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Special nano zirconium dioxide composite powder material for glass reflective insulation paint

A reflective thermal insulation coating, nano-zirconia technology, applied in the direction of reflection/signal coating, polyurea/polyurethane coating, coating, etc., can solve the problem of difficult to prepare high-performance nano-zirconia-titania glass reflective thermal insulation coating, Good dispersion and other issues

Active Publication Date: 2014-04-23
山东广通新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It is difficult to prepare high-performance nano-zirconia-titania glass reflective heat-insulating coating, so that it can still maintain a nano-scale state in the coating
[0013] 3. The zirconia-titanium oxide composite nano-powder material product specially used for glass reflective heat insulation coatings with good dispersion and excellent performance has not been seen yet

Method used

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  • Special nano zirconium dioxide composite powder material for glass reflective insulation paint
  • Special nano zirconium dioxide composite powder material for glass reflective insulation paint
  • Special nano zirconium dioxide composite powder material for glass reflective insulation paint

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0085] Prepare the nano zirconia composite powder material dedicated to the glass reflective heat insulation coating of the present invention according to the following operation steps

[0086] ①. Solution A is zirconium oxychloride ZrOCl 2 .8H 2 Preparation of O absolute ethanol solution

[0087] First preparation concentration is 2000 milliliters of dehydrated ethanol solutions of zirconium oxychloride of 0.5mol / L, then in prepared solution, adding molecular weight is 12 grams of polyethylene glycols of 2000, stirs;

[0088] ②. Solution B is the preparation of absolute ethanol solution of butyl titanate

[0089] First prepare 2325 milliliters of absolute ethanol solution of butyl titanate with a concentration of 0.3 mol / L, then add 13 grams of triethanolamine to the prepared solution, and stir evenly;

[0090] ③. Prepare the aqueous ammonium bicarbonate solution whose molar concentration is 2.0mol / L;

[0091] ④. Preparation of mixed sol

[0092] First, under stirring co...

Embodiment 2

[0099] According to the method and step of embodiment 1, concrete formula, processing condition are as follows:

[0100] Prepare 2000ml of 1.5mol / L zirconium oxychloride absolute ethanol solution, add 21g polyethylene glycol, and stir evenly; prepare 1265ml0.5mol / L butyl titanate solution with absolute ethanol as solvent, and add 11g of triethanolamine, stirred evenly; prepare an aqueous ammonium bicarbonate solution with a molar concentration of 1.0mol / L; mix the prepared a and b solutions under stirring conditions, and spray the ammonium bicarbonate aqueous solution to the The mixed solution of a and b in the stirring state, the reaction temperature is 70°C, spray until the final pH value is 7-8, stop adding, continue to stir for 7 hours, age for 15 hours, filter and wash; the drying process uses isobutanol as an azeotrope agent, the azeotropic point is 89.9°C, after dehydration is completed, the temperature of the system rises to the boiling point of isobutanol of 108.4°C, ...

Embodiment 3

[0104] According to the method and step of embodiment 1, concrete formula, processing condition are as follows:

[0105] Prepare 2000ml of 1.0mol / L zirconium oxychloride absolute ethanol solution, add 35g polyethylene glycol, and stir evenly; prepare 1350ml0.8mol / L butyl titanate solution with absolute ethanol as solvent, and add 8g of triethanolamine, stirred evenly; prepare an aqueous ammonium bicarbonate solution with a molar concentration of 3.0mol / L, the reaction temperature is 40°C, mix the prepared a and b solutions under stirring conditions, and pass the aqueous ammonium bicarbonate solution through After spraying and atomizing, spray to the mixed solution of a and b in the stirring state, the reaction temperature is 60°C, spray until the final pH value is 7-8, stop adding, continue stirring for 8 hours, age for 13 hours, filter and wash; the drying process uses N-butanol is the entrainer, and the azeotropic point is 93°C. After dehydration, the temperature of the syst...

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Abstract

The invention relates to a special nano zirconium dioxide composite powder material for glass reflective insulation paint, belonging to the field of manufacturing of metal oxide ultrastructures. The material is characterized by comprising the following chemical components in percentage by mass: 70-90% of zirconium dioxide (ZrO2) and 10-30% of titanium dioxide (TiO2). The preparation method comprises the following steps: continuously spraying an atomized ammonium bicarbonate water solution into an anhydrous ethanol solution (which is prepared by respectively preparing zirconium oxychloride (ZrOCl2.8H2O) and tetrabutyl titanate and mixing evenly) in a stirring state to react to obtain a mixed sol, carrying out azeotropic dehydration on the mixed sol by using butanol as an azeotrope former to obtain a dry material, and calcining to obtain the special nano zirconium dioxide composite powder material for glass reflective insulation paint, of which the particle size is 30-50nm and the specific area is greater than or equal to 30 m<2> / g. The invention provides a high-activity high-dispersity high-stability special nano zirconium dioxide composite powder material for glass reflective insulation paint, and a preparation method and application method thereof. The sunlight reflectance of the prepared paint for white is up to 0.85; and the hemispherical emittance is up to 0.85.

Description

technical field [0001] The invention is a nano-zirconia composite powder material specially used for glass reflective and heat-insulating coatings. It belongs to the manufacture of metal oxide ultramicrostructure. Background technique [0002] Saving energy and protecting the environment is a crucial issue for the sustainable development of the world economy and even human life. According to statistics, building energy consumption accounts for 30% to 40% of the total human energy consumption. The energy is mainly used for heating and cooling electricity consumption in the building. [0003] The door and window glass of a building can provide indoor ventilation, light transmission, outdoor perception, noise blocking and other functions, so it is an important component that must be installed in buildings, vehicles, and engine rooms. [0004] Nanoparticles are aggregates composed of a small number of molecules or atoms. They are between macroscopic substances and microscopic...

Claims

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Application Information

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IPC IPC(8): C09D7/12C09D5/33C09D133/00C09D133/08C09D133/04C09D175/04C09D175/08
Inventor 尹海顺房永民李园园刘良良王淑占
Owner 山东广通新材料有限公司
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