Application of fluorescent silica nanoparticles as anti-fake mark
A technology of silicon nanoparticles and anti-counterfeiting marks, which is applied in the field of silicon nanomaterials to achieve good anti-counterfeiting effects, good fluorescent properties, and high quantum yields
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Embodiment 1
[0018] (1) Preparation of fluorescent silicon nanoparticles
[0019] After crushing the rice husk, wash it with deionized water, add 38wt%-5wt% hydrochloric acid, and heat it in a water bath for 1h-10h; wash the acid-treated sample with deionized water until it is neutral, put it in a porcelain crucible, and wash it with alcohol. The lamp is heated until the sample turns into white powder; take a small amount of white powder, add 0.1mol / L-10mol / L NaOH solution, and heat it with microwave radiation for 30min-20h at a power of 15W-1000W and a temperature of 100°C-160°C to obtain a water-soluble permanent silicon nanoparticles.
[0020] (2) Using silicon nanoparticles for anti-counterfeiting preparation
[0021] The prepared fluorescent silicon nanoparticles were used as anti-counterfeiting ink for printing patterns.
Embodiment 2
[0023] (1) Preparation of fluorescent silicon nanoparticles
[0024] After crushing the wheat straw, wash it with deionized water, add 38wt%-5wt% hydrochloric acid, and heat it in a water bath for 1h-10h; wash the acid-treated sample with deionized water until it is neutral, put it in a porcelain crucible, and wash it with alcohol The lamp is heated until the sample turns into white powder; take a small amount of white powder, add 0.1mol / L-10mol / L NaOH solution, and heat it with microwave radiation for 30min-20h at a power of 15W-1000W and a temperature of 100°C-160°C to obtain a water-soluble permanent silicon nanoparticles.
[0025] (2) Using silicon nanoparticles for anti-counterfeiting
[0026] The prepared fluorescent silicon nanoparticles were used as anti-counterfeiting ink for printing patterns.
Embodiment 3
[0028] (1) Preparation of fluorescent silicon nanoparticles
[0029] Crush the bagasse and wash it with deionized water, add 38wt%-5wt% hydrochloric acid, heat in a water bath for 1h-10h; wash the acid-treated sample with deionized water until it is neutral, put it in a porcelain crucible, and wash it with alcohol The lamp is heated until the sample turns into white powder; take a small amount of white powder, add 0.1mol / L-10mol / L NaOH solution, and heat it with microwave radiation for 30min-20h at a power of 15W-1000W and a temperature of 100°C-160°C to obtain a water-soluble permanent silicon nanoparticles.
[0030] (2) Using silicon nanoparticles for anti-counterfeiting
[0031] The prepared fluorescent silicon nanoparticles were used as anti-counterfeiting ink for printing patterns.
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