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Treatment method of rubber accelerator production wastewater

A technology for rubber accelerators and waste water production, applied in biological water/sewage treatment, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc., can solve problems such as secondary pollution, high cost, failure, etc., and achieve The effect of reducing processing costs, increasing economic benefits, and reducing pressure

Inactive Publication Date: 2015-04-29
SHANDONG YONGTAI CHEM GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The biggest disadvantage of this method of physical chemistry + biochemical combination is that it only simply transfers or dilutes the pollutants, which consumes a lot of water treatment chemicals, which not only costs high, but also causes secondary pollution, and a large amount of inorganic salts are discharged into the environment. It will cause the harm of soil salinization. Some auxiliary wastewater such as vulcanization accelerator NS wastewater will change color and increase in chroma after biochemical treatment, which cannot meet the relevant discharge requirements.
The resin adsorption method will fail due to pore blockage; membrane separation technology has high requirements for suspended solids and acidity and alkalinity, and it is not suitable to pretreat the wastewater; the salt content of the wastewater treated by the extraction method has not changed; if the wastewater is only used Simple distillation and evaporation treatment can separate inorganic salts and water, but the effluent will still contain some organic pollutants, and the water quality still cannot meet the discharge requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] Rubber accelerator production waste water treatment method comprises the following steps:

[0063] (1) Add acid to the waste water to neutralize it until its pH is about 7, and then perform multi-effect evaporation desalination treatment;

[0064] (2) adding a defoamer to the waste water in step (1), and then undergoing aeration and defoaming treatment for 4 hours, the defoamer accounts for 0.03% of the weight of the waste water;

[0065] (3) adding microbial water purifying agent in the waste water in step (2);

[0066] The parts by weight of the microbial water purifying agent are: 1.2 of nitrifying bacteria powder, 0.9 of denitrifying paracoccus powder, 0.6 of sulfur bacteria powder, 0.9 of aniline-degrading bacteria powder, and 0.9 of brevibacillus powder, and its weight accounts for 0.08% of the total weight;

[0067] (4) add enzyme preparation in the waste water in step (3); The parts by weight of described enzyme preparation are: pectinase 0.8, cellulase 0.9, d...

Embodiment 2

[0078] Rubber accelerator production waste water treatment method comprises the following steps:

[0079] (1) Adding acid to the waste water to neutralize it to a pH of 6.8, and then performing multi-effect evaporation desalination treatment;

[0080] (2) adding a defoamer to the waste water in step (1), and then undergoing aeration and defoaming treatment for 3 hours, the defoamer accounts for 0.01% of the weight of the waste water;

[0081] (3) Add microbial water purifying agent in the waste water in step (2), its weight accounts for 0.05% of waste water gross weight

[0082] The parts by weight of the microbial water purifying agent are: 0.5 of nitrifying bacteria powder, 0.4 of denitrifying paracoccus bacteria powder, 0.2 of sulfur bacteria powder, 0.3 of aniline degrading bacteria powder, and 0.4 of brevis bacillus powder, and its weight accounts for 0.05% of the total weight;

[0083] (4) add enzyme preparation in the waste water in step (3); The parts by weight of de...

Embodiment 3

[0086] Rubber accelerator production waste water treatment method comprises the following steps:

[0087] (1) adding acid to the waste water to neutralize it to a pH of 7.2, and then performing multiple-effect evaporation desalination treatment;

[0088] (2) Adding an organosilicon defoamer to the waste water in step (1), and then undergoing aeration and defoaming treatment for 6 hours, the organosilicon defoamer accounts for 0.06% of the weight of the waste water;

[0089] (3) adding microbial water purifying agent in the waste water in step (2);

[0090] The parts by weight of microbial water purifier are: nitrifying bacteria powder 2.0, denitrifying paracoccus bacteria powder 1.5, sulfur bacteria powder 0.8, aniline degrading bacteria powder 1.2, flocculation bacteria powder 1.5, silicate bacteria powder 1.0, Bacillus subtilis powder 1.2, its weight accounts for 0.2% of the total weight of waste water;

[0091](4) add enzyme preparation in the waste water in step (3); The...

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PUM

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Abstract

The invention belongs to the technical field of environment-friendly water treatment and particularly relates to a treatment method of rubber accelerator production wastewater. The treatment method comprises the following steps: (1) carrying out acid neutralization on wastewater until the pH value is 6.5-7.5, and carrying out multiple-effect evaporation and desalination; (2) adding a defoaming agent into the wastewater in the step (1), and carrying out aeration defoaming; (3) adding a microbial water purifier into the wastewater in the step (2); (4) adding an enzymic preparation into the wastewater in the step (3); and (5) oxidizing and adsorbing the wastewater in the step (4). By virtue of the sewage treatment method, the water purification effect is good, the water purification speed is high, the safety is high, and the secondary pollution is avoided; the wastewater is treated by taking materials with the adsorption capacity as the raw materials and supplementing microorganisms, the use range is wide, and the treated water is extremely high in transparency and can be recycled.

Description

technical field [0001] The invention belongs to the technical field of environmental protection water treatment, and in particular relates to a method for treating wastewater produced by rubber accelerators. Background technique [0002] With the development of the rubber industry, the rubber additives industry has also been rapidly developed and expanded, and is marching towards the direction of scale and intensification, and has a pivotal position in the global industry. The rubber industry is one of the major drainage households in the petrochemical industry. Its drainage water quality is complex and changes greatly. For example, rubber accelerator wastewater contains more refractory organic matter. It is difficult to achieve the ideal by direct physical clarification or chemical reagent treatment. Governance effect. The wastewater produced in the synthetic rubber production process has a large amount of discharge and strong toxicity. If it is discharged directly without...

Claims

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Application Information

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IPC IPC(8): C02F9/14C02F3/34
Inventor 尤晓明王显涛李洋迟文泉邓世海
Owner SHANDONG YONGTAI CHEM GROUP
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