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Method for preparing novel denitration catalyst

A denitrification catalyst, a new type of technology, applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of high raw material cost for carrier manufacturing and increased catalyst preparation cost, etc.

Inactive Publication Date: 2013-08-21
姚光纯
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Although the catalysts currently on the market have good denitrification effects, the problem is that the manufacture of this product requires a large amount of high-quality titanium dioxide materials, vanadium compounds and tungsten compounds. At present, most of the mainstream processes in the world use ammonium metavanadate and metatungstic acid. Ammonium is used as the source material of vanadium pentoxide (vanadium) and tungsten oxide (tungsten) compounds, and its usage is 1.5-2.2% and 5.5-7.5% of the total amount of titanium dioxide, and the carrier is all made of titanium dioxide. The cost of raw materials for carrier manufacturing is high, and the cost of catalyst preparation is increased.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Embodiment 1 Preparation method steps are:

[0029] A, attapulgite 25wt%, bentonite 8%wt%, alumina powder 15wt%, 4A molecular sieve 42wt%, diatomaceous earth 5.5wt% and methyl cellulose 4.5wt% are mixed into powder;

[0030] B. The powder is kneaded, vacuum smelted, stale, extruded, and dried to make a carrier semi-finished product, and then the semi-finished product is fired into a carrier at a temperature of 500°C~700°C with an oxidizing flame in a kiln;

[0031] C. Put ammonium metavanadate and ammonium metatungstate into hot water at a temperature of 88°C at a ratio of 16% by weight of hot water and 8% by weight of hot water, and stir slowly until they are fully dissolved;

[0032] D, take water as solvent, prepare 25% ethanol solution and nitric acid solution of ethanol solution weight 28%, ethanol solution and nitric acid solution are mixed to form mixed solution, then add mixed solution gross weight 24% titanate in mixed solution, Constantly stir the solution to...

Embodiment 2

[0036] Embodiment 2 preparation method steps are:

[0037] A, attapulgite 18wt%, bentonite 5%wt%, alumina powder 30wt%, 4A molecular sieve 41wt%, diatomaceous earth 2.5wt% and methyl cellulose 3.5wt% are mixed into powder;

[0038] B. The powder is kneaded, vacuum smelted, stale, extruded, and dried to make a carrier semi-finished product, and then the semi-finished product is fired into a carrier at a temperature of 500°C~700°C with an oxidizing flame in a kiln;

[0039] C. Put ammonium metavanadate and ammonium metatungstate into hot water at a temperature of 86°C at a ratio of 5% by weight of hot water and 25% by weight of hot water, and stir slowly until they are fully dissolved;

[0040] D. Using water as a solvent, prepare 78% ethanol solution and 10% carboxylic acid solution by weight of the ethanol solution, mix the ethanol solution and carboxylic acid solution to form a mixed solution, and then add 12% titanic acid by total weight of the mixed solution to the mixed so...

Embodiment 3

[0048] Embodiment 3 preparation method steps are:

[0049] a, attapulgite 12wt%, bentonite 15%wt%, alumina powder 10wt%, 4A molecular sieve 53wt%, diatomite 9wt% and hydroxypropyl methylcellulose 1wt% are mixed into powder;

[0050] b. Weigh 20% of the weight of the powder in deionized water and heat it to 83°C, and maintain this temperature;

[0051] c. Weigh 1.8% and 4% ammonium metavanadate and ammonium metatungstate, respectively, of the weight of the powder that removed the weight of the auxiliary agent in step a, add them to the hot water in step b, and keep stirring to make them fully dissolve. into solution;

[0052] d. Add the powder obtained in step a and the solution obtained in step c into the kneader, stir for 1-2 hours, then heat and vacuumize to make mud;

[0053] e. Send the mud made in step d into the stale room to seal and stale for 24 hours. When stale, control the relative humidity of the environment at 70-75%, and the temperature at 20-30°C;

[0054] f....

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Abstract

The invention discloses a method for preparing a novel denitration catalyst. The method comprises the steps of: mixing 10-40wt% of attapulgite, 0.5-15wt% of bentonite, 10-35wt% of alumina powder, 40-70wt% of 4A molecular sieve, 0.5-10wt% of kieselguhr and 0.5-10wt% of assistant into powder; molding in water mediating and extruding manners and firing a carrier by a high-temperature flame; feeding ammonium metavanadate and metatungstic acid into hot water of which the temperature is not less than 85 DEG C; mixing an ethanol solution with an acid solution to form a mixing solution; adding titanate which is 5-30% of total weight of the mixing solution to the mixing solution, soaking the carrier in steeping liquor; and baking the dried carrier and preparing into the denitration catalyst. The carrier is prepared from a cheap material instead of an expensive titanium dioxide material through reasonable prescription combination; good and stable mechanical strength, 30-70% of water absorption and 20-80 m<2> / g of specific surface area of the catalyst carrier can be ensured by changing the material of the carrier; and the preparation cost can be reduced by 20-50% under the condition of keeping the catalytic effect.

Description

technical field [0001] The invention relates to a preparation method of a catalyst, in particular to a preparation method of a denitrification catalyst. Background technique [0002] While enjoying the huge achievements brought about by the rapid development of industry, we are also deeply hurt by environmental pollution. In response to the serious challenge of environmental pollution, most countries in the world have taken relevant measures to improve the environment. my country's Twelfth Five-Year Plan has also clearly issued energy-saving and emission-reduction goals, and stricter control over industrial exhaust gas, especially toxic gases. It clearly stipulates that high-emission and high-polluting enterprises such as steel plants, coal power plants, and cement plants must bear responsibility for environmental pollution. Responsibility for pollution and duty to improve the environment. [0003] Iron and steel, thermal power generation, cement and other industries emit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/30B01J23/22B01J37/00B01D53/86B01D53/56
Inventor 姚光纯张金云李付林
Owner 姚光纯
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