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Direct forming production method for lithium ion battery cathode

A lithium-ion battery and production method technology, applied to battery electrodes, circuits, electrical components, etc., can solve problems such as reducing capacitance and cycle life, hidden dangers in battery safety performance, and affecting battery charge and discharge performance, etc., to achieve weight reduction and volume, reduced electrode area, good formability

Inactive Publication Date: 2013-02-06
耿世达
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] This traditional method of coating the active material on the current collector has some insurmountable shortcomings, such as uneven coating, easy fall off of the active material, large thickness of the electrode sheet, etc. After the battery is assembled, these shortcomings will affect the battery. The charging and discharging performance of the battery will reduce the capacity and cycle life, and there will be hidden dangers in the safety performance of the battery.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] 70g of modified graphite, 27g of polythiophene fibers and 3g of polyvinylidene fluoride were mixed in a reactor, the temperature was controlled at 40°C, the stirring speed was 180 rpm, and the mixture was mixed for 5 hours.

[0016] Put the mixture into a tablet machine for tableting, control the temperature at 100°C, and the pressure at 150Mpa to obtain an integrally formed lithium-ion battery negative electrode sheet with a capacity of 345mAh / g. After 200 cycles, the capacity decays to 3%. .

Embodiment 2

[0018] 70g of mesocarbon microspheres, 25g of carbon fiber and 5g of sodium carboxymethylcellulose were mixed in a reaction kettle, the temperature was controlled at 40°C, the stirring speed was 200 rpm, and the mixture was mixed for 6 hours.

[0019] Put the mixture into a tablet machine for tableting, control the temperature at 120°C, and the pressure at 120Mpa to obtain an integrally formed lithium-ion battery negative electrode sheet with a capacity of 220mAh / g. After 200 cycles, the capacity decay is 3.6%. .

Embodiment 3

[0021] 60g of natural graphite, 35g of nickel fiber and 5g of polytetrafluoroethylene were mixed in a reactor, the temperature was controlled at 50°C, the stirring speed was 200 rpm, and the mixture was mixed for 5 hours.

[0022] Put the mixture into a tablet machine for tableting, control the temperature at 100°C, and the pressure at 180Mpa to obtain an integrally formed lithium-ion battery negative electrode sheet with a capacity of 365mAh / g. After 200 cycles, the capacity decays to 4.5%. .

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Abstract

The invention relates to a direct forming production method for a lithium ion battery cathode. The method comprises the following steps of: 1) mixing 30 to 70 percent of lithium ion battery cathode active substance, 10 to 50 percent of conductive fiber and 1 to 20 percent of adhesive in percentage by mass in a reaction kettle respectively, wherein the temperature is controlled between 20 and 50 DEG C, the stirring speed is 60 to 300 revolutions per minute and the mixing is performed for 1 to 10 hours; and 2) pressing the mixture in a piece press to obtain an integrally formed lithium ion battery cathode pole piece, wherein the temperature is controlled between 70 and 120 DEG C and the pressure is 50 to 200MPa. The method has simple process; compared with the pole piece produced by a traditional method, the pole piece has the advantages of good forming property, low density and small volume; and the method can greatly reduce the weight and the volume of the pole piece. The method for producing the electrode pole piece can effectively reduce the thickness of the pole piece so as to improve the diffusion coefficient of lithium ions in the cathode and improve the electric capacity of a battery; and the active substance is uniformly contacted with the adhesive and organic electrolyte to prepare a high-density electrode so as to reduce the electrode area of side reaction in the charging / discharging process, prolong the service life of the battery and improve the stability of the battery.

Description

technical field [0001] The invention relates to a production method for direct forming of a negative electrode of a lithium-ion battery, in particular to a production method for an integrally formed pole piece which is different from the traditional method of coating a negative electrode active material on a current collector material. Background technique [0002] Due to the advantages of small size and high energy density, lithium-ion batteries are widely used in electronic products such as mobile communication equipment, digital cameras, and notebook computers. [0003] The battery cell of a lithium-ion battery is mainly composed of a positive electrode, a negative electrode, a separator, and an electrolyte. The performance of the negative electrode has the greatest impact on the performance of the lithium-ion battery. The volume of the negative active material will expand when intercalating and deintercalating lithium. [0004] Common lithium-ion battery negative electro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/1393
CPCY02E60/12Y02E60/122Y02E60/10
Inventor 耿世达
Owner 耿世达
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