Treatment method of alkaline oily wastewater with demulsifier
A treatment method and demulsifier technology, applied in water/sewage multi-stage treatment, flotation water/sewage treatment, water/sludge/sewage treatment, etc., can solve secondary pollution and other problems, and achieve simple and strong dosing Effect of surface activity and low running cost
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Embodiment 1
[0026] Step 1, preparation of demulsifier: proportioning by weight percentage of the following raw materials:
[0027] Calcium chloride 0.05-0.5%, polyferric sulfate 0.1-1.5%, polyaluminum chloride 0.5-3.0%, cationic polyacrylamide 0.01-0.1%, and the rest is water. Slowly add the above raw materials in sequence under normal temperature and pressure, and evenly Stir and dissolve in water to prepare a demulsifier for ready-to-use liquid products;
[0028] Step 2. Primary demulsification: the wastewater to be treated enters the primary demulsification tank. The dosage of primary demulsifier is 0.5-3.0ml / L per liter of treated wastewater. The pH of the water quality is controlled between 7-11, and the water temperature is controlled At 10-65°C, and stirring at a stirring speed of 40-100rpm, the residence time of the primary demulsifier in the wastewater is controlled within 5-21min;
[0029] Step 3, first-level vortex air flotation: the mixed liquid after the above pretreatment e...
Embodiment 2
[0033] Step 1, prepare a demulsifier, take mass fraction of calcium chloride 0.20%, polyferric sulfate 1.25%, polyaluminum chloride 2.0%, cationic polyacrylamide 0.02%, and the rest is water; at normal temperature and pressure, dissolve in water in sequence spare;
[0034] Step 2. Primary demulsification: The dosage of primary demulsifier is 2.0ml / L per liter of treated wastewater, the pH of water quality is controlled to 8.5, the water temperature is controlled at 45°C, and the stirring speed is 50rpm. The primary demulsifier is added to the waste water The residence time is controlled at 10min;
[0035] Step 3, first-level vortex air flotation: same as step 3 in Example 1, the effluent water is analyzed with a sewage removal rate of 90%, and the effluent water is clear;
[0036] Step 4, preparing a secondary demulsifier, taking mass fractions of calcium chloride 0.10%, polyferric sulfate 0.55%, polyaluminum chloride 1.00%, cationic polyacrylamide 0.01%, and the rest is wate...
Embodiment 3
[0039] Step 1, prepare a demulsifier, take 0.10% of calcium chloride, 1.50% of polyferric sulfate, 1.70% of polyaluminum chloride, 0.01% of cationic polyacrylamide in mass fraction, and the rest is water; at normal temperature and pressure, dissolve in water in sequence spare;
[0040] Step 2. Primary demulsification: The dosage of primary demulsifier is 2.5ml / L per liter of treated wastewater, the pH of water quality is controlled to 7.5, the water temperature is controlled at 62°C, and the stirring speed is 40rpm. The primary demulsifier is added to the waste water The residence time is controlled at 15min;
[0041] Step 3, one-stage vortex-concave air flotation: same as step 3 in Example 1, the effluent is analyzed with a sewage removal rate of 88%;
[0042] Step 4, prepare the secondary demulsifier, take mass fraction of calcium chloride 0.15%, polyferric sulfate 0.35%, polyaluminum chloride 1.55%, cationic polyacrylamide 0.02%, and the rest is water, which is dissolved i...
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