A kind of catalytic cracking diesel oil conversion method
A technology for catalytic cracking of diesel oil and catalyst, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrotreating process, etc., can solve the problems of accelerated carbon deposition rate of catalyst, affecting long-term operation, poor quality of diesel products, etc., so as to avoid further cracking. , the effect of shortening the contact time and reducing the diffusion resistance
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Embodiment 1~3
[0031] Embodiment 1~3 adopts flow process of the present invention as figure 1 .
[0032] In Examples 1-3, the hydrogenation pretreatment reactor was filled with FF-36 catalyst, and the hydrocracking reactor was loaded with different proportions of bulk phase catalysts and hydrocracking catalysts according to the order of the catalyst bed from top to bottom. catalyst. In the three examples, the ratios of the bulk catalyst to the cracking catalyst 1 and the cracking catalyst 2 in the three mixed catalyst beds are 3:1:0, 1:1:1, and 0:1:2, respectively.
[0033] The composition and properties of the catalyst are shown in Table 1, the properties of the raw materials used are shown in Table 2, and the reaction conditions and reaction results of Examples 1 to 3 are shown in Table 3 and Table 4 below.
Embodiment 4
[0035] use figure 2 process shown. Feedstock oil, and catalyst used are the same as embodiment 3. Wherein a gas extraction pipeline is set between the second and third cracking catalyst beds, and the others are the same as in Embodiment 3. The amount of gas phase material drawn from the gas phase extraction pipeline is 30% of the amount of circulating hydrogen.
[0036] Table 1 The composition and main properties of the catalysts used in the examples.
[0037] project FTX Cracking Catalyst 1 Cracking Catalyst 2 Cracking Catalyst 3 Chemical composition, mass% MoO 3 16 — — NiO 18 4 4 6 WO 3 42 18 18 22 margin Aluminum oxide Alumina + molecular sieve Alumina + molecular sieve carrier Aluminum oxide Aluminum oxide Aluminum oxide cracking components — Y molecular sieve Y molecular sieve Y molecular sieve Content, m% — 70 40 70
[0038] Table 2 Raw oil properties.
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