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Semi-solid rheological squeeze casting forming method of flame retardant magnesium alloy

A semi-solid rheological and squeeze casting technology, which is applied in the field of semi-solid rheological squeeze casting of flame-retardant magnesium alloys, can solve the problem of difficulty in obtaining parts with complete shapes, increased viscosity of magnesium alloy melt, and influence on the mechanical properties of alloys and other problems, to achieve the effect of strong practicability of the process, reduction of oxidation loss, and improvement of utilization rate

Inactive Publication Date: 2014-08-27
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These processes mainly have two deficiencies: one is that when pouring at high temperature, the crystal grains are coarse, and a coarse network second phase is formed at the grain boundary, which seriously affects the mechanical properties of the alloy; the other is that after adding Ca element, the viscosity of the magnesium alloy melt increases. Large, difficult to fill, difficult to obtain parts with complete shape
Therefore, the use of semi-solid rheo-squeeze casting to prepare Ca-containing flame-retardant magnesium alloys has a good application prospect, but there is no semi-solid rheo-squeeze casting method suitable for flame-retardant magnesium alloys.

Method used

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  • Semi-solid rheological squeeze casting forming method of flame retardant magnesium alloy
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  • Semi-solid rheological squeeze casting forming method of flame retardant magnesium alloy

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Embodiment 1

[0033] This embodiment relates to a flame-retardant magnesium alloy obtained by adding metal Ca to an AZ91 alloy ingot, wherein the mass fraction of Ca is 1.5%.

[0034] The preparation method of the fire-resistant magnesium alloy includes three process steps of smelting, preparation of semi-solid slurry and subsequent extrusion casting.

[0035] Among them, the previous smelting process is in SF6 and CO 2 Under the condition of mixed gas protection, the specific steps are: put the dried AZ91 alloy ingot into the SF 6 / CO 2 Melt in a gas-protected crucible resistance furnace, add Ca at 700°C after the alloy is melted, refine and remove slag at 730°C, and cool the melt down to 610-630°C.

[0036] The subsequent semi-solid slurry preparation process is: use a quantitative scoop to extract the magnesium alloy liquid at 610-630°C, then put the blowing device into the magnesium alloy liquid for blowing and stirring, and prepare it into a semi-solid slurry. Among them, the air bu...

Embodiment 2

[0040] This embodiment relates to a flame-retardant magnesium alloy obtained by adding metal Ca to an AM50 alloy ingot, wherein the mass fraction of Ca is 3.0%.

[0041] The preparation method of the fire-resistant magnesium alloy includes three process steps of smelting, preparation of semi-solid slurry and subsequent extrusion casting.

[0042] Among them, the previous smelting process is in SF 6 and CO 2 Under the condition of mixed gas protection, the specific steps are: put the dried AM50 alloy ingot into SF 6 / CO 2 Melt in a gas-protected crucible resistance furnace, add Ca at 700°C after the alloy is melted, refine and remove slag at 730°C, and cool the melt down to 610-630°C. The subsequent semi-solid slurry preparation process is: use a quantitative scoop to extract the magnesium alloy liquid at 610-630°C, then put the blowing device into the magnesium alloy liquid for blowing and stirring, and prepare it into a semi-solid slurry. Among them, the air bubble flow r...

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Abstract

The invention discloses a semi-solid rheological squeeze casting forming method of flame retardant magnesium alloy. The method includes the steps of the early processes of conventional melting, refining and slagging-off and two subsequent technological processes of semi-solid slurry preparation and semi-solid rheological squeeze casting; the semi-solid slurry preparation is achieved through imposing air bubble to flame retardant magnesium alloy melt to be stirred, and then squeeze casting forming is conducted on the obtained semi-solid slurry. Through the method, the semi-solid rheological squeeze casting forming of the flame retardant magnesium alloy is achieved, a primary phase and a secondary phase in the flame retardant magnesium alloy can be refined respectively, the casting overall organization is dense, the casting surface is high in quality, and the mechanical property and the surface quality of a product are greatly improved; the pouring temperature is decreased from 700 DEG C in a traditional process to about 600 DEG C, energy consumption can be lowered, impact to a mould is decreased, oxidation losses of magnesium alloy materials are lowered, and the utilization rate of the materials is improved.

Description

technical field [0001] The invention belongs to the technical field of semi-solid forming of metal materials, and in particular relates to a semi-solid rheological extrusion casting forming method of a flame-retardant magnesium alloy. Background technique [0002] Flame-retardant magnesium alloy is a hot spot in the field of magnesium alloy research. By adding a certain amount of flame-retardant alloy elements to magnesium alloy, it can inhibit the severe oxidation and combustion of magnesium alloy, and realize direct smelting and processing under atmospheric conditions. At present, the commonly used flame retardant alloying elements in magnesium alloy research include Ca, Be and rare earth elements. Ca is a commonly used alloying element in magnesium alloys. The research results on the flame retardant effect of Mg-Ca binary alloys show that the ignition point of magnesium alloys containing 1wt% Ca can be increased by 250 ° C; The oxide film is thin and the surface is smoot...

Claims

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Application Information

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IPC IPC(8): B22D17/00
Inventor 张扬吴国华刘文才张亮张鹏丁文江
Owner SHANGHAI JIAO TONG UNIV
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