Liquid crystal resin composition for camera modules
A resin composition and liquid crystal technology, which are applied in the field of liquid crystal resin compositions and can solve problems such as the reduction of optical properties of camera modules
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[0038] The (A) liquid crystalline resin used in the present invention can be prepared from the above-mentioned monomer compound (or a mixture of monomers) by a known method using a direct polymerization method or an ester exchange method, usually using a melt polymerization method or a slurry polymerization method. Wait. The above-mentioned compounds having ester-forming ability may be used in the polymerization as they are, or may be modified from a precursor to a derivative having the ester-forming ability in the early stage of polymerization. For their polymerization, various catalysts can be used, and typical examples include dialkyltin oxides, diaryltin oxides, titanium dioxide, alkoxytitanosilicates, titanium alkoxides, carboxylic acid Alkali metal salts and alkaline earth metal salts, like BF 3 Such Lewis acid salts etc. The amount of the catalyst used is usually about 0.001 to 1% by mass, particularly preferably about 0.01 to 0.2% by mass, based on the total weight o...
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[0089] The following examples are given to illustrate the present invention in more detail, but the present invention is not limited to these examples.
[0090]
[0091] Liquid crystal resin (liquid crystal polyester amide resin): VECTRA (registered trademark) E950i (manufactured by Polyplastics Co., Ltd.)
[0092] Fibrous filler 1: TISMO N-102 manufactured by Otsuka Chemical Co., Ltd. (potassium titanate fiber, average fiber diameter 0.3-0.6 μm, average fiber length 10-20 μm)
[0093] Fibrous filler 2: Nitto Bosho Co., Ltd. make PF70E-001 (ground glass fiber, fiber diameter 10 μm, weight average length 70 μm)
[0094] Non-fibrous filler 1: Crown Talc PP manufactured by Matsumura Sangyo Co., Ltd. (talc, average particle diameter 12.8 μm, average aspect ratio 6)
[0095] Non-fibrous filler 2: AB-25S manufactured by Yamaguchi Mica Industry (mica, average particle diameter 24 μm)
[0096] Non-fibrous filler 3: A-41S manufactured by Yamaguchi Mica Industry (Mica, average parti...
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