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A kind of production method of float glass

A production method and float glass technology, applied in the field of float glass production, can solve the problems of rapid cooling of tin liquid, high local concentration of iron, easy generation of bubbles in float glass, etc., and achieve the effect of less bubbles and small amount of tin penetration

Inactive Publication Date: 2017-02-15
HAINAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the iron used must be pure iron. Pure iron melts and absorbs heat, which will cause the tin liquid to cool down too quickly, and the iron will also bring a small amount of iron oxide impurities, and adding iron directly into the tin bath will also cause the local concentration of iron to be too high. The existence of these factors makes the float glass prone to air bubbles

Method used

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  • A kind of production method of float glass
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preparation example Construction

[0024] The preparation method of described tin bath additive preferably comprises the following steps:

[0025] Mix 18-48.8wt% tin and 51.2-82wt% iron and vacuum arc melting to obtain a master alloy with uniform composition;

[0026] The master alloy is granulated to obtain a tin bath additive with a tin content of 18-48.8% by mass and a melting point of 1130-1400°C.

[0027] The present invention uses tin and iron as raw materials, and first mixes them according to the mass ratio. The mass percentage of the tin is 18-48.8wt%, preferably 25-38wt%, more preferably 28-35wt%. The mass percentage of the iron is 51.2-82wt%, preferably 62-75wt%, more preferably 65-78wt%.

[0028] After the tin and iron are mixed, they are vacuum arc melted to obtain a master alloy with a uniform composition. The vacuum arc melting is preferably carried out in an inert gas protection, and the inert gas is preferably argon. The air pressure of the vacuum arc melting is preferably 0.02-0.04 MPa. In...

Embodiment 1

[0034] After mixing 488 grams of tin and 512 grams of iron, use gas shielded arc melting, repeated melting to obtain an alloy with uniform composition;

[0035] The master alloy was placed in a mechanical device and shaped to obtain a tin bath additive with a particle size of 3mm.

Embodiment 2

[0038] After mixing 380 grams of tin and 620 grams of iron, use gas shielded arc melting, repeated melting to obtain an alloy with uniform composition;

[0039] The master alloy was placed in a mechanical device and shaped to obtain a tin bath additive with a particle size of 3mm.

[0040] According to the phase diagram, the equilibrium structure of the tin bath additive is hypomotectic, with a large number of agglomerated α-Fe particles and FeSn phases, and its melting point is 1216°C.

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Abstract

The invention provides a production method of float glass. The method comprises the following steps: melting glass to obtain molten glass; adding a tin bath additive to molten tin at a tin bath constriction section at 650-750 DEG C; adding the molten glass to the tin bath to obtain a glass tape; and annealing the glass tape to obtain the float glass, wherein the tin bath additive is an iron-tin monotectic or hypomonotectic alloy with the mass percentage content of tin of 18-48.8% and the melting point of 1130-1400DEG C. The melting point of tin is lower than that of iron, the addition of a proper amount of tin makes the tin bath additive have a low melting point, and the temperature of the molten tin does not violently decrease when the tin bath additive is added to the molten tin in the tin bath, so bubbles are avoided. A ratio of tin to iron is proper, so after the tin bath additive is added to the molten tin, local enrichment of iron is unlikely, and bubbles can also be avoided. The use of the tin bath additive in the invention is helpful to obtain the high-quality float glass with few bubbles and small tin permeability.

Description

technical field [0001] The invention relates to the field of float glass production, in particular to a production method of float glass. Background technique [0002] The production process of float glass is as follows: the molten glass is continuously flowed from the tank kiln and floated on the surface of the relatively dense tin liquid, and under the action of gravity and surface tension, the glass liquid is spread on the surface of the tin liquid, Flatten to form a glass ribbon with flat and hardened upper and lower surfaces, pull the glass ribbon out of the tin bath, anneal and cut to obtain float glass products. [0003] In the above-mentioned float glass production process, the tin bath is a container for storing molten tin, and its function is to form glass with a certain thickness and width by external force at a certain temperature with the molten glass. [0004] After the tin liquid in the tin bath is oxidized by oxygen, the generated tin monoxide easily penetra...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03B18/00C03B18/18
Inventor 马艳平李长久姜宏
Owner HAINAN UNIV
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