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Synthetic resin for water-soluble printing ink and preparation method thereof

A synthetic resin and water-soluble technology, which can be used in inks, applications, household utensils, etc., can solve the problems of slow drying, volatile pollution, poor wetting and dispersibility of pigments, etc., and achieve convenient and easy raw materials, low preparation costs, and high adhesion strength Effect

Inactive Publication Date: 2013-05-29
贺红专 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Plastic gravure printing ink is a coloring material for plastic packaging printing. It is a liquid substance processed by grinding and other processes. The performance of the resin determines the type of ink solvent and determines the ink. Printability, pigment dispersibility, adhesion fastness, etc. For a long time, my country's plastic gravure ink is mainly composed of benzene and other organic soluble synthetic resins. The ink contains a large amount of benzene and other organic solvents, so the manufacturing of ink , There are volatilization pollution of benzene solvent and other organic solvents in the process of use, which endangers the health of producers and consumers
What's more serious is that the benzene and other organic solvents left on the packaging bags pollute articles and food, and are very harmful to people's lives and health.
In recent years, although water-based plastic gravure inks and other types of inks have appeared in the market, there are problems such as high prices, poor wetting and dispersibility of pigments, slow drying, and poor adhesion fastness, which have affected the popularization and use of such products.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The amount of raw materials used in the preparation of synthetic resin for water-soluble ink: 210 kg of turpentine, 290 kg of butyl acrylate, 70 kg of methyl methacrylate, 350 kg of vinyl acetate, 50 kg of hydroxyethyl acrylate, 30 kg of acrylic acid, persulfuric acid Potassium 4.8 kg, catalyst: 5.5 kg of a mixture of benzyl chloride and aluminum chloride (mass ratio 1: 1).

[0029] The concrete preparation steps of synthetic resin for water-soluble ink are as follows:

[0030] 1. Terpene Prepolymer Preparation

[0031] [1] Catalyst is joined in the mixed solvent that is made up of 36kg ethyl acetate and 4kg toluene, mixes;

[0032] [2] turpentine and the mixed solvent that is made up of 162kg ethyl acetate and 18kg toluene are dropped into reactor, stir;

[0033] [3] When the temperature of the reactor reaches 5°C, add the catalyst solution obtained in step [1] into the reactor, keep the temperature of the reactor not exceeding 15°C, and react for 3 hours;

[0034] ...

Embodiment 2

[0040] The amount of raw materials used in the preparation of synthetic resin for water-soluble ink: 180 kg of turpentine, 380 kg of butyl acrylate, 100 kg of methyl methacrylate, 270 kg of vinyl acetate, 40 kg of glycidyl acrylate, 30 kg of acrylic acid, persulfuric acid Potassium 5.1 kg, catalyst: 4.8 kg of a mixture of benzyl chloride and aluminum chloride (mass ratio 1: 1).

[0041] The concrete preparation steps of synthetic resin for water-soluble ink are as follows:

[0042] 1. Terpene Prepolymer Preparation

[0043] [1] Catalyst is joined in the mixed solvent that is made up of 36kg ethyl acetate and 4kg toluene, mixes;

[0044] [2] turpentine and the mixed solvent that is made up of 135kg ethyl acetate and 18kg toluene are dropped into reactor, stir;

[0045] [3] When the temperature of the reactor reaches 10°C, add the catalyst solution obtained in step [1] into the reactor, keep the temperature of the reactor not exceeding 15°C, and react for 3 hours;

[0046] [4...

Embodiment 3

[0052]The amount of raw materials used in the preparation of synthetic resin for water-soluble ink: 190 kg of turpentine, 330 kg of butyl acrylate, 80 kg of styrene, 330 kg of vinyl acetate, 30 kg of methacrylic acid, 40 kg of tertiary vinyl ester (Shell) , 5.2 kg of potassium persulfate, catalyst: 4.8 kg of a mixture of benzyl chloride and aluminum chloride (mass ratio 1: 1).

[0053] The concrete preparation steps of synthetic resin for water-soluble ink are as follows:

[0054] 1. Terpene Prepolymer Preparation

[0055] [1] Catalyst is joined in the mixed solvent that is made up of 36kg ethyl acetate and 4kg toluene, mixes;

[0056] [2] turpentine and the mixed solvent that is made up of 144kg ethyl acetate and 16kg toluene are dropped into reactor, stir;

[0057] [3] When the temperature of the reactor reaches 10°C, add the catalyst solution obtained in step [1] into the reactor, keep the temperature of the reactor not exceeding 15°C, and react for 3 hours;

[0058] [4]...

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PUM

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Abstract

The invention belongs to the field of synthetic resin and provides synthetic resin for water-soluble printing ink. The synthetic resin is prepared from 15-21 parts of turpentine oil, 15-45 parts of butyl acrylate, 7-15 parts of methyl methacrylate or styrene, 20-35 parts of vinyl acetate and 6-12 parts of active functional group monomer. A preparation method comprises the following steps of: reacting the turpentine oil under the effect of a mixed catalyst of benzyl chloride and aluminum chloride to obtain a terpene prepolymer; making the terpene prepolymer into an emulsion; adding butyl acrylate, methyl methacrylate, vinyl acetate and part of the active functional group monomer into the terpene prepolymer emulsion; adding part of an initiator and the remaining monomer mixture at 60-80 DEG C, and reacting for 10-20 minutes; adding the remaining initiator and heating to 90-95 DEG C for reaction; and cooling to obtain the synthetic resin for water-soluble printing ink.

Description

technical field [0001] The invention belongs to the field of synthetic resins, in particular to a synthetic resin for water-soluble ink and a preparation method thereof. Background technique [0002] Plastic gravure printing ink is a coloring material for plastic packaging printing. It is a liquid substance processed by grinding and other processes. The performance of the resin determines the type of ink solvent and determines the ink. Printability, pigment dispersibility, adhesion fastness, etc. For a long time, my country's plastic gravure ink is mainly composed of benzene and other organic soluble synthetic resins. The ink contains a large amount of benzene and other organic solvents, so the manufacturing of ink , In the process of use, there is volatilization pollution of benzene solvent and other organic solvents, which is harmful to the health of producers and consumers. What is more serious is that benzene and other organic solvents remaining on the packaging bags poll...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F277/00C08F220/18C08F220/14C08F218/08C08F212/08C08F2/30C08F2/26C09D11/10C09D11/107
Inventor 贺红专贺媛
Owner 贺红专
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