Low-temperature sintering hexagonal crystal series soft magnet ferrite
A soft ferrite and hexagonal ferrite technology, applied in the field of metal materials, can solve problems such as affecting the sintering effect and reducing the performance of components, and achieve the effects of high material performance indicators, wide firing temperature and wide application prospects.
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Embodiment 1
[0012] Example 1, using analytically pure Fe 2 O 3 , BaCO 3 , Bi 2 O 3 , CuO, Co 3 O 4 , ZnO, MgO, MnO 2 , NiO, TiO 2 As the initial raw materials, weigh the raw materials according to the component ratio (weight ratio) shown in Table 1. Use absolute ethanol as the medium to ball mill and mix for 24 hours, dry at 75°C, pass through a 200-mesh sieve, and pre-burn for 4 hours; ball mill the resulting powder Sieving, granulating, forming, and sintering at 890°C for 4 hours. Ring sample, outer diameter 20mm, inner diameter 10mm, thickness 2.5mm, molding pressure 7MPa; sheet sample, diameter 10mm, thickness 1mm, molding pressure 2MPa. The upper and lower surfaces of the sintered flake samples were coated with silver and their dielectric constant and resistivity were measured. After firing, the ring-shaped sample was measured with a HP4291B (1M-1GHz) RF impedance analyzer to measure the magnetic spectrum. The performance parameters of the obtained samples are shown in Table 1.
Embodiment 2
[0013] Example 2, using analytically pure Fe 2 O 3 , BaCO 3 , Bi 2 O 3 , CuO, Co 3 O 4 , ZnO is the initial raw material, and Fe is based on the weight ratio 2 O 3 : BaCO 3 : Bi 2 O 3 : CuO: Co 3 O 4 :ZnO=100:37.7:4.9:3.4:8.5:6.9 Weigh the raw materials, mix them by ball milling with absolute ethanol for 24 hours, dry at 75°C, pass through a 200-mesh sieve, pre-burn at 900°C, and keep the temperature for 4 hours to obtain Pure single-phase Y-type hexagonal ferrite powder; ball milled, sieved, granulated, molded, and sintered at 850℃, 870℃, 890℃, and 910℃ for 2 hours (denoted as samples 2-1, 2- 2, 2-3 and 2-4). Ring sample, outer diameter 20mm, inner diameter 10mm, thickness 2.5mm, molding pressure 7MPa; sheet sample, diameter 10mm, thickness 1mm, molding pressure 2MPa. The upper and lower surfaces of the sintered flake samples were coated with silver and their dielectric constant and resistivity were measured. After firing, the ring-shaped sample was measured with a HP4291B (1M-1G...
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