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Porous particle with functions of adsorbing and biodegrading petroleum hydrocarbon and preparation method of porous particle

A porous particle and biodegradable technology, applied in chemical instruments and methods, biological water/sewage treatment, water pollutants, etc., can solve the problems of long cycle of bioremediation technology, lack of technology and research reports, etc., achieve high treatment efficiency, The effect of simple production process

Inactive Publication Date: 2012-06-20
BEIJING NORMAL UNIVERSITY
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  • Summary
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Problems solved by technology

However, the cycle of bioremediation technology is relatively long, and at the same time, limited by the existence of highly efficient petroleum hydrocarbon degrading bacteria, the physical adsorption method faces the problem of reprocessing the adsorbent after the adsorption is saturated. If the physical adsorption method and biodegradation can be combined It can make up for the deficiencies of the two, and it will have greater advantages in dealing with oil spill pollution in water bodies.
[0004] However, in order to further promote and apply the technology of combining physical adsorption and biodegradation in the treatment of oil spill pollution in water bodies, materials with both physical adsorption and biodegradation functions have been developed, which will help improve the efficiency of oil spill pollution treatment in water bodies, It is of great significance to reduce environmental pollution, but there is still a lack of technology and research reports in this area

Method used

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preparation example Construction

[0013] The invention provides a kind of porous particles with functions of adsorption and biodegradation to petroleum hydrocarbons and a preparation method thereof. Mix 160mL poly-β-hydroxybutyrate chloroform solution with a mass fraction of 8% and 40mL polyoxyethylene chloroform solution to obtain a 200mL mixed solution; add 50mL deionized water dropwise to the above 200mL mixed solution under stirring to obtain a 250mL mixed solution solution, then stirred at 1000r / min for 4min; the obtained 250mL mixed solution was added dropwise to 250mL of polyvinyl alcohol solution with a mass fraction of 3% to obtain a 500mL mixed solution, then stirred at 400r / min for 4min; 1000mL The polyvinyl alcohol solution with a mass fraction of 0.4% was added to the above 500mL mixed solution, and stirred at 400r / min for 7-8h to fully volatilize the solvent and cause poly-β-hydroxybutyrate-polyoxyethylene to undergo a polymerization reaction. Then, centrifugation was carried out under the condit...

Embodiment

[0016] The porous particles with adsorption and biodegradation functions for petroleum hydrocarbons prepared by the method of the present invention have carried out adsorption and biodegradation tests on petroleum hydrocarbons in oil spill polluted water bodies, and the results show that the porous particles can effectively remove petroleum hydrocarbons in water bodies. Adsorption and biodegradation: When the initial concentration of petroleum hydrocarbons in the polluted water body is 66.7mg / L, the concentration of petroleum hydrocarbons in the water can be reduced to 0.01mg / L after 12 hours, and the concentration of petroleum hydrocarbons in the porous particles has not been detected after 14 days.

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PUM

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Abstract

The invention discloses a porous particle with functions of adsorbing and biodegrading petroleum hydrocarbon and a preparation method of the porous particle. Poly-beta-hydroxybutyrate chloroformic solution with mass fraction of 8% and polyoxyethylene chloroformic solution with mass fraction of 8% are mixed according to the proportion of 4:1; deionized water is dripped into the mixed solution according to the proportion of 1:4, and mixture of the deionized water and the mixed solution is stirred for 4 minutes; obtained mixed liquid is dripped into polyvinyl alcohol solution with mass fraction of 0.3% according to the proportion of 1:1, and mixture is stirred for 4 minutes; polyvinyl alcohol solution with mass fraction of 0.4% is added in the mixture according to the proportion of 2:1, the mixture is centrifugally separated after being stirred for 7 hours to 8 hours, and is washed by deionized water for three times, the porous particle is obtained after the mixture is lyophilized; and the porous particle is taken out to be aired after being cultivated in petroleum hydrocarbon degrading bacterium culture solution for 24 hours. The porous particle and the preparation method thereof are simple in process, a prepared porous particle is high in efficiency to treat pollutants of the petroleum hydrocarbon, and an ecological environment of water cannot be polluted secondarily or damaged.

Description

technical field [0001] The invention belongs to the technical field of physical adsorption and biodegradation treatment of oil-spill-polluted water bodies, and in particular relates to a porous particle capable of adsorbing and biodegrading petroleum hydrocarbons and a preparation method thereof. Background technique [0002] In recent years, with the increasing demand for oil and its products in various countries around the world, oil spill accidents have occurred frequently in the process of offshore mining, loading and unloading, transportation and utilization of oil, which not only caused a large amount of crude oil loss, but also caused serious pollution to the environment. It is increasingly threatening the ecological environment of water bodies and land areas, and has long-term harm to water body environment, natural resources and aquaculture resources. Therefore, oil spill pollution in water bodies has become a major environmental problem that people must face. [00...

Claims

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Application Information

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IPC IPC(8): B01J20/26B01J20/28B01J20/30C02F3/34C02F101/30
Inventor 豆俊峰李帅冉程莉蓉丁爱中郑蕾马梦娇王鸿婷
Owner BEIJING NORMAL UNIVERSITY
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