Organic polymer slow-controlled release nitrogen and phosphorus fertilizer containing iron, manganese, copper and zinc microelements and preparation method of organic polymer slow-controlled release nitrogen and phosphorus fertilizer
A technology of organic polymers and trace elements, applied in the direction of nitrogen fertilizer, urea compound fertilizer, fertilization device, etc., can solve the problems of being easily fixed by the soil, high production cost of chelate, and low utilization rate, so as to increase crop yield and improve The effect of crop quality and simple preparation method
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Embodiment 1
[0053] A preparation method of an organic polymer slow-release nitrogen-phosphorus fertilizer containing trace elements of iron, manganese, copper and zinc, comprising the following steps:
[0054] (1) Add 1.8g of phosphoric acid and 0.0375g of zinc powder into the first reactor, stir and dissolve to obtain component A;
[0055] (2) Add 50 mL of distilled water to the second reactor, add 1.25 g of ferrous sulfate, 0.525 g of manganese sulfate and 0.108 g of copper sulfate crystals, adjust the pH to 8-10, let stand, and filter to obtain component B;
[0056] (3) Add component B to component A to obtain product C;
[0057] (4) Add a molar ratio of 39.0g urea and 35.0mL formaldehyde into the third reactor, react for 120min at a pH value of 8-10 and a temperature of 30-35°C, and then raise the temperature to 50°C- 60°C, continue to react for 30 minutes, add product C, raise the temperature to 70-80°C, continue to react for 40 minutes, the reaction solution becomes viscous, granul...
Embodiment 2
[0060] The preparation method of the organic macromolecule slow and controlled release nitrogen and phosphate fertilizer containing trace elements of iron, manganese, copper and zinc comprises the following steps:
[0061] (1) Add 1.8g of phosphoric acid and 0.0375g of zinc powder into the first reactor, stir and dissolve to obtain component A;
[0062] (2) Add 50 mL of distilled water to the second reactor, add 1.25 g of ferrous sulfate, 0.525 g of manganese sulfate and 0.108 g of copper sulfate crystals, adjust the pH to 8-10, let stand, and filter to obtain component B;
[0063] (3) Add component B to component A to obtain product C;
[0064] (4) Add 39.0g urea and 39.0mL formaldehyde into the third reactor, react for 120min under the conditions of pH value 8-10 and temperature 30-35°C, then raise the temperature to 50°C-60°C, Continue the reaction for 30 minutes, add product C, raise the temperature to 70-80°C, continue the reaction for 35 minutes, the reaction solution b...
Embodiment 3
[0067] The preparation method of the organic macromolecule slow and controlled release nitrogen and phosphate fertilizer containing trace elements of iron, manganese, copper and zinc comprises the following steps:
[0068] (1) Add 1.8g of phosphoric acid and 0.0375g of zinc powder into the first reactor, stir and dissolve to obtain component A;
[0069] (2) Add 50 mL of distilled water to the second reactor, add 1.25 g of ferrous sulfate, 0.525 g of manganese sulfate and 0.108 g of copper sulfate crystals, adjust the pH to 8-10, let stand, and filter to obtain component B;
[0070] (3) Add component B to component A to obtain product C;
[0071] (4) Add 39.0g of urea and 30.5mL of formaldehyde into the third reactor, react for 40min under the conditions of pH value 8-10 and temperature 30-35°C, then raise the temperature to 50°C-60°C, Continue to react for 30 minutes, add product C, raise the temperature to 70-80°C, continue to react for 30 minutes, the reaction solution beco...
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