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High-efficiency coal combustion catalyst

A coal combustion and catalyst technology, applied in the field of high-efficiency coal combustion catalysts, can solve problems such as difficult ignition and heat transfer, reduced thermal efficiency, and large coal heat capacity, so as to ensure combustion conditions and output loads, improve combustion efficiency, and improve combustion efficiency. speed effect

Inactive Publication Date: 2015-02-04
SCI RES ACADEMY OF GUANGXI ENVIRONMENTAL PROTECTION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Coal combustion is a complex oxidation process, which can generally be divided into volatile combustion (called homogeneous combustion) and carbon particle ignition (called heterogeneous combustion). The biggest problem in the combustion and utilization of coal resources is the reason for the low calorific value utilization. Because of the large heat capacity of coal, it is not easy to ignite and transfer heat, and its basic one-way reaction C+O 2 =CO 2 The reaction activation energy is large and prone to negative reactions C+CO 2 = 2CO, which greatly reduces thermal efficiency, of which industrial boilers consume about 300 million tons of coal. Industrial kilns and other furnaces consume about 300 million tons of coal
The traditional combustion method is mostly flame combustion, and the heat emitted is not fully utilized, and because of insufficient combustion, it will inevitably cause a huge waste of energy; on the other hand, the traditional combustion method can also produce a large amount of toxic and harmful gases. , resulting in serious pollution of the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Take by weight the following raw materials: Triisopropanolamine 5%, Baume degree is 30% of alkali plant waste liquid of 35 ° Bé, tert-butyl alcohol 20%, propylene glycol 15%, lanthanum nitrate 5%, Span-205 %, Tween-205%, isobutanol 6%, NaCl 2%, FeCl 3 7%;

[0026] Add triisopropanolamine, tert-butanol, propylene glycol and isobutanol into the reaction kettle and stir for 50 minutes, then add waste liquid from the alkali plant, stir and mix thoroughly, then add lanthanum nitrate, Span-20, and Tween-20 after filtering , NaCl and FeCl 3 , while continuing to stir, the reactor was heated to 50° C. for 3 hours to obtain the desired coal combustion catalyst.

Embodiment 2

[0028] Take the following raw materials by weight percentage: 7% of triisopropanolamine, 28% of alkali plant waste liquid that Baume degree is 37 ° of Bé, 23% of tert-butyl alcohol, 13% of propylene glycol, lanthanum sulfate 4%, fatty acid glyceride 6 %, Tween-405%, isobutanol 5%, NaCl 3%, FeCl 3 6%;

[0029] Add triisopropanolamine, tert-butanol, propylene glycol and isobutanol into the reaction kettle and stir for 50 minutes, then add waste liquid from the alkali plant, stir and mix thoroughly, and then add lanthanum sulfate, fatty acid glyceride, Tween-40, NaCl and FeCl 3 , while continuing to stir, the reactor was heated to 50° C. for 3 hours to obtain the desired coal combustion catalyst.

Embodiment 3

[0031] Take by weight the following raw materials: Triisopropanolamine 10%, Baume degree is 25% of alkali plant waste liquid of 38 ° B é, tert-butyl alcohol 25%, propylene glycol 12, lanthanum nitrate 3%, Tween-80 12% , Isobutanol 4%, NaCl 4%, FeCl 3 5%;

[0032] Add triisopropanolamine, tert-butanol, propylene glycol and isobutanol into the reaction kettle and stir for 50 minutes, then add waste liquid from the alkali plant, stir and mix thoroughly, and then add lanthanum nitrate, Tween-80, NaCl and FeCl after filtering 3 , while continuing to stir, the reactor was heated to 50° C. for 3 hours to obtain the desired coal combustion catalyst.

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Abstract

The invention relates to the technical field of coal combustion additives, particularly a high-efficiency coal combustion catalyst which is prepared from the following raw materials in percentage by weight: 5-15% of triisopropanolamine, 20-30% of alkali plant waste liquid, 20-30% of tert-butyl alcohol, 10-15% of propanediol, 1-5% of rare-earth element compound, 10-15% of nonionic surfactant, 2-6% of isobutanol, 2-6% of NaCl and 3-7% of FeCl3. When being used in the coal combustion process, the coal combustion catalyst can lower the ignition point of the coal and enhance the combustion velocity, thereby enhancing the coal combustion efficiency and lowering the discharge amount of harmful substances. By using the alkali plant waste liquid as the raw material, the coal combustion catalyst changes wastes into valuable substances and lowers the cost.

Description

technical field [0001] The invention relates to the technical field of coal combustion admixtures, in particular to a high-efficiency coal combustion catalyst. Background technique [0002] Coal is mainly composed of elements such as carbon, hydrogen, oxygen, nitrogen, sulfur and phosphorus, and is the most important primary energy source in my country, accounting for 76% of China's total energy consumption. It is estimated that by 2000, my country's coal output will reach 1.4 billion tons. By 2050, my country's annual coal demand will be about 2.1 billion tons, accounting for about 50% of the primary energy mix. With the rapid development of our country's economy and the dwindling of the world's oil reserves, the position of coal as the main energy source will be more consolidated and will not change for a long time. From the perspective of coal utilization, about 84% of the total coal output is used for direct combustion every year. In addition, there are a small number ...

Claims

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Application Information

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IPC IPC(8): C10L9/10
Inventor 于芳
Owner SCI RES ACADEMY OF GUANGXI ENVIRONMENTAL PROTECTION
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