Intermediate transfer belt and manufacturing method thereof
An intermediate transfer belt and modified technology, which can be used in building structures, instruments, door/window protection devices, etc., can solve such problems such as poor craftsmanship
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[0038]In the preparation of a polysiloxane-modified polyamic acid solution, when the polysiloxane resin is used in an amount of less than 10% by weight based on the amount of diamine, water repellency and oil repellency are not greatly improved , thus not significantly improving the low moisture resistance which is a disadvantage of polyimide. On the other hand, if the amount exceeds 30% by weight, attributable to the influence of the polysiloxane resin having flexibility with respect to polyimide, the mechanical strength is sharply lowered.
[0039] During polymerization, a solvent selected from highly polar aprotic solvents such as N, N-dimethylformamide (DMF), dimethylacetamide (DMAc) and N-methyl-2- Pyrrolidone (NMP).
[0040] In consideration of heat dissipation, the resulting intermediate transfer belt preferably has a thermal conductivity of 5.1 to 7.4 W / mk. Therefore, when preparing the polysiloxane-modified polyamic acid solution, a thermally conductive filler is al...
Embodiment 1
[0061] While introducing nitrogen into a four-necked flask equipped with a mechanical stirrer, a reflux condenser and nitrogen filling into the inlet, the PMDA of 47g and 43g of 4,4'-diaminodiphenyl ether were dissolved in In the highly polar aprotic solvent DMF of 380g, afterward, with the weight based on 4,4'-diaminodiphenyl ether is the amount of 10% by weight to add 10% by weight of the number average molecular weight is 600 and has at its two ends Dimethicone containing aminoaminopropyl groups, from which a complete solution is prepared. Then, based on the total weight of the solute, 2% by weight of Ketyan black and 0.5% by weight of Dentall TM-200 as conductive fillers were dispersed in the above solution with an ultrasonic dispenser, and then allowed to react at room temperature for 1 hour, by This prepares a polydimethylsiloxane-modified polyamic acid solution containing a conductive filler.
[0062] The polydimethylsiloxane-modified polyamic acid solution thus prepar...
Embodiment 2
[0065] A polydimethylsiloxane-modified polyimide-based intermediate transfer belt was produced in the same manner as in Example 1 except that Dentall TM-200 was not used as the conductive filler.
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