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Two-component epoxy glue and preparation method thereof

An epoxy adhesive, two-component technology, used in epoxy resin adhesives, adhesives, adhesive types, etc., can solve the problems of industry development influence and constraints, low peel strength, difficult continuous production, etc., to reduce curing. Effects of crosslinking density, improved peel strength, and improved toughness

Active Publication Date: 2015-11-18
GUANGZHOU BAIYUN CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the current domestic aluminum honeycomb adhesives have the advantages of high strength and superior aging resistance, they have shortcomings such as short operating time, and the maximum strength can only be achieved after a certain period of reaction, it is difficult to achieve continuous production, and the mechanical properties are not ideal.
[0004] Epoxy resin has the characteristics of excellent mechanical properties, adhesion, electrical insulation and good manufacturability, so it is widely used in the industrial field, but the cured product of ordinary epoxy adhesive is generally brittle when it is not toughened. Small, poor impact resistance, and peel strength is an important technical index to detect the quality of aluminum honeycomb panels, and the adhesive layer of aluminum honeycomb panels is brittle, and aluminum honeycomb panels will delaminate after long-term vibration
[0005] As the demand for aluminum honeycomb panel adhesives continues to increase, the quality and performance of existing technical products on the market are difficult to adapt to and meet the needs of applications, which inevitably has a great impact and restriction on the development of the industry.

Method used

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  • Two-component epoxy glue and preparation method thereof
  • Two-component epoxy glue and preparation method thereof
  • Two-component epoxy glue and preparation method thereof

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Embodiment

[0047] Present embodiment 6 kinds of two-component epoxy glues, comprise the raw material of percentage by weight as shown in table 1:

[0048] Table 1

[0049]

[0050]

[0051]

[0052] The epoxy resin E-44: epoxy equivalent 210-240g / eq; viscosity (25°C) 20000-40000mPa·s;

[0053] Polyurethane modified epoxy resin SL3451: epoxy value 0.45-0.50eq / 100g, viscosity (25°C) 5000-15000mPa·s;

[0054] Polyurethane modified epoxy resin SL3453: epoxy value 0.37-0.40eq / 100g, viscosity (25°C) 45000-55000mPa·s;

[0055] Epoxy resin DER331: epoxy equivalent 182-192g / eq, viscosity (25°C) 11000-14000mPa·s;

[0056] Epoxy resin DER791: epoxy equivalent 255-275g / eq, viscosity (25°C) 28000-3400mPa·s.

[0057] The preparation method of above-mentioned two-component epoxy glue, comprises the following steps:

[0058] (a) adding the epoxy resin, diluent, toughening agent, liquid flame retardant, fumed silica and defoamer into a planetary mixer, stirring and mixing evenly;

[0059] (b)...

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Abstract

The invention relates to two-component epoxy glue and a preparation method thereof. The two-component epoxy glue comprises a component A and a component B, and the component A comprises epoxy resin, a toughening agent, a liquid flame retardant, a powder flame retardant, a diluent, an antifoaming agent and reinforcing fillers; the component B comprises an aliphatic amine curing agent, polyether amine, polyamide 650 and a curing accelerator. According to the two-component epoxy glue and the preparation method thereof, screening is conducted on the components of the epoxy glue, performance complementation of the components is achieved, a two-component epoxy glue with excellent comprehensive performance is formed through synergetic cooperation, the toughness, the anti-stripping strength and the anti-impact performance of the epoxy glue are significantly improved, the flame-retardant performance can reach the grade UL94-V0, the operable time is more appropriate, the curing time is short, and the continuous production can be achieved.

Description

technical field [0001] The invention relates to the field of adhesives, in particular to a two-component epoxy adhesive and a preparation method thereof. Background technique [0002] The aluminum honeycomb panel is made of a honeycomb core plus a surface panel. The unique material and sandwich structure make the aluminum honeycomb panel have high strength, strong rigidity, light weight, durability, and good heat insulation and sound insulation. Therefore, it is widely used in high-speed On trains, subways, light rails and intercity rail trains, with the rapid development of my country's high-speed rail, high-speed rail aluminum honeycomb panel materials will surely play a more important role. [0003] The bonding strength between the aluminum honeycomb core and the panel directly affects the safety and service life of the aluminum honeycomb panel. Although the current domestic aluminum honeycomb adhesives have the advantages of high strength and superior aging resistance, t...

Claims

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Application Information

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IPC IPC(8): C09J163/00C09J163/02C09J175/04C09J11/06C09J11/04C09J11/08
Inventor 冯朝波侯甫文王运利陈建军
Owner GUANGZHOU BAIYUN CHEM IND
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