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High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate

A polyurethane urea and organic fluorine technology, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of windward surface wear, unsatisfactory effect, and low anti-wear performance.

Inactive Publication Date: 2010-03-10
西北永新涂料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is generally used in seaside wind farms, and the effect in land wind farms is not ideal, with low wear resistance and severe wear on the windward side.

Method used

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  • High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate
  • High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0071] Step 1: Synthesis of Polyester

[0072] Add 26.5% adipic acid, 36.25% sebacic acid, 32.9% 1,4-butanediol, 4% trimethylolpropane to the reaction kettle, and add catalyst—0.2% p-toluenesulfonic acid, stabilizer— - 0.15% triphenyl phosphate. Raise the temperature to 180°C, keep it warm for 2 hours, and then vacuumize for about 1.5 hours to remove trace water and excess diol under reduced pressure. After discharge.

[0073] The second step: 32.9% polyester synthesized in the first step, 9.2% PTMG1500, 0.3% 1,4-butanediol, 5.6% hydroxyl-terminated siloxane (molecular weight 1500), 18% xylene, melted and mixed Heat up to 130°C for reflux dehydration, then cool down to 75°C, add 9% anhydrous ethyl acetate, anhydrous cyclohexanone, start to add 20% isophorone diisocyanate dropwise, finish dropping within 0.5 hours, add after dropwise Catalyst——0.2% p-toluenesulfonic acid, and heat-retaining reaction for 3 hours, then began to drop 5% amino-terminated fluorine-containing poly...

Embodiment 2

[0077] Step 1: Synthesis of Polyester

[0078]Add 66.3% sebacic acid, 12.5% ​​1,3-propanediol and 20.85% diethylene glycol to the reaction kettle, and add catalyst - 0.2% p-toluenesulfonic acid, stabilizer - 0.15% triphenyl phosphate . Raise the temperature to 180°C, keep it warm for 2 hours, and then vacuumize for 2 hours to remove trace water and excess diol under reduced pressure. After discharge.

[0079] The second step: melt and mix 26.4% and 6.1% PTMG2000, 10.1% hydroxyl-terminated polysiloxane (molecular weight 2000), 1.4% trimethylolpropane, and 18% xylene in the first step and heat up to 130°C Reflux for dehydration, then lower the temperature to 80°C, add 9% anhydrous ethyl acetate, 3% anhydrous cyclohexanone, start to drop 26% phorone diisocyanate (IPDI), drop it within 0.5 hours, and add Catalyst - 0.2% p-toluenesulfonic acid, and heat preservation reaction for 2.5 hours, then began to drop 4% amino-terminated fluorine-containing polysiloxane (molecular weight ...

Embodiment 3

[0083] Step 1: Synthesis of Polyester

[0084] Add 27.55% azelaic acid, 21.6% adipic acid, 34.5% tetraethylene glycol, 16% 1,4-butanediol to the reaction kettle, and add 0.2% p-toluenesulfonic acid (catalyst), 0.15% Triphenyl Phosphate (stabilizer). Raise the temperature to 180°C, keep it warm for 1.5 hours, and then vacuumize for about 1 hour to remove trace water and excess diol under reduced pressure. After discharge.

[0085] The second step: 30.4% and 13.4% PTMG3000 of the polyester synthesized in the first step, 0.8% glycerin, 13.4% amino-terminated polysiloxane (molecular weight 3000), and xylene are melted and mixed and heated to 130° C. for reflux dehydration, and then cooled to At 90°C, add 9% anhydrous ethyl acetate and 3% anhydrous cyclohexanone, start to add 12% hexamethylene diisocyanate (HDI) dropwise, and finish dropping within 0.5 hours. Start to add 18% amino-terminated fluorine-containing polysiloxane (molecular weight: 3000) dropwise, and finish the drop...

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Abstract

The invention discloses high-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate. The high-performance wind-power generating facility coating is prepared from component A and component B according to proportion. The wind-power generating facility coating has toughness, attrition resistance, high elasticity, excellent mechanical property, yellowing resistance, good colour retention, high ultraviolet resistance, high weather resistance, favorable and excellent electrical insulation, chemical stability, moisture resistance and freeze resistance. In addition, the wind-power generating facility coating has high performance and moderate cost and can strongly protect the wind-power generating facility, reduce the maintenance frequency and lower the purchasing cost of the wind-power generating facility, thereby having extremely high implementation value and social and economic benefit.

Description

technical field [0001] The invention relates to the field of wind power coatings, in particular to a high-performance wind power coating prepared by using organofluorosilicon modified elastic polyurethane urea resin as a base material. Background technique [0002] In order to alleviate the contradiction between energy supply and demand, countries all over the world are actively researching and developing new energy, especially renewable energy, so as to ensure the long-term and stable energy supply of human beings. [0003] Wind power has become the fastest-growing renewable energy in recent years, and it has begun to develop from "supplementary energy" to "strategic alternative energy". Wind power stations are exposed to harsh weather conditions for a long time, requiring effective corrosion protection. Among them, large-scale wind power equipment is expensive and the working environment is harsh, so it is inconvenient to disassemble and repair the main parts on site. Th...

Claims

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Application Information

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IPC IPC(8): C09D175/06C09D7/12C09D5/00C08G18/66C08G18/38C08G18/42
Inventor 杨建忠王云普盛永宁颜小东李丽许玉霞刘志云
Owner 西北永新涂料有限公司
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