Method for preparing bright yellow active dye stuff K-6G
A reactive dye, bright yellow technology, applied in reactive dyes, dyeing methods, azo dyes, etc., can solve the problems of color supply, color fixation rate, low solubility, poor chlorine bleaching fastness, etc., to achieve excellent color supply, Eliminate the discharge of sewage, the effect of improvement and color fixing rate
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Embodiment 1
[0031] 1. Ingredients list:
[0032] raw material name
Molecular weight
Molecular ratio
100% discount (kg)
Feeding amount (mole)
2,4-Diaminobenzene sulfonate sodium
3-formylamino-4-methyl-6-
Hydroxy-N-Ethylpyridone
184.5
210.2
69.01
36.5
196
173.2
1.0
0.9584
0.9802
3.2
0.949
1.05
149.25
162.97
54.72
94.48
150.47
147.1
0.80894
0.80894
0.80894
0.80894
0.80894
0.80894
[0033] 2. The K-6G preparation process of the present invention operates as follows:
[0034] a. Dissolution of sodium 2,4-diaminobenzene sulfonate
[0035] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust the pH=5.5 with dilute hydrochloric acid, the temperature is 18℃, the v...
Embodiment 2
[0058] a. Dissolution of sodium 2,4-diaminobenzene sulfonate
[0059] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust pH to 6.0 with dilute hydrochloric acid, temperature to 20°C, volume to 3200L, C%=7 in the solution.
[0060] b. The first condensation reaction: add 200L of water and crushed ice to a shrinkage, cast weight content of industrial product 99.5% cyanuric chloride 150kg, beating for 45 minutes, adjust pH=2.5 with dilute hydrochloric acid, temperature 5℃, Add the sodium 2,4-diaminobenzene sulfonate solution to a shrinking pot within 2 hours, stir and react for 2 hours after the addition, and control the temperature of the solution at 8°C after the reaction.
[0061] c. Neutralization and acidification
[0062] Quickly add 10% soda ash water within 10 minutes to adjust the pH of the product to 6.5, stabilize for 2 minutes, add crushed ice, quickly add hydrochloric acid, increase the volume of 4...
Embodiment 3
[0074] a. Dissolution of sodium 2,4-diaminobenzene sulfonate
[0075] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust pH=5.0 with dilute hydrochloric acid, temperature 15℃, volume 3200L, C%=6 in the solution.
[0076] b. The first condensation reaction: add 200L of water and crushed ice to a shrinkage, cast weight content of industrial product 99.5% cyanuric chloride 150kg, beating for 45 minutes, adjust pH=1.5 with dilute hydrochloric acid, temperature is 0℃, And in 1.5 hours, add 2,4-diaminobenzene sulfonate sodium solution to a shrinking pot, and after the addition, the reaction was stirred for 2 hours, and the temperature of the solution was controlled at 2°C after the reaction.
[0077] c. Neutralization and acidification
[0078] Quickly add 10% soda ash water within 10 minutes to adjust the pH of the product to 5.5, stabilize for 2 minutes, add crushed ice, quickly add hydrochloric acid, increase t...
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