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Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof

A resin composition, acrylonitrile technology, applied in the field of polymer materials, can solve the problems of life safety and living environment threats, property loss, a large amount of black smoke, etc.

Active Publication Date: 2011-11-09
SHENZHEN XINGSHENGDI NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, ABS resin is a kind of flammable polymer material. Its horizontal combustion speed is very fast, and a large amount of black smoke is produced when it is burned. It continues to burn after leaving the fire. It will pose a great threat to people's life safety and living environment

Method used

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  • Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof
  • Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof
  • Flame-retardant acrylonitrile-butadiene-styrene resin composition and preparation method thereof

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Experimental program
Comparison scheme
Effect test

preparation example Construction

[0037] The preparation method of the flame-retardant acrylonitrile-styrene-butadiene resin composition includes the following steps: providing the following components in parts by weight:

[0038]

[0039] Stir the above-mentioned components evenly, and place them in a twin-screw extruder with a screw speed of 40-45Hz. The set temperature of each zone in the twin-screw extruder is: 190°C for the first zone, 200°C for the second zone, and 210°C for the third zone. , Zone 4 210°C, Zone 5 205°C;

[0040] Extrude and granulate to obtain a flame-retardant acrylonitrile-styrene-butadiene resin composition.

[0041] Preferably, it also includes the step of adding 1-30 parts by weight of glass fiber at the fiber-reinforcing hole of the screw extruder after extrusion.

[0042] The preparation method is simple in principle, low in cost and low in equipment requirements, and the prepared flame-retardant acrylonitrile-styrene-butadiene resin composition has good performance and can be...

Embodiment 1

[0045] The composition ratio of the following table is prepared (1 part=100 grams):

[0046] ABS 757 (product of Taiwan Chi Mei Company)

100 copies

ABS 181 (Korea Kumho Petrochemical Company product)

3 copies

Chlorinated polyethylene

5 copies

FR245

18 copies

Antimony trioxide

5 copies

Anti-dripping agent PTFE powder

0.2 parts

Antioxidant 4,4'-thiobis(6-tert-butyl-3-methylphenol)

0.3 parts

Lubricant EBS

0.2 parts

[0047] Pour the prepared ingredients except glass fiber into the mixer and stir evenly, and put them in the twin-screw extruder, the screw speed is 42Hz, and the set temperature is: 190°C in the first zone, 200°C in the second zone, and 210 in the third zone. ℃, 210 ℃ in the fourth zone, 205 ℃ in the fifth zone, extrude, and add 15 parts of glass fiber in proportion to the weight of the fiber hole of the screw at the same time, and granulate to obtain a flame-retardant ac...

Embodiment 2

[0052] The composition ratio of the following table is prepared (1 part=100 grams):

[0053] ABS 757

100 copies

ABS DP270 (product of Korea LG Chemical Company)

8 servings

Chlorinated polyethylene

3 copies

Decabromodiphenylethane

15 copies

Antimony trioxide

6 servings

Anti-dripping agent PTFE particles

0.2 parts

Antioxidant 4,4'-thiobis(6-tert-butyl-3-methylphenol)

0.3 parts

Lubricant EBS

0.2 parts

[0054] Pour the prepared ingredients except glass fiber into the mixer and stir evenly, and put them in the twin-screw extruder, the screw speed is 42Hz, and the set temperature is: 190°C in the first zone, 200°C in the second zone, and 210 in the third zone. ℃, 210℃ in the fourth zone, 205℃ in the fifth zone, extrude, and at the same time add 8 parts of glass fiber in proportion to the weight of the fiber hole of the screw, and granulate to get the flame-retardant acrylonitrile-styren...

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Abstract

The invention relates to a flame-retardant acrylonitrile-butadiene-styrene resin composition, which comprises the following components in part by weight: 100 parts of acrylonitrile-butadiene-styrene resin, 0.5 to 15 parts of toughening agent, 14 to 30 parts of flame retardant and flame retardant synergist, 0.1 to 0.5 part of antifogging agent and 0.1 to 2 parts of antioxidant and lubricating agent. The flame retardant is added into the flame-retardant acrylonitrile-butadiene-styrene resin composition, the composition has excellent flame retardancy; in the formula, the components have better compatibility; meanwhile, due to the synergism of the lubricating agent and the antioxidant, the processing fluidity of the flame-retardant acrylonitrile-butadiene-styrene resin composition can be improved and the dispersion performance of the flame retardant in the composition can be improved; and the prepared flame-retardant acrylonitrile-butadiene-styrene resin composition has high impact strength, bending strength, tensile strength, flame retardancy and fluidity. In addition, the invention also relates to a method for preparing the flame-retardant acrylonitrile-butadiene-styrene resin composition.

Description

【Technical field】 [0001] The invention relates to the field of polymer materials, in particular to a flame-retardant acrylonitrile-styrene-butadiene resin composition and a preparation method thereof. 【Background technique】 [0002] ABS (Acrylonitrile Butadiene Styrene) resin is an acrylonitrile-styrene-butadiene copolymer, which has high impact strength, good processing performance and chemical stability, is easy to mold, and the product is glossy and has both toughness and flexibility. Therefore, ABS resin is widely used in the automotive industry, electronic and electrical industry, light industrial appliances, textile and construction industries due to its excellent comprehensive performance, and has gradually become one of the most used thermoplastics. However, ABS resin is a kind of flammable polymer material. Its horizontal combustion speed is very fast, and a large amount of black smoke is produced when it is burned. It continues to burn after leaving the fire. It ...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L23/28C08L25/06C08L63/00C08K13/04C08K7/14C08K5/03C08K5/3492C08K3/22B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 许第修段海斌
Owner SHENZHEN XINGSHENGDI NEW MATERIALS
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