Method for preparing polyimide liquid crystal aligning agent
A technology of liquid crystal aligning agent and polyimide, applied in liquid crystal materials, chemical instruments and methods, etc., can solve the problems of high single-point defect rate and insufficient
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preparation Embodiment 1
[0052] At room temperature, under nitrogen protection, 10 g of the specific diamine was dissolved in 50 ml of N-methylpyrrolidone. Add 14.5 g of pyromellitic dianhydride and stir for 2 hours. Add 10 g of 4,4'-diaminobenzenemethane and stir for 36 h. It was diluted with 600 ml of 1,4-butyrolactone to obtain a polyimide liquid crystal alignment liquid. A liquid crystal cell is made, and the measured pretilt angle is 10.5 degrees.
preparation Embodiment 2
[0054] At room temperature, under nitrogen protection, 10 g of the specific diamine was dissolved in 200 ml of N-methylpyrrolidone. Add 11.7 g of pyromellitic dianhydride and stir for 2 hours. Add 8 g of 3,3'-diaminobenzophenone, and stir for 36 h. It was diluted with 200 ml of 1,4-butyrolactone to obtain a polyimide liquid crystal alignment liquid. A liquid crystal cell is made, and the measured pretilt angle is 11.1 degrees.
[0055]
preparation Embodiment 3
[0057]At room temperature, under nitrogen protection, 10 g of the specific diamine was dissolved in 100 ml of N-methylpyrrolidone. Add 10.5 g of 3,4,9,10-perylenetetracarboxylic anhydride, and stir for 2 hours. Add 8 g of 3,3'-diaminobenzophenone, and stir for 36 h. It was diluted with 500 ml of 1,4-butyrolactone to obtain a polyimide liquid crystal alignment liquid. A liquid crystal cell is made, and the measured pretilt angle is 12.4 degrees.
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