Synthesis of acenes and hydroxy-acenes
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[0012] The present invention recognizes the benefits of synthesizing acenes via two consecutive reduction reactions. In the first reduction reaction, an acenequinone of the target acene is converted into an acenepolyhydrodiol. In the second reduction reaction, the acenepolyhydrodiol can be converted to the target acene. Alternatively, the acenepolyhydrodiol can be thermally converted into a hydroxy-substituted acene. These reactions advantageously reduce the need for toxic compounds for the synthesis. In addition, some of the acenepolyhydrodiols or hydroxy-substituted acenes are soluble in organic solvents, thereby facilitating the fabrication of devices via solution deposition processes.
[0013] One embodiment is a method of synthesis. FIG. 1 presents a flow diagram showing selected steps in an exemplary method of synthesis. In step 110, an acenequinone of the target acene is provided. In step 120, the acenequinone is reduced to form an acenepolyhydrodiol by exposing the acenequinon...
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