Device and method for on-line measuring biochemical oxygen demand in sample
A biochemical oxygen demand, sample technology, applied in the direction of electrochemical variables of materials, etc., to achieve the effects of low cost, reduced manual workload, and shortened measurement cycle
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Embodiment 1
[0044] See figure 1 . The device for online determination of biochemical oxygen demand in samples includes: BOD sample pool 1, sample feed pump 2, pipeline filter 3, sterilizing filter membrane 4, BOD sampling feedback control valve 5, dilution buffer storage tank 6, dilution Buffer solution feeding pump 7, diluted buffer solution sampling feedback control valve 8, upflow microbial fuel cell 9, anode 10, cathode 11, external resistor 12, A / D conversion card 13, microbial fuel cell circulation pump 14, microbial fuel Battery cycle feedback control valve 15, sample collection container 16, data acquisition processing and feedback control valve control computer system 17;
[0045] The discharge port of the BOD sample pool 1 is connected with the sample feed pump 2 through the pipeline, the discharge port of the sample feed pump 2 is connected with the feed port of the pipeline filter 3 through the pipeline, and the pipeline filter 3 The discharge port is connected to the polyte...
Embodiment 2
[0053] The device for online determination of biochemical oxygen demand in the sample is the same as in Example 1. The concentration of eutrophic BOD was determined by pulse integration method. The sample is 2mmol / L sodium acetate solution. At this time, the voltage signal at both ends of the external resistance detected by the data acquisition process and the feedback control valve control computer system is 100mV, which is higher than the set value. The pulse integration method is selected to measure the concentration of eutrophic BOD. Then close the dilution buffer sampling feedback control valve, open the microbial fuel cell cycle feedback control valve, control the BOD sampling feedback control valve to realize pulsed sampling, close the BOD sampling feedback control valve, and the sample enters the upflow microbial fuel cell. , flows out from the top, enters the upflow microbial fuel cell again through the microbial fuel cell cycle feedback control valve and the microbia...
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