Catalytic cracking catalyst and preparation method thereof

Abstract

The invention relates to a catalytic cracking catalyst and a preparation method. The catalytic cracking catalyst contains a cracking activity component, a mesoporous silicon-aluminum material, clay and an adhesive, wherein the cracking activity component comprises a rare-earth Y-type molecular sieve; and the rare-earth content in the Y-type molecular sieve is 10-25 wt% on the basis of rare-earth oxides, the cell constant is 2.440-2.472nm, the crystallinity is 35-65%, the silicon / aluminum atomic ratio in the framework is 2.5-5.0, and the product of the ratio (I1 / I2) of 2theta=11.8+ / -0.1 degree peak intensity I1 to 2theta=12.3+ / -0.1 degree peak intensity I2 in an X-ray diffraction pattern and the rare-earth weight percent in the molecular sieve on the basis of rare-earth oxides is greater than 50. The preparation method comprises the following steps: preparing a mixed slurry containing the cracking activity component, mesoporous silicon-aluminum material, adhesive and clay, and carrying out spray drying. Compared with the prior art, the rare-earth-containing Y-type molecular sieve is matched with the mesoporous silicon-aluminum material, so that the catalyst has higher thermal and hydrothermal stability and higher heavy oil cracking capacity, and can reduce the consumption of the molecular sieves in the catalyst, thereby lowering the catalyst production cost.

Description

Background technique [0001] Catalytic cracking (FCC) is an important secondary processing process of crude oil and occupies a pivotal position in the oil refining industry. In the catalytic cracking process, heavy fractions such as vacuum distillate oil or residues of heavier components react in the presence of catalysts and are converted into high value-added products such as liquefied gas, gasoline, and diesel oil. In this process, it is usually necessary to use Catalytic material with high cracking activity. Microporous zeolite catalytic materials are widely used in petroleum refining and processing industries due to their excellent shape-selective catalytic performance and high cracking reactivity. Among them, Y-type molecular sieve has been the main active component of catalytic cracking catalyst since it was first used in the 1960s. Especially the Y-type molecular sieve modified by rare earth has a significant effect on improving the acidity and structural stability of...

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Problems solved by technology

[0011] In the prior art, regardless of the rare earth Y molecular sieve obtained by the double-cross-two-baking process or the one-cross-one-baking process, the rare earth content in the product is always lower than the total rare earth amount input, such as CN1053808A, CN1069553C, several disclosed in CN1026225C All kinds of rare earth Y molecular sieves have this feature. Even if more rare earth ions are located in the small cages, it is inevitable that some rare earth ions still exist in the supercages, and the rare earth ions in the supercages will be washed in the subsequent washing process. It is backwashed down, resulting in the loss of rare earths, resulting in a decrease in the utilization rate of rare earths

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