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Graphene coated lithium battery cathode material and preparation method thereof

A graphene-coated, positive-electrode material technology, applied in the direction of battery electrodes, circuits, electrical components, etc., can solve problems such as restricting development prospects, lack of manganese resources, and high prices, and achieve extended storage time, improved self-discharge, and low cost Effect

Inactive Publication Date: 2014-09-24
QINGDAO QIANYUN HIGH TECH NEW MATERIAL
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AI Technical Summary

Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but manganese resources are scarce and expensive And it is toxic, so it is an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials.
Spinel-type positive electrode materials represented by lithium manganate and layered oxides of ternary materials have been widely studied in the past decade, but their development prospects are restricted by their respective defects.

Method used

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Embodiment Construction

[0014] The graphene-coated lithium battery cathode material is prepared in parts by weight from the following components according to the ratio shown: graphene oxide 15~25, active material 80~85, functional material 5~10, conductive material 3~ 5. Adhesive materials 3~5. The functional material is 60% lithium iron nitrate solution. The positive electrode material is lithium manganate. The conductive agent is flake graphite

[0015] The preparation method of the graphene-coated lithium battery cathode material comprises the following steps:

[0016] (1) Take graphite and sodium nitrate, put them in a certain amount of concentrated sulfuric acid in an ice bath with a mass ratio of 2:1, add potassium permanganate 3 times the mass of the graphite under stirring, mix well, and control the temperature to low Stir at 20°C for about 1 h, then increase the temperature to 32-38°C for 2 h, slowly add quantitative deionized water dropwise, stir well, add hydrogen peroxide to terminate ...

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Abstract

The invention relates to a graphene coated lithium battery cathode material and a preparation method thereof. The graphene coated lithium battery cathode material is prepared from the following components in parts by weight: 15-25 parts of graphene oxide, 80-85 parts of active material, 5-10 parts of functional material, 3-5 parts of conductive material and 3-5 parts of binding material, wherein the functional material is 60% lithium iron nitrate solution; the cathode material is lithium manganate; the conductive agent is flake graphite. The defect of failure of lithium ion batteries caused by self-discharge of protection boards is overcome by adopting the graphene coated lithium battery cathode material, thus improving self-discharge of the whole battery pack, achieving the aim of prolonging the lithium battery storage time and ensuring that the lithium batteries can be stored for a longer time under the condition that users do not charge the electric appliances after using the electric appliances.

Description

technical field [0001] The invention relates to a graphene-coated lithium battery cathode material and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but manganese resources are scarce and expensive And it is toxic, so it has become an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium manganate and layere...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/505H01M4/1391
CPCY02E60/122H01M4/364H01M4/505H01M4/587H01M10/0525Y02E60/10
Inventor 孙琦李岩孙慧英
Owner QINGDAO QIANYUN HIGH TECH NEW MATERIAL
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