Application of Te/TeO2-SiO2 composite film as optical limiting material
A composite film and optical limiting technology, which is applied in the field of Te/TeO2-SiO2 composite film, can solve the problem that the optical limiting properties of tellurium-based composite films are rarely reported.
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Embodiment 1
[0020] Te / TeO of Example 1 2 -SiO 2 Composite thin film is SiO 2 The particles are embedded with TeO 2 And / or the composite film of Te, its preparation method comprises the following steps:
[0021] a. Preparation of TeO 2 -SiO 2 Transparent composite sol; TeO 2 -SiO 2 The transparent composite sol is prepared by mixing tellurium isopropoxide, ethyl orthosilicate, isopropanol, ethanol, water, hydrochloric acid and ethylene glycol;
[0022] b. TeO 2 -SiO 2 The transparent composite sol is electrochemically induced by constant potential at -0.4V to form a composite film on the working electrode, and the preparation time is 100s; the working electrode is ITO, the large-area Pt sheet is the auxiliary electrode, and the saturated calomel electrode is the reference electrode;
[0023] c. Slowly remove the working electrode with the gel membrane out of the electrolytic cell, absorb the excess sol with filter paper at the edge of the base, and dry the film at room temperature...
Embodiment 2
[0025] The difference between embodiment 2 and embodiment 1 is: the Te / TeO of embodiment 2 2 -SiO 2 The preparation voltage of the composite film is -0.8V.
Embodiment 3
[0027] The difference between embodiment 3 and embodiment 1 is: the Te / TeO of embodiment 3 2 -SiO 2 The preparation voltage of the composite film is -1.2V.
[0028] Select Te / TeO under different preparation voltages 2 -SiO 2 Composite thin film samples are subjected to optical limiting experiments. The optical limiting experiment is to excite the thin film medium by a laser with tunable light intensity. Under low input light intensity, the thin film medium has a high linear transmittance, and the output light passing through the thin film medium The intensity changes approximately linearly with the increase of the input light intensity; under high input light intensity, since the transmittance of the film medium no longer shows a linear change, the transmittance will decrease with the increase of the input light intensity, when the input light intensity reaches After a certain threshold, the output light intensity is limited within a certain range without changing the light...
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