High-performance wind-power generating facility coating prepared by taking organic fluorinated silicone modified elastic polyurethane-urea resin as substrate
A polyurethane urea and organic fluorine technology, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of windward surface wear, unsatisfactory effect, and low anti-wear performance.
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Embodiment 1
[0071] Step 1: Synthesis of Polyester
[0072] Add 26.5% adipic acid, 36.25% sebacic acid, 32.9% 1,4-butanediol, 4% trimethylolpropane to the reaction kettle, and add catalyst—0.2% p-toluenesulfonic acid, stabilizer— - 0.15% triphenyl phosphate. Raise the temperature to 180°C, keep it warm for 2 hours, and then vacuumize for about 1.5 hours to remove trace water and excess diol under reduced pressure. After discharge.
[0073] The second step: 32.9% polyester synthesized in the first step, 9.2% PTMG1500, 0.3% 1,4-butanediol, 5.6% hydroxyl-terminated siloxane (molecular weight 1500), 18% xylene, melted and mixed Heat up to 130°C for reflux dehydration, then cool down to 75°C, add 9% anhydrous ethyl acetate, anhydrous cyclohexanone, start to add 20% isophorone diisocyanate dropwise, finish dropping within 0.5 hours, add after dropwise Catalyst——0.2% p-toluenesulfonic acid, and heat-retaining reaction for 3 hours, then began to drop 5% amino-terminated fluorine-containing poly...
Embodiment 2
[0077] Step 1: Synthesis of Polyester
[0078]Add 66.3% sebacic acid, 12.5% 1,3-propanediol and 20.85% diethylene glycol to the reaction kettle, and add catalyst - 0.2% p-toluenesulfonic acid, stabilizer - 0.15% triphenyl phosphate . Raise the temperature to 180°C, keep it warm for 2 hours, and then vacuumize for 2 hours to remove trace water and excess diol under reduced pressure. After discharge.
[0079] The second step: melt and mix 26.4% and 6.1% PTMG2000, 10.1% hydroxyl-terminated polysiloxane (molecular weight 2000), 1.4% trimethylolpropane, and 18% xylene in the first step and heat up to 130°C Reflux for dehydration, then lower the temperature to 80°C, add 9% anhydrous ethyl acetate, 3% anhydrous cyclohexanone, start to drop 26% phorone diisocyanate (IPDI), drop it within 0.5 hours, and add Catalyst - 0.2% p-toluenesulfonic acid, and heat preservation reaction for 2.5 hours, then began to drop 4% amino-terminated fluorine-containing polysiloxane (molecular weight ...
Embodiment 3
[0083] Step 1: Synthesis of Polyester
[0084] Add 27.55% azelaic acid, 21.6% adipic acid, 34.5% tetraethylene glycol, 16% 1,4-butanediol to the reaction kettle, and add 0.2% p-toluenesulfonic acid (catalyst), 0.15% Triphenyl Phosphate (stabilizer). Raise the temperature to 180°C, keep it warm for 1.5 hours, and then vacuumize for about 1 hour to remove trace water and excess diol under reduced pressure. After discharge.
[0085] The second step: 30.4% and 13.4% PTMG3000 of the polyester synthesized in the first step, 0.8% glycerin, 13.4% amino-terminated polysiloxane (molecular weight 3000), and xylene are melted and mixed and heated to 130° C. for reflux dehydration, and then cooled to At 90°C, add 9% anhydrous ethyl acetate and 3% anhydrous cyclohexanone, start to add 12% hexamethylene diisocyanate (HDI) dropwise, and finish dropping within 0.5 hours. Start to add 18% amino-terminated fluorine-containing polysiloxane (molecular weight: 3000) dropwise, and finish the drop...
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