following steps:

[0021] (1) Pretreatment of loofah: mix loofah fiber, zinc chloride, and potassium hydroxide, add 3 times the total weight of deionized water, heat and stir at 140°C for 11 hours, filter, dry, and put in a horse boiling furnace carbonization at 630°C for 2.5 hours in an inert gas environment to obtain loofah fibers with strong adsorption capacity;

[0022] (2) Mix silica gel, water glass, so...

Embodiment 3

[0024] Embodiment 3: a loofah zeolite molecular sieve used for adsorption and separation of water turbidity, the composition includes the following raw materials in parts by weight: loofah fiber 140, zinc chloride 5, potassium hydroxide 6, sulfuric acid 8, silica gel 20 , water glass 30, sodium silicate 15, aluminum phosphite 30, aluminum sulfate 20, hydrochloric acid 10, chitosan 25, appropriate amount of deionized water.

[0025] A preparation method for a loofah zeolite molecular sieve used for adsorption and separation of water body turbidity, comprising the following steps:

[0026] (1) Pretreatment of loofah: mix loofah fiber, zinc chloride, and potassium hydroxide, add 3 times the total weight of deionized water, heat and stir at 160°C for 10 hours, filter, dry, and put in a horse boiling furnace carbonization at 660°C for 2 hours in an inert gas environment to obtain loofah fibers with strong adsorption capacity;

[0027] (2) Mix silica gel, water glass, sodium silica...

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Abstract

The invention discloses a loofah sponge zeolite molecular sieve for water muddy matter adsorption separation and a preparation method of the loofah sponge zeolite molecular sieve. The loofah sponge zeolite molecular sieve comprises the following raw materials in parts by weight: 120-140 parts of loofah sponge fiber, 2-5 parts of zinc chloride, 3-6 parts of potassium hydroxide, 6-8 parts of sulfuric acid, 20-40 parts of silica gel, 30-50 parts of water glass, 15-25 parts of sodium silicate, 30-40 parts of aluminum orthophosphite, 20-40 parts of aluminum sulfate, 8-12 parts of hydrochloric acid, 20-30 parts of chitosan and the balance of water. According to the invention, the loofah sponge fiber can create a carrier environment for zeolite gel to enable a bundle structure and a pore structure of the loofah sponge fiber to be filled with the zeolite gel, so that the loofah sponge zeolite molecular sieve is more stable and does not deactivate easily, meanwhile, the surface area ratio is increased and adsorbability is improved.

Description

technical field [0001] The invention belongs to the field of molecular sieves, and in particular relates to a loofah zeolite molecular sieve used for adsorption and separation of turbid substances in water bodies and a preparation method. Background technique [0002] Zeolite molecular sieve is a kind of artificially synthesized aluminosilicate with microporous cubic lattice. Molecules that adsorb or repel different substances according to the size of the pores inside their crystals have good thermal and hydrothermal stability while having good shape-selective properties, and are widely used in catalytic and adsorption separation processes. Generally, the directly synthesized zeolite molecular sieve is a loose crystal powder, which is easy to be deactivated and aggregated into agglomerates during the actual storage process. During the application process, the dust is large, and a binder needs to be added to form it, so that the effective surface area of ​​​​the material is s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B39/02C02F1/28
Inventor 陈贵青
Owner 上海熙如材料科技有限公司
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