Conducting film combined by graphene and metal nanowires, preparing method thereof and application for preparing transparent conducting film
A technology of metal nanowires and composite conductive films, applied in the direction of metal/alloy conductors, conductive layers on insulating carriers, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problems of unsatisfactory practical application and high price and cost
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Embodiment 1
[0026] According to the literature (Byeong-Su Kim, et al. ACS Nano 2010, 4, 3861.), graphene was prepared by redox method of graphite, and it was made into 0.0004 mg / mL graphene aqueous dispersion. Copper nanowires were prepared according to literature (Benjamin J.Wiley, et al.Adv.Mater.2010,22,3558; Adv.Mater.2011,23,4798.), and dispersed in 3wt% hydrazine hydrate solution, the concentration 0.01mg / mL.
[0027] Take 250 mL of the above graphene solution (0.0004 mg / mL), add 2 mL of the above copper nanowire hydrazine hydrate dispersion (0.01 mg / mL) into it, and ultrasonically 10 min to fully mix the two. After filtering through an alumina membrane with a pore size of 0.22 μm and a diameter of 47 mm, a graphene / copper nanowire composite conductive film supported by an alumina membrane is obtained, and the weight ratio of graphene and copper nanowires contained therein is 1:0.2.
Embodiment 2
[0029] Take 125mL of the same graphene solution (0.0004mg / mL) in Example 1, add 1mL of the same copper nanowire hydrazine hydrate dispersion (0.01mg / mL) in Example 1, and ultrasonically 10min to make the two fully mix . After passing through a polycarbonate membrane with a pore size of 0.22 μm and a diameter of 25 mm, a graphene / copper nanowire composite conductive film supported by a polycarbonate membrane is obtained, wherein the weight ratio of graphene and copper nanowires is 1:0.2.
Embodiment 3
[0031] The preparation method is basically the same as in Example 2, except that the filter membrane adopts a polytetrafluoroethylene membrane with a pore size of 0.22 μm and a diameter of 25 mm. After ultrasonic compounding, filtration and washing, a graphene / copper nanowire composite conductive film supported by a polytetrafluoroethylene membrane is obtained, wherein the weight ratio of graphene and copper nanowires is 1:0.2.
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