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Method for preparing light oil from low-hydrogen-content oil with self-contained asphalten

A technology of asphaltene and hydrogen content, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrogenation process, etc., and can solve the problems of poor combustion performance, increased investment, increased energy consumption, etc.

Inactive Publication Date: 2015-04-08
何巨堂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] ① To produce delayed coke, it is necessary to build a coking unit, increase investment, increase energy consumption, and at the same time convert a large amount (about 50%) of components with a conventional boiling point of 500-540°C into coke. Industrial production shows that medium-temperature coal tar in northern Shaanxi As a raw material, the yield of coke is about 14.5%, and the yield of coking gas is about 5.0%, and the quality of coke is poor, and the scope of use is limited; it belongs to the uneconomical "oil zoom, gas" process;
[0005] ②In the production of fuel oil, in order to meet the requirements of the viscosity and freezing point of fuel oil, the content of light oil in it is relatively high, resulting in low-value utilization of this part of the components. Industrial production shows that using medium-temperature coal tar in northern Shaanxi as raw material, fuel The oil yield is about 10-15%. At the same time, because of its poor combustion performance, serious pollution, and low price, the scope of use is limited, and it is not economical to use;
[0006] ③The production of coal tar pitch is difficult to sell due to its high ash content and low coking value;
[0017] Method of the present invention has no report

Method used

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  • Method for preparing light oil from low-hydrogen-content oil with self-contained asphalten

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0114] The medium and low temperature coal tar produced in the coal-to-semi-coke process is shown in Table 1. The annual processing capacity is 500,000 tons / year, the annual operating hours are 7920, and the quantity is 63132kg / h. In order to separate the light residual oil component to the greatest extent, and simultaneously concentrate the asphaltenes, ash, and particulate matter in the coal tar in the heavy coal tar pitch to obtain a high softening point of the coal charcoal, adopt the present invention, and the operation steps are as follows:

[0115] In the deep vaporization separation part STEP1, under the condition that no obvious coking reaction occurs, the raw material F01 is heated and separated into vapor phase V1 (59072kg / h, 93.57% of the raw material F01) and the liquid phase L1 (4060 / h, accounting for 6.43% of the raw material F01) containing the residual oil component, the weight content of the components with a conventional boiling point higher than 500 ° C in t...

Embodiment 2

[0123] Based on Example 1, in the vaporized oil recovery step, the vapor phase V1 from the deep vaporization separation part STEP1 and the stripped oil vapor V2 from the steam stripping part STU are condensed to obtain hydrocarbon oil HPF.

[0124] In the hydrogenation step, the hydrocarbon oil HPF is converted into a hydrogenated oil product through the hydro-upgrading process HP, and the hydro-upgrading process HP includes the hydrofinishing process HT of the hydrocarbon oil HPF, and also includes the separation of the hydrofinishing process HT Hydrocracking process HC of hydrorefined wax oil HTVGO obtained mainly from hydrocarbon components with conventional boiling point higher than 350°C obtained by hydrogenation HTP.

[0125] This example forms a combination process of medium and low temperature coal tar deep drawing and vaporized oil hydrogenation upgrading process.

[0126] Table 1 Analysis data of coal tar properties

[0127]

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PUM

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Abstract

The invention provides a method for preparing light oil from low-hydrogen-content oil with self-contained asphalten. The method is suitable for processing of medium-low temperature coal tar. According to the invention, a deep evaporation method is adopted to isolate the medium-low temperature coal tar into distillate oil vapor V1 and liquid L1 under the condition of no occurrence of obvious coking, wherein the liquid L1 is mainly composed of macromolecular colloidal bituminous components; after cooling and molding, the liquid L1 used as soft coal or green coal can be used as fire coal to achieve green storage and usage of the liquid L1; and the distillate oil vapor V1 is condensed to obtain an oil product which can be used for preparing a clean oil product via a hydrogenation process. The method for preparing light oil from low-hydrogen-content oil with self-contained asphalten provided by the invention enables the product direction of the macromolecular colloidal bituminous components in medium-low temperature coal tar to jump out of the traditional range of coke, coal tar pitch, fuel oil, suspended-bed or bubbling-bed hydrogenation raw material to produce coal-like products; and the traditional concept of ultimate obtainment of light oil and residual oil through vapor-liqiud separation is converted into the concept of ultimate obtainment of light oil and solid through vapor-liqiud separation.

Description

technical field [0001] The present invention relates to a kind of method for producing light oil from asphaltene-containing low-hydrogen content oil; particularly the present invention relates to a kind of method for producing light oil from asphaltene-containing coal tar; more particularly The present invention relates to a method for producing light oil from medium and low temperature coal tar containing asphaltenes. The medium and low temperature coal tar is separated into distillate steam V1 by adopting a deep vaporization method without obvious coking reaction. And liquid L1 mainly composed of macromolecular colloidal asphalt-like components, liquid L1 can be used as "soft media" or coal green after cooling and forming, which can be used as coal to realize its environmental protection storage and use; distillate steam V1 The condensed oil can be hydrogenated to produce clean oil. The present invention jumps out the product direction of the macromolecular colloidal pitch-...

Claims

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Application Information

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IPC IPC(8): C10G7/00C10G67/00
CPCC10G7/00C10G67/00
Inventor 何巨堂
Owner 何巨堂
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