Mold release composition and surface protective film
A technology of surface protection film and composition, which is applied in the direction of photoplate making process, coating, instrument, etc. on the patterned surface, and can solve the problems such as the decrease of exposure accuracy
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Embodiment 1
[0056] The coating solution containing the release composition of the following composition was applied to one surface of a transparent polymer film (LUMIRROR: Toray) with a thickness of 6 μm by the bar coating method, and heated and cured at 120°C for 5 minutes to form A coating film with a thickness of about 0.5μm. Furthermore, the coating liquid for an adhesive layer of the following composition was apply|coated on the other surface, and it dried, and the adhesive layer of thickness about 4 micrometers was formed, and the surface protection film of Example 1 was produced. In order to facilitate the operation, a 25 μm-thick polyethylene terephthalate release film (MRB: Mitsubishi Chemical Polyester Film Co., Ltd.) was attached to the adhesive layer.
[0057]
[0058] ·Binder resin 1.85 parts
[0059] (ES-1002T: Shin-Etsu Chemical Co., Ltd., solid content 60%)
[0060] ·0.05 parts of silicone oil with alkoxy groups at the end
[0061] (X-22-1968: Shin-Etsu Chemical Co., Ltd., solid...
Embodiment 2
[0074] The surface protection film of Example 2 was prepared in the same manner as in Example 1, except that the coating liquid containing the releasable composition used in Example 1 was replaced with the coating liquid containing the releasable composition of the following composition.
[0075]
[0076] ·Binder resin 1.85 parts
[0077] (ES-1002T: Shin-Etsu Chemical Co., Ltd., solid content 60%)
[0078] 0.02 parts of silicone oil with alkoxy groups at the end
[0079] (X-22-1968: Shin-Etsu Chemical Co., Ltd., solid content 100%)
[0080] ·Silanolate condensate 2.22 parts
[0081] (X-40-2308: Shin-Etsu Chemical Co., Ltd., 100% active ingredient)
[0082] ·Curing agent 0.1 part
[0083] (Titanium-based chelate, 100% active ingredient)
[0084] ·Silane coupling agent 0.3 parts
[0085] (100% active ingredients)
[0086] · 9.64 parts of solvent
Embodiment 3
[0088] The surface protection film of Example 3 was prepared in the same manner as in Example 1, except that the coating liquid containing the releasable composition used in Example 1 was replaced with the coating liquid containing the releasable composition of the following composition.
[0089]
[0090] ·Binder resin 1.85 parts
[0091] (ES-1002T: Shin-Etsu Chemical Co., Ltd., solid content 60%)
[0092] 0.19 parts of silicone oil with alkoxy groups at the end
[0093] (X-22-1968: Shin-Etsu Chemical Co., Ltd., solid content 100%)
[0094] ·Silanolate condensate 2.22 parts
[0095] (X-40-2308: Shin-Etsu Chemical Co., Ltd., 100% active ingredient)
[0096] ·Curing agent 0.1 part
[0097] (Titanium chelate, 100% active ingredient)
[0098] ·Silane coupling agent 0.3 parts
[0099] (100% active ingredients)
[0100] · 9.64 parts of solvent
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