Gadolinium-containing Nd-Fe-B rare earth permanent magnetic material dn its manufacturing method
A rare earth permanent magnet and neodymium iron boron technology, applied in the field of magnetic materials, can solve problems such as unspecified Gd, and achieve the effect of reducing costs
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Embodiment 1
[0041] A kind of neodymium iron boron rare earth permanent magnet material containing gadolinium, according to the batching described in following table 1:
[0042] Table 1
[0043] existing magnet 1
Example 1
weight
%%
B
0.97
0.97
Dy
1
1
Tb
0
0
Nd
31.9
31.9
Pr
0
0
co
1
1
Cu
0.11
0.11
Gd
0
0.05
Ga
0.12
0.12
Al
0
0
Nb
0.3
0.3
Fe
64.6
64.55
[0044] Then adopt following steps to prepare NdFeB rare earth permanent magnet material:
[0045] (1) Melting-casting: the raw materials are formed into molten alloy liquid by vacuum melting method, and then the molten alloy liquid is cast and cooled into a book-shaped alloy ingot with a thickness of about ...
Embodiment 2
[0056] The smelting step adopts vacuum smelting; the thickness of the alloy ingot is about 10mm; the ingot is crushed into powder by the mechanical coarse crushing method, and the average particle size is <1mm; forming: forming by molding and cooling isostatic pressing; sintering: the blank after forming Carry out sintering at 1085° C. for 1 hour in a vacuum sintering furnace; finally temper at 500° C. for 1 hour, and the rest of the steps are the same as in Example 1 to obtain NdFeB rare earth permanent magnet materials. See Table 3 for the results.
[0057] table 3
[0058] existing magnet 2
[0059] By comparison, it can be found that the Hcj of the magnet of Example 2 added with Gd is 1.03 kOe higher than that of the existing magnet 2 without Gd added.
Embodiment 3
[0061] The smelting process adopts vacuum smelting, and the alloy ingot with a thickness of about 0.2mm is used; the solution heat treatment process (1095°C) is used between the casting and crushing processes; the ingot is crushed into powder by hydrogen crushing method, and the average particle size is <1mm; : Formed by rubber molding; the temperature of the vacuum sintering furnace is 1085° C., the tempering temperature is 600° C., and the rest of the steps are the same as in Example 1 to obtain the NdFeB rare earth permanent magnet material. The results are shown in Table 4.
[0062] Table 4
[0063] Existing magnet 3
[0064] By comparison, it can be found that the Hcj of the magnet of Example 3 added with Gd is 0.98 kOe higher than that of the existing magnet 3 without Gd added.
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