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Production method of rare earth aluminum manganese calcium iron alloy

A ferroalloy, aluminum-manganese-calcium technology, applied in the field of rare earth aluminum-manganese-calcium-iron alloy and its production, can solve the problems of not easy to float, nodule at the nozzle, not easy to add, etc., and achieve the effects of reducing labor intensity, convenient use and high hit rate

Inactive Publication Date: 2013-01-23
包头市北科创业高新材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the advantages of rare earths have been widely recognized by people, the use of rare earths in steelmaking plants faces the following difficulties: (1) rare earths are easily oxidized and difficult to add to steel, resulting in a low yield of rare earths; (2) the addition of rare earths (3) The proportion of rare earth inclusions generated is large, and it is difficult to float up from the molten steel; (4) It is easy to produce nozzle nodules during casting, and it is difficult to ensure the smooth progress of continuous casting production, etc.
The existence of these problems limits the enthusiasm of enterprises for rare earth applications

Method used

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  • Production method of rare earth aluminum manganese calcium iron alloy
  • Production method of rare earth aluminum manganese calcium iron alloy

Examples

Experimental program
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Effect test

Embodiment 1

[0029] (1) The ratio of 85% aluminum ingot: 15% calcium metal is added to the induction furnace and heated for 45 minutes, the temperature is maintained at 850° C., the furnace is poured into a mold to cast into a block, and naturally cooled to form a high-alumina-calcium alloy.

[0030] (2) The ratio of 90% aluminum ingot: 10% rare earth is added to the induction furnace and heated for 38 minutes, the temperature is kept at 820° C., it is taken out of the furnace and poured into a mold to cast into a block, and cooled naturally to form a rare earth aluminum alloy.

[0031] (3) Angle iron 55%: the ratio of medium carbon ferromanganese 7% is added in the induction furnace and heated for 33 minutes, and the temperature is maintained at 1620° C., adding the prepared high aluminum calcium alloy 15%: rare earth aluminum alloy 20% smelting for 22 minutes, Turn off the power supply, add 3% aluminum ingot, cool down to 1090°C naturally, pour it into a mold and cast it into a block, and...

Embodiment 2

[0035] (1) The ratio of 90% aluminum ingot: 10% calcium metal is added to the induction furnace and heated for 40 minutes, the temperature is maintained at 840° C., the furnace is poured into a mold to cast into a block, and naturally cooled to form a high-alumina-calcium alloy.

[0036] (2) The ratio of aluminum ingot 86%: rare earth 14% is added to the induction furnace and heated for 40 minutes, the temperature is kept at 800°C, it is taken out of the furnace and poured into a mold to cast into a block, and naturally cooled to form a rare earth aluminum alloy.

[0037] (3) Angle iron 10%: the ratio of medium carbon ferromanganese 8% is added in the induction furnace and heated for 35 minutes, and the temperature is maintained at 1600° C., adding 20% ​​of the prepared high-alumina-calcium alloy: 60% rare earth aluminum alloy for smelting for 20 minutes, Turn off the power supply, add 2% aluminum ingot, cool down to 1100°C naturally, pour it into a mold and cast it into a bloc...

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Abstract

The invention discloses a rare earth aluminum manganese calcium iron alloy and a production method thereof, belonging to the technical field of steel smelting deoxidier. The alloy comprises the following components by weight percent: 40-70% of Al, 5-20% of Mn, 1-10% of RE, 1-3% of Ca, not less than 5% of other residual elements, and the balance of Fe, wherein, the RE is rare-earth Ce, La or at least contains one mixed rare earth of Ce and La; the content of Ce and La in the mixed rare earth is not less than 90%; other residual elements are the mixed elements of carbon, sulfur, phosphorus and silicon in the alloy smelting process; and the preparation process flows are as follows: selecting materials, preparing the materials, charging, melting, deslagging, pouring, weighing and storing into a warehouse. The invention has the advantages of realizing strong deoxidation effect and high functional element yield; the rare earth aluminum manganese calcium iron alloy is easily removed as the impurity particle generated in the molten steel is large, is not only the strong deoxidizer, but also an additive of the alloy, and also can be used as intermediate alloy.

Description

technical field [0001] The invention belongs to the technical field of deoxidizers for steelmaking, and in particular provides a rare earth aluminum-manganese-calcium-iron alloy and a production method thereof. Background technique [0002] Deoxidation is an important process link in the steelmaking process. The choice and amount of deoxidizer are related to the control of the converter smelting end point, the denaturation of steel slag, the requirements for components, the denaturation treatment of inclusions and the change of continuous casting casting performance. In addition, the nature, shape and quantity of deoxidation products (mainly oxides and sulfides) will have a great impact on the mechanical and physical and chemical properties of steel. In the actual production process, some solid solvents need to be sprayed into molten steel. That is, denaturants, such as silicon-calcium, rare earth alloys, etc., change the properties of non-metallic inclusions solidified in ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/06
CPCY02P10/20
Inventor 陈向明曲俊涛成国光杨晓红山丹
Owner 包头市北科创业高新材料有限责任公司
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