A kind of water-based protective coating capable of adhering to high-temperature billet and preparation method thereof

A protective coating, water-based technology, applied in the direction of sustainable manufacturing/processing, coating, climate sustainability, etc., to achieve a wide range of operating temperature, reduce heat dissipation, and reduce the effect of burning in the furnace

Active Publication Date: 2016-06-22
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is suitable for high temperature protective coating technology and high temperature steel surface blackening technology in billet continuous casting and rolling process

Method used

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  • A kind of water-based protective coating capable of adhering to high-temperature billet and preparation method thereof
  • A kind of water-based protective coating capable of adhering to high-temperature billet and preparation method thereof
  • A kind of water-based protective coating capable of adhering to high-temperature billet and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Clay, magnesite, magnetite and steel slag are mixed according to the chemical composition ratio of dry material: 50wt% MgO, 15wt% Al 2 o 3 , 15wt% ZnO, 5wt% CaO, 5wt% SiO 2 , 2wt% Fe 2 o 3 , 3wt%Na 2 O, 2wt%K 2 O, 3wt% rare earth and other components, and then ball milled to below 300 mesh; the density of the powder is adjusted to 1.45g / cm by adding water 3 ; Sodium dodecylbenzene sulfonate and sodium citrate were put into water according to mass fraction 0.2%, 0.5% and stirred respectively, then ZnSO was added according to mass fraction 10%, 5% respectively 4, ZnO was added to the previously prepared liquid, and stirred at 60° C. for 3 minutes to form a sol; 5% mass fraction of the sol was added to the above coating to obtain the coating. The paint is sprayed on the surface of the room temperature Q235 billet to form a light yellow protective coating. After leaving the heating furnace, the iron oxide scale is obviously thinned, and the oxidation burning loss is ...

Embodiment 2

[0032] Clay, magnesite, diatomite, magnetite and Ni slag are mixed according to the chemical composition ratio of dry material: 40wt% MgO, 15wt% Al 2 o 3 , 20wt% ZnO, 8wt% CaO, 2wt% Fe 2 o 3 , 5wt% SiO 2 , 2wt% NiO, 3wt% Na 2 O, 2wt%K 2 O, 3wt% rare earth and other components, and then ball milled to below 300 mesh; the density of the powder is adjusted to 1.3g / cm by adding water 3 ; Sodium carboxymethyl cellulose and sodium citrate were put into water according to mass fraction 0.2%, 0.5% and stirred respectively, and then ZnO, ZnSO were respectively mixed according to mass fraction 10%, 5%. 4 Add it to the previously prepared liquid, and stir at 70°C for 4 minutes to make a sol; add 4% mass fraction of the sol to the above coating, and finally add 2wt% low-melting glass powder to obtain the coating. The paint is sprayed on the surface of Q235 steel billet at about 700°C to form a light yellow protective coating. After leaving the heating furnace, the iron oxide scale ...

Embodiment 3

[0034] Clay, magnesite, diatomite, magnetite and blast furnace slag are mixed according to the chemical composition ratio of dry material: 35wt% MgO, 12wt% Al 2 o 3 , 30wt% ZnO, 5wt% CaO, 3wt% Fe 2 o 3 , 5wt% SiO 2 , 5wt%Na 2 O, 2wt%K 2 O, 3wt% rare earth and other components, and then ball milled to below 300 mesh; the density of the powder is adjusted to 1.2g / cm by adding water 3 ; Sodium carboxymethyl cellulose and sodium citrate were put into water according to mass fraction 0.2%, 0.5% and stirred respectively, and then ZnO, ZnSO 4 , Zn(OH) 2 Add it to the previously prepared liquid, and stir at 80°C for 5 minutes to make a sol; add 4% mass fraction of the sol to the above coating, and finally add 3wt% low-melting glass powder to obtain the coating. Spray the paint on the surface of Q235 steel billet at about 1050℃ to form a layer of milky white protective coating. After leaving the heating furnace, the iron oxide scale is obviously thinned, and the oxidation burni...

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Abstract

The invention relates to a water-based protective coating capable of adhering to a high temperature billet and a preparation method thereof, and belongs to the field of metal high-temperature protection. The water-based protective coating comprises main powder, 0-3wt% of an inorganic binder and 3-5wt% of a self-made additive. The main powder is prepared from natural raw materials such as clay, magnesite, diatomite, magnetite and metallurgy tailings. The self-made additive is a sol system comprising a surfactant and a Zn-containing component. The powder is subjected to ball milling so that particle sizes are less than 300 meshes, density of the slurry is adjusted to 1.2-1.5g / cm<3> and density is decreased with spray-coating temperature increasing. The water-based protective coating is suitable for spray-coating a billet having a temperature less than 1200 DEG C and heated in a heating furnace for 1-10h. The preparation method can realize adjustment and control of billet trace element distribution, does not change billet surface physicochemical characteristics and reduces a burning loss by more than 60%. The preparation method has active promotion effects of saving energy and reducing consumption in the metallurgy industry, improving steel quality and improving core competitiveness of a steel enterprise.

Description

technical field [0001] The invention relates to a preparation method of a water-based protective coating capable of adhering to a high-temperature steel billet, in particular to a preparation method of a water-based inorganic protective coating capable of adhering to a high-temperature steel billet at room temperature to 1200°C. It belongs to the field of metal high temperature coating protection. Background technique [0002] The heating of billet is an essential and important process before forging and rolling of steel. Increasing the temperature of billet is an important method to improve its plasticity. Since the steel parts are heated in the heating furnace for a long time, the surface of the steel parts and the oxygen in the atmosphere undergo a strong oxidation reaction at high temperature to form a large amount of oxide scales. It consumes energy, reduces the yield of steel billet, and causes the quality of steel after rolling to decrease, and the service life of he...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D7/12
CPCY02P20/10
Inventor 仉小猛魏连启叶树峰单欣陈运法
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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