Composite biocide

A biocide and adjuvant technology, used in biocides, biocides, fungicides, etc., can solve the problem of inability to achieve effective application of suspended solids and oily industrial circulating cooling water, insignificant sterilization effect, and large dosage of chemicals, etc. problem, to achieve the effect of long duration of drug effect, long continuous drug effect, and low dosage

Active Publication Date: 2009-05-06
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

They have played a certain role in controlling the bacteria and algae in circulating water. However, when glutaraldehyde single agent is used as a biocide, due to its poor penetration ability, the dosage of the agent is relatively large; common quaternary ammonium salts (including After the combination of dialkyl quaternary ammonium salt) and glutaraldehyde, the penetration ability of the agent is strengthened, but to achieve the same bactericidal effect, the dosage of the agent is still relatively large
Other patents related to glutaraldehyde such as CN03139646.1, CN98112806.8, CN97107140.3, CN98113676.1, CN98114208.7, CN97191642.X, CN97191671.3, CN98106772.7, CN01145564.0, CN00144203 .7, CN97111762.4, CN97122763.2, CN96122359.6, CN96100827.X, etc. aim to provide a liquid disinfectant with low irritating odor, low toxicity, weak irritation to skin and ...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Prepare compound biocide according to the following ratio:

[0034] Glutaraldehyde 800Kg, dication biocide (XT-LX435H Hebei Xiangtai Lanxing Fine Chemical Co., Ltd. production) 100kg, dodecyl dimethyl benzyl ammonium chloride 50kg, deionized water 50Kg. The total amount of biocide is 1000Kg.

[0035] The oil content in the cooling water system is 30mg / l, and the total number of heterotrophic bacteria is 4.56×10 5 pieces / ml. Add biocide 60mg / l in the cooling water system, and the killing rates of heterooxygen bacteria in 24 hours and 48 hours are 99.09% and 98.86% respectively.

Embodiment 2

[0037] Prepare compound biocide according to the following ratio:

[0038] Glutaraldehyde 500Kg, double cation biocide (XT-LX435H Hebei Xiangtai Lanxing Fine Chemical Co., Ltd. production) 200kg, tetradecyl dimethyl benzyl ammonium chloride 200kg, deionized water 100Kg. The total amount of biocide is 1000Kg.

[0039] The oil pollution content of the cooling water system is 30mg / l, and the total number of heterotrophic bacteria is 3.58×10 5 pieces / ml. Adding biocide 60mg / l in the cooling water system, the killing rate of heterotrophic bacteria in 24 hours and 48 hours were 99.62% and 99.31% respectively.

Embodiment 3

[0041] Prepare compound biocide according to the following ratio:

[0042] Glutaraldehyde 600Kg, dication biocide (XT-LX435H Hebei Xiangtai Lanxing Fine Chemical Co., Ltd. production) 120kg, cetyl dimethyl benzyl ammonium chloride 180kg, deionized water 100Kg. The total amount of biocide is 1000Kg.

[0043] The oil content of the cooling water system is 30mg / l, and the total number of heterotrophic bacteria is 1.28×10 5 pieces / ml. Adding biocide 60mg / l in the cooling water system, the killing rate of heterotrophic bacteria in 24 hours and 48 hours were 98.88% and 97.92% respectively.

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Abstract

The invention relates to a compound biocide suitable for industrial circulation water. Counted by the 100 percent of the total weight of the components, the components comprise 50 to 80 percent of a main agent of glutaric dialdehyde, 10 to 30 percent of a secondary agent of a dication biocide as well as 5 to 30 percent of a secondary agent of a C8 to C18 alkyl (or double dodecyl) quaternary ammonium salt. The compound biocide has the characteristics of broad spectrum, high effect, speediness, long continuous drug effect, less dosage and broad application range and the like and excellent sterilizing performance when the pH value ranges from 7.0 to 9.5; the compound biocide also has excellent penetrability, and can effectively peel off the slimebiological fouling in a system and effectively prevents under-deposit corrosion and simultaneously the compound biocide suitable for industrial circulation water can effectively ease the problems of eutrophy, fast bacteria and algae propagation and device corrosion in the water quality caused by the leakage oil products in the system, thus being particularly suitable for the industrial circulation water with higher oil stain content.

Description

technical field [0001] The invention relates to a composite biocide, in particular to a biocide mainly used in the sterilization treatment of circulating water with relatively high suspended solids and oil pollution content in oil refineries. Background technique [0002] There are often oil leaks in the industrial circulating water of refineries. After the oil leaks into the water system, the bactericide and algicide commonly used in the circulating water system can easily react with the oil and reduce the bactericidal ability of the biocide. At the same time, when the circulating water is suspended When the content of organic matter is high, it is difficult for the bactericidal ability of some biocides to penetrate into the lower layer of slime, thus affecting the bactericidal and algae killing effect of the agent. When the oil pollution content in the circulating water system is high, the bactericidal ability of the agent is often reduced, the bacteria and algae in the wa...

Claims

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Application Information

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IPC IPC(8): A01N43/72A01N41/00A01P3/00A01N35/02A01N37/00
Inventor 杨岳陈际帆刘发强刘光利刘志花张伟
Owner PETROCHINA CO LTD
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