Petroleum resin hydrogenation catalyst and application thereof
A hydrogenation catalyst, petroleum resin technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problem of affecting resin color, stability and resin compatibility In order to achieve the effect of good chromaticity, simple preparation method and appropriate ratio
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Embodiment 1
[0020] Weigh an appropriate amount of nickel nitrate, ammonium metatungstate, cobalt nitrate and cerium nitrate, and add them into deionized water to form a mixed solution of 85 mL as an impregnation solution. Weigh 100g of Al prepared according to the method of patent ZL02146005.1 2 o 3 -TiO 2 The carrier is added to the above impregnation solution for impregnation at room temperature for 4 hours. After filtration, the solid was dried at a temperature of 120°C for 10 hours, and then calcined at a temperature of 550°C for 6 hours, and the calcined solid was taken out and allowed to cool down to room temperature naturally to obtain catalyst A. Based on the total weight of the catalyst A, it contains 9.4% by weight of Ni, 11.6% by weight of W, 1.0% by weight of Co, and 1.0% by weight of Ce.
Embodiment 2
[0022] Weigh an appropriate amount of nickel nitrate, ammonium metatungstate, cobalt nitrate and cerium nitrate, and add them into deionized water to form a 95mL mixed solution as the impregnation solution. Weigh 100g of Al prepared according to the method of patent ZL02146005.1 2 o 3 -TiO 2 The carrier is added to the above impregnation solution for impregnation at room temperature for 4 hours. After filtration, the solid was dried at a temperature of 120°C for 10 hours, and then calcined at a temperature of 550°C for 6 hours, and the calcined solid was taken out and allowed to cool down to room temperature naturally to obtain catalyst B. Based on the total weight of the catalyst B, Ni is 12.4% by weight, W is 9.2% by weight, Co is 0.8% by weight, and Ce is 0.5% by weight.
Embodiment 3
[0024] Weigh an appropriate amount of nickel nitrate, ammonium metatungstate, cobalt nitrate and cerium nitrate, and add them into deionized water to form a 102mL mixed solution as an impregnation solution. Weigh 100g of Al prepared according to the method of patent ZL02146005.1 2 o 3 -TiO 2 The carrier is added to the above impregnation solution for impregnation at room temperature for 4 hours. After filtration, the solid was dried at a temperature of 120°C for 10 hours, and then calcined at a temperature of 550°C for 6 hours, and the calcined solid was taken out and allowed to cool down to room temperature naturally to obtain catalyst C. Based on the total weight of the catalyst C, Ni is 14.4% by weight, W is 7.0% by weight, Co is 1.4% by weight, and Ce is 0.5% by weight.
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