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Inorganic composite conditioner for effective sludge dehydrating

An inorganic composite and sludge dewatering technology, which is applied in the direction of dehydration/drying/concentrated sludge treatment, etc., can solve the problem of high content of organic polymer dehydration conditioner, large dosage of calcium salt or calcium oxide, and increased organic matter content of mud cake and other problems, to achieve the effect of reducing capillary water absorption time, improving sludge dewatering performance, and reducing organic matter content

Active Publication Date: 2012-05-16
UNIVERSTAR SCI & TECH SHENZHEN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the treatment effect is good, the content of organic polymer dehydration conditioner is high, the cost is high, and it is difficult to reuse the dewatered cake
In CN1986788A, the sludge is tempered by adding water first, and then adding iron salt, calcium salt or calcium oxide step by step. Although the dehydration effect is still good, the dosage of calcium salt or calcium oxide is too large, and the mud cake is highly alkaline.
The sludge dewatering agent disclosed in CN101100345A is aimed at dewatered sludge with a water content of about 80%, and the surface active ion dispersant is as high as 5%, and the surfactant in the filtrate will inevitably increase, causing secondary pollution
The composition of composite filter aid in CN101182095A includes as many as 9 kinds, and the preparation process is complicated
The disadvantage is that the dosage is too large, which is 5-20% of the mass of the water-containing sludge, which will inevitably lead to a large increase in sludge volume.
CN101693593A The organic matter content of the mud cake produced by the conditioning method is about 10% higher than that of the mud cake with iron salt and calcium oxide as dehydrating agents, which is not conducive to subsequent disposal methods such as landfill
[0005] First, the dewatered sludge with a water content of 80% is used as the treatment object. Although it meets the actual operation needs of the current sewage treatment plant, in the long run, adding 60% to 70% of the water to the dewatered sludge is used for conditioning. The treatment process is complicated, wastes water resources, and is not conducive to energy saving and emission reduction;
[0006] Second, the conditioning agent has both organic and inorganic components, which increases the organic matter content of the mud cake, which is not conducive to being used as a landfill covering material or to prepare building materials;
[0007] Third, the dosage of the agent is too large, resulting in a large increase in the size of the mud cake

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Concentrated sludge with a moisture content of 96.8% is taken from an urban sewage treatment plant. The raw material components and percentage weight ratio of the inorganic composite conditioner are: FeCl 3 4.3%, fly ash 63.8%, quicklime 32.1%. The total dosage is 4.7% of the wet sludge (based on a moisture content of 97%).

[0035] The conditioning and dehydration method is: first add FeCl to the sludge according to the above formula 3 Solution, stir rapidly for 0.5min, then add fly ash, stir slowly for 5min, finally add quicklime, stir slowly for 5min. The adjusted sludge specific resistance is 1.89×10 7 the s 2 / g, the CST drops to 6.7s.

Embodiment 2

[0037] Thickened sludge with a water content of 96.7% is taken from an urban sewage treatment plant. The raw material components and percentage weight ratio of the inorganic composite conditioner are: FeCl 32.2%, fly ash 65.2%, quicklime 32.6%. The total dosage is 4.6% of the wet sludge (based on a moisture content of 97%).

[0038] The conditioning and dehydration method is: first add FeCl to the sludge according to the above formula 3 Solution, stir rapidly for 0.5min, then add fly ash, stir slowly for 3min, finally add quicklime, stir slowly for 5min. The adjusted sludge specific resistance is 4.60×10 7 the s 2 / g, the CST drops to 6.6s.

Embodiment 3

[0040] Take concentrated sludge from urban sewage treatment plant, its water content is 96.7%, and its specific resistance is 2.37×10 9 the s 2 / g, CST is 15.7. The raw material components and percentage weight ratio of the inorganic composite conditioner are: FeCl 3 2.4%, magnesite 58.6%, quicklime 39.0%. The total dosage is 2.05% of the wet sludge (based on a moisture content of 97%).

[0041] The conditioning and dehydration method is: first add FeCl to the sludge according to the above formula 3 Solution, stir rapidly for 0.5min, then add magnesite, stir slowly for 5min, finally add quicklime, stir slowly for 5min. The specific resistance drop of the conditioned sludge is 1.59×10 8 the s 2 / g, CST reduced to 7.2s.

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Abstract

The invention discloses an inorganic composite conditioner for effective sludge dehydrating, comprising an inorganic high valent cation coagulant, quicklime and inorganic powder fine aggregate, wherein the weight percentages are as follows: 2-10% of the inorganic high valent cation coagulant, 30-50% of quicklime and 40-67% of inorganic powder fine aggregate. The invention also discloses a use method for the inorganic composite conditioner. The conditioner disclosed by the invention can obviously lower specific resistance of sludge (SRF) and capillary suction time (CST) so as to large raise the sludge dehydrating performance. In addition, the drugs of the conditioner are cheap, and the organic contents of the sludge cake after dehydrating are low, and the inorganic material compositions in the conditioner are helpful for forming the strength during the subsequent preparation of backfilling mulching soil and building materials, and the sludge cake after dehydrating can be used as a raw material for preparing the backfilling mulching materials and the building materials.

Description

technical field [0001] The invention relates to sludge treatment technology, in particular to an inorganic composite conditioner for treating sludge with a water content as high as about 97%. Background technique [0002] The sludge produced by urban sewage treatment plants with a moisture content of about 97% is a hydrophilic organic aggregate mainly composed of extracellular polymers (ECP). Regular, non-uniform height, extremely high specific surface area and porosity (porosity is often greater than 99%); high organic content, easy to rot and smell; fine particles, small specific gravity; high moisture content, not easy to dehydrate. The current dehydration technology generally adopts polyacrylamide (PAM) flocculant conditioning and then undergoes mechanical dehydration, and only mud cakes with a moisture content of about 80% can be obtained. Generally, thermal drying technology with high energy consumption and high operating cost is required to further dewater deeply to ...

Claims

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Application Information

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IPC IPC(8): C02F11/14
Inventor 杨家宽何姝王荣刘欢时亚飞李亚林
Owner UNIVERSTAR SCI & TECH SHENZHEN
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