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Biochemical-performance evaluation of industrial waste water

An industrial wastewater and evaluation method technology, applied in the direction of testing water, measuring devices, instruments, etc., can solve the problems of high content of refractory substances in wastewater, ignoring the inhibition effect, and long measurement cycle, so as to achieve simple and fast measurement methods and avoid time-consuming The effect of laborious and simple measurement method

Inactive Publication Date: 2007-01-17
HARBIN INST OF TECH
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Problems solved by technology

If BOD is measured by dilution method 5 inhibition
[0012] (2) The concentration of organic matter directly affects the oxygen consumption rate in the biodegradation process. When the substrate concentration is very low, the oxygen consumption rate is proportional to the first power of the organic substrate concentration, but when the raw sewage substrate concentration is high, it will does not follow this rule
The concentration of nitrobenzene in the diluted water sample (based on the concentration of 1000mg / L in raw water) is 0.4mg / L, 0.6mg / L, and 1.2mg / L respectively, which are all lower than the "Comprehensive Wastewater Discharge Standard (GB8978-1996)" one The 2.0mg / L stipulated in the grade standard, it can be considered that the concentration of nitrobenzene in the water sample after high dilution has little effect on the microbial activity, and cannot represent the biochemical characteristics of the original wastewater
[0014] Therefore, for high-concentration industrial wastewater, the high-fold dilution method is used to determine BOD 5 Or use it to judge the biodegradability of sewage, it can only explain the results in the diluted state, and cannot represent the nature of the original sewage, BOD 5 The / COD index ignores the impact of pollutant concentration in wastewater on biodegradability, and the error is large in the process of use. This result shows that the biochemical characteristics of high-concentration sewage water quality are not completely correct
[0015] 2. The measurement cycle is too long:
[0016] BOD 5 It takes five days from the beginning of the measurement to the result. The measurement period is too long. In the face of complex and changeable sewage water quality, the original measurement method cannot guide the engineering practice in time, which brings changes to the operation and management of sewage treatment facilities.
[0017] High content of refractory substances in wastewater, high biological toxicity, and many inhibitory substances may be the cause of poor biochemical properties of wastewater
BOD 5 When the / COD ratio is low, it can be considered that the biodegradability of the wastewater is poor, but it cannot explain the cause of the poor biodegradability

Method used

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  • Biochemical-performance evaluation of industrial waste water
  • Biochemical-performance evaluation of industrial waste water
  • Biochemical-performance evaluation of industrial waste water

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Experimental program
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specific Embodiment approach 1

[0032] Specific embodiment one: this embodiment evaluates the biodegradability of industrial waste water according to the following method:

[0033] (1) Determination method of oxygen consumption rate

[0034] The dissolved oxygen meter was used to measure the oxygen consumption of endogenous respiration and biochemical respiration, and the biochemical respiration line and endogenous respiration line were drawn to qualitatively evaluate the differences in the biochemical properties of different wastewaters. At the same time, the ratio of biochemical oxygen consumption to endogenous respiratory oxygen consumption—the relative oxygen consumption—was used to quantitatively evaluate the biodegradability of wastewater.

[0035] 1. Measuring instrument device

[0036] ①Precise dissolved oxygen meter;

[0037] ② Dissolved oxygen bottle;

[0038] ③Constant temperature water tank;

[0039] ④Oxygenation pump;

[0040] ⑤ pH meter.

[0041] Measuring device see figure 1 , using 85...

specific Embodiment approach 2

[0069] Specific implementation mode two: select papermaking wastewater, pharmaceutical wastewater, and nitro chemical wastewater to measure biodegradability, and the assay method is as follows:

[0070] 1. Determination of oxygen consumption rate of endogenous respiration and biochemical oxygen consumption rate of different wastewater

[0071] According to the measurement method introduced in the specific embodiment one, the endogenous respiration oxygen consumption rate and the biochemical oxygen consumption rate of different wastewater are measured, and the biochemical respiration line of wastewater is drawn, see image 3 .

[0072] 2. Calculate 30min relative oxygen consumption ROC 30

[0073] according to image 3 results, according to Calculation of ROC for different wastewater 30 They are: papermaking wastewater 1.12, pharmaceutical wastewater 0.88, nitro chemical wastewater 0.78. It is preliminarily determined that the biodegradability of these types of wastewate...

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Abstract

A estimation method of the biotransformation of industrial sewage, it relates to a estimation method of the biotransformation of waste water in sewage treatment. To solve the problem that the measurement error because of high-power diluting and the measure period is too long in the present measurement, the invention using the dissolve oxygen detecting instrument detect the endogenous respiration oxygen consumption and the biochemical breath oxygen consumption of industrial sewage, estimating the biotransformation of industrial sewage according to the relative oxygen consumption: when the water sample waiting for measuring ROC> 1, explaining that the base material does not poison or inhibit the action of the microorganism, the bigger the ROC value is the better the biotransformation of waste water waste is; When the water sample waiting for measuring ROC <1, explaining that base material poisons or inhibits the action of the microorganism, the smaller the ROC value is the stronger the toxicity of the waste water is, the worse the biotransformation of waste water waste is. The invention uses a method by detecting the oxygen consumption rate of microorganism, can detect the impact of different waste water thickness to the action of the microorganism, it avoids the error of high power dilution; and the method is simple, rapid, it can gain the measurement result in 30 ~ 60 min.

Description

technical field [0001] The invention relates to a method for evaluating biodegradability of wastewater in sewage treatment. Background technique [0002] At present, my country's wastewater pollution is mainly organic pollution, which determines that the vast majority of wastewater treatment must use biological treatment as the main treatment process. The biological treatment method has certain requirements on the biodegradability of wastewater. If the biodegradability of the wastewater is strong, it means that the wastewater is easy to biodegrade, and the wastewater can be directly treated with biological treatment processes; if the biodegradability of the wastewater is poor, it means that the wastewater is difficult to biodegrade. The biological treatment process is directly adopted, so determining the biodegradability of wastewater is of great significance to the selection of wastewater treatment process. [0003] The commonly used index to measure the biodegradability o...

Claims

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Application Information

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IPC IPC(8): G01N33/18G01N27/00
Inventor 李欣祁佩时
Owner HARBIN INST OF TECH
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