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Application of Te/TeO2-SiO2 composite film as optical limiting material

A composite film and optical limiting technology, which is applied in the field of Te/TeO2-SiO2 composite film, can solve the problem that the optical limiting properties of tellurium-based composite films are rarely reported.

Inactive Publication Date: 2013-03-20
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still few domestic and foreign reports on the optical limiting effect of tellurium-based materials. Indian scholar C.S. Suchand Sandeep et al. conducted research on the optical limiting properties of Te and Ag2Te nanowires, and found that Ag The limiting effect of 2Te nanowires is significantly higher than that of Te nanowires; domestic scholar Li Yuqiong et al. The optical limiting properties of 2:Er2O3 materials were studied, and Er3 doped +Glass material, using a 532nm picosecond laser to measure the change of the output power under different incident powers, it is found that the output power and the incident power are approximately linear when the incident power is low, but when the incident power reaches the threshold of 1.2mW , the output power no longer increases with the increase of the incident power, and the output power tends to a threshold range
[0005] From the above-mentioned domestic and foreign research progress and literature reports, although there have been individual reports on the optical limiting characteristics of tellurium-based materials, the research on tellurium-based composite thin films There are few research reports on the optical limiting characteristics of

Method used

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  • Application of Te/TeO2-SiO2 composite film as optical limiting material
  • Application of Te/TeO2-SiO2 composite film as optical limiting material
  • Application of Te/TeO2-SiO2 composite film as optical limiting material

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Effect test

Embodiment 1

[0020] Te / TeO of Example 1 2 -SiO 2 Composite thin film is SiO 2 The particles are embedded with TeO 2 And / or the composite film of Te, its preparation method comprises the following steps:

[0021] a. Preparation of TeO 2 -SiO 2 Transparent composite sol; TeO 2 -SiO 2 The transparent composite sol is prepared by mixing tellurium isopropoxide, ethyl orthosilicate, isopropanol, ethanol, water, hydrochloric acid and ethylene glycol;

[0022] b. TeO 2 -SiO 2 The transparent composite sol is electrochemically induced by constant potential at -0.4V to form a composite film on the working electrode, and the preparation time is 100s; the working electrode is ITO, the large-area Pt sheet is the auxiliary electrode, and the saturated calomel electrode is the reference electrode;

[0023] c. Slowly remove the working electrode with the gel membrane out of the electrolytic cell, absorb the excess sol with filter paper at the edge of the base, and dry the film at room temperature...

Embodiment 2

[0025] The difference between embodiment 2 and embodiment 1 is: the Te / TeO of embodiment 2 2 -SiO 2 The preparation voltage of the composite film is -0.8V.

Embodiment 3

[0027] The difference between embodiment 3 and embodiment 1 is: the Te / TeO of embodiment 3 2 -SiO 2 The preparation voltage of the composite film is -1.2V.

[0028] Select Te / TeO under different preparation voltages 2 -SiO 2 Composite thin film samples are subjected to optical limiting experiments. The optical limiting experiment is to excite the thin film medium by a laser with tunable light intensity. Under low input light intensity, the thin film medium has a high linear transmittance, and the output light passing through the thin film medium The intensity changes approximately linearly with the increase of the input light intensity; under high input light intensity, since the transmittance of the film medium no longer shows a linear change, the transmittance will decrease with the increase of the input light intensity, when the input light intensity reaches After a certain threshold, the output light intensity is limited within a certain range without changing the light...

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Abstract

The invention relates to new application of a Te / TeO2-SiO2 composite film, namely, the application of the Te / TeO2-SiO2 composite film as an optical limiting material. The Te / TeO2-SiO2 composite film is a composite film in which TeO2 and / or Te is embedded among SiO2 particles and the Te / TeO2-SiO2 composite film is generated by carrying out constant-potential electrochemical induction on transparent TeO2-SiO2 composite sol under -0.1 to -1.5V. According to the invention, optical limiting experiments are carried out by selecting Te / TeO2-SiO2 composite film samples prepared under different voltages, the Te / TeO2-SiO2 composite film is proved to have a better optical limiting property, and the application value of the Te / TeO2-SiO2 composite film in optical limiting is revealed. Therefore, the Te / TeO2-SiO2 composite film can be applied as the optical limiting material and can be applied to an optical limiter.

Description

technical field [0001] The present invention relates to Te / TeO 2 -SiO 2 Use of composite thin films, especially involving Te / TeO 2 -SiO 2 Application of composite thin films as optical limiting materials. Background technique [0002] In the era when laser technology is very developed and laser weapons are becoming more and more mature, laser has been widely used in industrial processing, communication technology, military fields, etc. At the same time, laser has constituted a potential threat to military and civilian optical facilities and human eyes. Inevitable injury and damage to users and optical components. When people realized the seriousness of the problem, they began to study laser protection technology. Although scholars at home and abroad have developed various optical protection methods, relatively speaking, optical limiters have broad-spectrum resistance to variable wavelength lasers. It has many advantages such as easy processing, fast response time, can ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/34
Inventor 辜敏甘平鲜晓东鲜学福
Owner CHONGQING UNIV
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