Decoking and coal-saving additive for supercritical or super-supercritical boiler

A technology for ultra-supercritical boilers and coal-saving additives, applied in fuel additives, petroleum industry, solid fuels, etc., can solve problems such as coking of thermal power generation units, achieve low environmental pollution, improve use safety, and have good decoking effects Effect

Active Publication Date: 2013-07-24
湖南省湘电试验研究院有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to provide a coke-removing and coal-saving additive for supercritical or ultra-supercritical boilers with little corrosion to metal materials, no pollution to the environment, easy to use, and low cost, so as to solve the problem of supercritical or ultra-supercritical firepower. Generator set coking problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Mix the following ingredients by weight percentage:

[0024] Magnesium nitrate 8.5%, copper nitrate 5.0%, ammonium chloride 6.0%, ammonium bicarbonate 1.2%, boric acid 2.3%, sodium dodecylsulfonate 1.5, water-soluble modified nano-ceramic powder 1.2%, stabilizer 1.2 %, the balance is water.

Embodiment 2

[0026] Mix the following ingredients by weight percentage:

[0027] Magnesium nitrate 9.5%, copper nitrate 5.6%, ammonium chloride 6.6%, ammonium bicarbonate 1.7%, boric acid 2.5%, sodium dodecylsulfonate 1.6%, water-soluble modified nano-ceramic powder 1.6%, stabilizer 1.4%, the balance is water.

Embodiment 3

[0029] Mix the following ingredients by weight percentage:

[0030] Magnesium nitrate 10.8%, copper nitrate 6.2%, ammonium chloride 7.5%, ammonium bicarbonate 1.9%, boric acid 3.0%, sodium dodecylsulfonate 1.8%, water-soluble modified nano-ceramic powder 2.4%, stabilizer 1.7%, the balance is water.

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PUM

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Abstract

The invention discloses a decoking and coal-saving additive for a supercritical or super-supercritical boiler. The additive comprises the components in percentage by weight as follows: 8.5-12.3% of magnesium nitrate, 5.0-7.2% of cupric nitrate, 6.0-8.5% of ammonium chloride, 1.2-2.5% of ammonium bicarbonate, 2.3-3.6% of boric acid, 1.5-2.0% of sodium dodecyl sulfate, 1.2-2.8% of modified nano ceramic powder dissolved in water, 1.2-2.2% of stabilizer and the balance of water. The additive provided by the invention has the advantages that 1, the additive is simple to operate and small in use level; 2, the decoking effect is good, and coke blocks can be quickly smashed; 3, the additive is less in environmental pollution, less in heavy metal salt content and less in smoke carried and generated by combustion and heavy metal; 4, the using safety of the boiler can be improved, and after coking of the boiler, the additive is quickly used to effectively prevent tube explosion of the boiler, and meanwhile to prevent large coking blocks from falling into a submerged chain conveyor to lead to major accident of chain breakage of the submerged chain conveyor; and 5, the additive is safe and non-toxic and does not harm the human body.

Description

technical field [0001] The invention belongs to coal additives, in particular to a coke-removing and coal-saving additive for supercritical or ultra-supercritical boilers. Background technique [0002] Due to large capacity, high parameters, high thermal efficiency and environmental protection, more and more supercritical or ultra-supercritical thermal power generating units have been put into construction or operation. However, due to the influence of various factors such as unit combustion conditions and coal quality, severe coking and ash deposition are prone to occur in actual operation. Boiler coking will increase the thermal resistance of water-cooled wall tubes, and in severe cases, tube burst accidents will occur. [0003] At present, domestic supercritical or ultra-supercritical generating units generally solve the problem of coking by combining manual decoking or soot blowing. However, the above methods cannot play an effective role when the coking is serious. D...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L9/10C10L10/00
Inventor 郭新茹张玉福何铁祥冯斌刘凯徐松
Owner 湖南省湘电试验研究院有限公司
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