Process for preparing metal oxide nano powder
An oxide and nanopowder technology, applied in titanium oxide/hydroxide, zirconium oxide, titanium dioxide and other directions, can solve the problems of pollution and high cost, and achieve the effect of simple process, low equipment investment and low production cost
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Embodiment 1
[0020] Take 100g of titanium tetrachloride liquid, slowly add 150ml of distilled water for hydrolysis, and add 300ml of distilled water to dilute to about 500ml. Slowly add 25% ammonia water dropwise under vigorous stirring until the pH is 9 to obtain titanium hydroxide gel. Suction filter and wash the titanium hydroxide gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet titanium hydroxide gel and ethanol in a mass ratio of 1:0.5, place it in an autoclave, keep it at 120°C at about 0.3MPa for 8 hours, then cool to room temperature, filter, and dry at 110°C for 6 hours , roasted at 350°C for 4h in a high-temperature furnace to obtain titanium dioxide nanopowder.
[0021] Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, TEM and XRD respectively, and the bulk density of the nano-powder was measured by the stacking method. The specific surface area of th...
Embodiment 2
[0023] Take 80 g of zirconium oxychloride solid, add 300 ml of distilled water to dissolve. Slowly add 20% ammonia water dropwise under vigorous stirring until the pH is 9 to obtain zirconium hydroxide gel. Suction filter and wash the zirconium hydroxide gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet zirconium hydroxide gel and ethanol in a mass ratio of 1:1, place it in an autoclave, and keep it at 120°C at about 0.3Mpa for 8 hours, then cool to room temperature, filter, and dry at 110°C for 6 hours , roasted in a high-temperature furnace at 450°C for 6 hours to obtain zirconia nanopowder.
[0024] Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, TEM and XRD respectively, and the bulk density of the nano-powder was measured by the stacking method. The specific surface area of the resulting zirconia is 213m 2 / g, the particle size is 8.6nm (TEM)...
Embodiment 3
[0026] Take 95g of titanium tetrachloride liquid, slowly add 150ml of distilled water for hydrolysis, and add 300ml of distilled water to dilute to about 500ml. Aluminum trichloride (AlCl 3 ·6H 2 O) 10g, stirred to dissolve it. Slowly add 15% ammonia water dropwise under stirring until the pH is 9 to obtain a titanium hydroxide-aluminum mixed gel. Suction filter and wash the titanium hydroxide-aluminum mixed gel until there is no chloride ion (0.1M AgNO 3 test). Mix the wet titanium hydroxide-aluminum mixed gel with ethanol in a mass ratio of 1:0.8, place it in an autoclave, and keep it at 130°C at about 0.35Mpa for 4 hours, then cool to room temperature, filter, 110 ℃ drying for 6 hours, and calcination in a high-temperature furnace at 500 ℃ for 4 hours to obtain titanium-aluminum composite oxide nanopowder.
[0027]Sample after N 2 The specific surface area, particle size, particle size distribution and crystal shape of the nano-powder were measured by adsorption BET, ...
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