Electrographic photoreceptor, image forming apparatus, and electrographic cartridge

一种电子照相、感光体的技术,应用在光学、电记录术、仪器等方向,能够解决模糊、不能充分满足其要求、带电性降低等问题,达到电学特性优异的效果

Active Publication Date: 2009-06-03
MITSUBISHI RAYON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the electrophotographic photoreceptors using these phthalocyanines, the chargeability of the electrophotographic photoreceptors may decrease with the repeated use of the electrophotographic photoreceptors.
[0023] In particular, when the above electrophotographic photoreceptor is used in an imaging device for reverse development, due to the increase in blur and black spots, the stability of electrical characteristics is required due to the increase in imaging speed and high image quality in recent years. And the improvement of image quality, etc. (for example, when black point reduction, blurring, repeated stability, etc. are required), sometimes the requirements cannot be fully met.

Method used

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  • Electrographic photoreceptor, image forming apparatus, and electrographic cartridge
  • Electrographic photoreceptor, image forming apparatus, and electrographic cartridge
  • Electrographic photoreceptor, image forming apparatus, and electrographic cartridge

Examples

Experimental program
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Effect test

Embodiment

[0566] Hereinafter, the present invention will be described more specifically by giving examples and comparative examples, but the present invention is not limited thereto as long as the present invention does not deviate from the gist thereof. In addition, in description of an Example, "part" means a "weight part" unless otherwise stated.

[0567] [Example Group 1]

[0568] [Manufacture of oxytitanium phthalocyanine]

manufacture example 1-1

[0570] Under a nitrogen atmosphere, 66.6 g of phthalonitrile was suspended in 353 mL of diphenylmethane, and a mixed solution of 15.0 g of titanium tetrachloride and 25 mL of diphenylmethane was added at 40°C. After raising the temperature to 205-210°C in about 1 hour, a mixed solution of 10.0 g of titanium tetrachloride and 16 mL of diphenylmethane was added dropwise, and the mixture was reacted at 205-210°C for 5 hours. The product was heated and filtered at 130 to 140° C., and washed with N-methylpyrrolidone (hereinafter referred to as “NMP” as appropriate) and n-butanol in this order. Next, after heating to reflux in 600 mL of n-butanol, NMP, water, and methanol were suspended and washed, and dried to obtain 47.0 g of B-type oxytitanium phthalocyanine.

[0571] With 20.0g of this type B oxytitanium phthalocyanine and 120mL glass beads ( 1.0mm~ 1.4 mm) together with a paint shaker for 25 hours, elute oxytitanium phthalocyanine with methanol, and obtain amorphous oxytita...

manufacture example 1-2

[0575] Under a nitrogen atmosphere, 66.6 g of phthalonitrile was dissolved in 436 mL of 1-chloronaphthalene, and a mixture of 25.0 g of titanium tetrachloride and 21 mL of 1-chloronaphthalene was added dropwise at 200°C. After reacting at 205-210°C for 5 hours, the product was heated and filtered at 130-140°C. Next, it was heated to reflux in 580 mL of n-butanol, then suspended and washed with water, NMP, and methanol, and dried to obtain 48.7 g of B-type oxytitanium phthalocyanine.

[0576] With 30.0g of this type B oxytitanium phthalocyanine and 200mL glass beads ( 1.0mm~ 1.4 mm) together with a paint shaker for 20 hours, then elute oxytitanium phthalocyanine with methanol, and obtain amorphous oxytitanium phthalocyanine after filtration. After suspending this oxytitanium phthalocyanine in 625 mL of water, add 48 mL of o-dichlorobenzene, stir at room temperature for 1 hour, discard the water by decantation, carry out suspension washing with methanol, filter and dry, and ...

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Abstract

An electrographic photoreceptor has an underlying layer, which is formed on a conductive support and contains metal oxide particles and a binder resin, and a photosensitive layer formed on the underlying layer. In order to provide the electrographic photoreceptor with high sensitivity and a low residual potential, the underlying layer is so formed that the volume average particle diameter, measured by a dynamic light scattering method, of the metal oxide particle in a solution dispersed in a solvent including methanol and 1-propanol mixed with a weight ratio of 7:3 is made at most 0.1 [mu]m and the cumulative 90% particle diameter is made at most 0.3 [mu]m. In addition, the photosensitive layer includes crystalline phthalocyanine having one or more clear main diffraction peaks at Bragg angles (2theta +- 0.2 DEG) of 27.0 DEG to 29.0 DEG in an X-ray diffraction spectrum.

Description

technical field [0001] The present invention relates to an electrophotographic photoreceptor having an undercoat layer, and an image forming device and an electrophotographic cartridge using the electrophotographic photoreceptor. Background technique [0002] Since electrophotographic technology can obtain immediacy, high-quality images, etc., this technology has been widely used not only in the field of copiers but also in various printer fields in recent years. For the electrophotographic photoreceptor (hereinafter referred to as "photoreceptor" when appropriate), which is the core of electrophotography technology, people are developing organic photoreceptors using organic photoconductive materials as their photoconductive materials, which are compatible with inorganic photoconductive materials. Compared with organic materials, organic photoconductive materials have the advantages of being pollution-free and easy to manufacture. [0003] Generally, an organic photorecepto...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03G5/14G03G5/06
CPCG03G5/0672G03G5/0668G03G5/142G03G5/0507G03G5/0614G03G5/104G03G5/043G03G5/0525G03G5/0696G03G5/0514G03G5/047G03G5/144G03G5/061443G03G5/06147G03G5/061473G03G5/06149
Inventor 三森光幸石尾耕三渕上宏惠
Owner MITSUBISHI RAYON CO LTD
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