Radiation-sensed resin composition, layer insulation film, microlens and forming method thereof
A technology of resin composition and radiation, which is applied in the direction of lens, photosensitive material processing, photoplate making process of pattern surface, etc. It can solve the problems of developer penetration, low dielectric constant transmittance, easy peeling, etc.
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[0209] Synthesis example of copolymer [A]
Synthetic example A-1
[0211] 7 parts by weight of 2,2'-azobis(2,4-dimethylvaleronitrile) and 220 parts by weight of diethylene glycol ethyl methyl ether were placed in a flask equipped with a condenser tube and a stirrer. Then load 20 parts by weight of methacrylic acid, tricyclic methacrylic acid [5.2.1.0 2,6 ] 15 parts by weight of decane-8-yl ester, 20 parts by weight of N-cyclohexylmaleimide, 30 parts by weight of glycidyl methacrylate, 15 parts by weight of styrene and α-methylstyrene dimer 3 parts by weight, after performing nitrogen substitution, stirring was started slowly. The temperature of the solution was raised to 70°C, and the temperature was maintained for 4 hours, whereby a polymer solution containing the copolymer [A-1] was obtained. The solid content concentration (referring to the ratio of the weight of the polymer to the total weight of the polymer solution; the same below) of the polymer solution was 32.0% by weight.
[0212] The polystyrene conversion weight average molecula...
Synthetic example A-2
[0214] 8 parts by weight of 2,2'-azobis(2,4-dimethylvaleronitrile) and 220 parts by weight of diethylene glycol ethyl methyl ether were placed in a flask equipped with a condenser tube and a stirrer. Then load 20 parts by weight of methacrylic acid, 45 parts by weight of 3,4-epoxycyclohexylmethyl methacrylate, 10 parts by weight of styrene, tricyclomethacrylic acid [5.2.1.0 2,6 ] 25 parts by weight of decan-8-yl ester and 3 parts by weight of α-methylstyrene dimer were replaced with nitrogen, and then stirring was started slowly. The temperature of the solution was raised to 70° C., and the temperature was maintained for 4 hours, whereby a polymer solution containing the copolymer [A-2] was obtained. The solid content concentration of this polymer solution was 31.9% by weight.
[0215] The polystyrene conversion weight average molecular weight (Mw) of copolymer [A-2] was 8,800, and molecular weight distribution (Mw / Mn) was 2.4.
[0216] Synthesis example of copolymer [C] ...
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