Electrolyte and lithium ion secondary battery including the same
A secondary battery and electrolyte technology, which is applied in the field of electrolyte for lithium-ion secondary batteries and lithium-ion secondary batteries, and can solve problems such as reducing the effective capacity of graphite negative electrodes and deteriorating battery high-rate cycle life
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Embodiment 1
[0084] The cathode active material LiCoO 2 , a binder polyvinylidene fluoride (PVdF), and a conductive material carbon were mixed in N-methyl-2-pyrrolidone at a weight ratio of 92:4:4 to prepare a slurry for a positive electrode active material. The resulting slurry was coated on an aluminum foil, dried and rolled to prepare a positive electrode plate. 97 wt % of artificial graphite as a negative active material and 3 wt % of polyvinylidene fluoride (PVdF) as a binder were mixed and dispersed in water to prepare a negative active material slurry. The resulting slurry was coated on a copper foil, dried and rolled to prepare a negative electrode plate.
[0085] A separator made of polyethylene (PE) was inserted between the electrodes, wound, pressed and inserted into a prismatic can (46mmx34mmx50mm).
[0086] LiPF 6 Add ethylene carbonate and ethyl methyl carbonate with 3:7 (v / v) in the mixed solvent that mixes, until final concentration reaches 1.3M, and the ionic liquid N-m...
Embodiment 2
[0089] A lithium-ion secondary battery was manufactured in the same manner as in Example 1, except that 1 part by weight of lithium fluorooxalate borate was added.
Embodiment 3
[0091] A lithium ion secondary battery was manufactured in the same manner as in Example 1, except that 40 parts by weight of MPPTFSI (N-methylpropylpyrrolidinium bis(trifluoromethanesulfonyl)imide) was used as the ionic liquid.
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