Method for forming plural-layered coated film
A multi-layer coating film and coating film technology, which is applied to the surface coating liquid device, coating, polyurea/polyurethane coating, etc., can solve the problem that the surface smoothness of the multi-layer coating film is not fully improved.
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Embodiment 1
[0122] (A) Preparation of water-based surfacer
[0123] (preparation of pigment dispersion paste)
[0124] 4.5 parts of commercially available dispersant "Disperbyk 190" (nonionic anionic dispersant produced by Byk-Chemie, trade name), 0.5 parts of antifoaming agent "BYK-011" (antifoaming agent produced by Byk-Chemie agent), 22.9 parts of ion-exchanged water and 72.1 parts of rutile titanium dioxide are premixed, and the glass bead medium is added to the paint seasoning tank. The above-mentioned materials in the paint seasoning tank are mixed at room temperature and dispersed to form particles with a particle size of 5 microns or less A pigment dispersion paste was obtained.
[0125] (preparation of acrylic resin emulsion)
[0126] 445 parts of water and 5 parts of Neucol293 (manufactured by Nippon Nyukazai Co., Ltd.) were added to a reaction vessel equipped with a stirrer, thermometer, dropping funnel, reflux condenser to prepare a common acrylic-based resin emulsion and n...
preparation example
[0150] Synthetic Acrylic Emulsion
[0151] An acrylic resin emulsion (resin 2) having 40.6% of nonvolatile matter was polymerized in the same manner as in "Preparation of Resin 1" except that the following monomer mixture was used.
[0152] Methyl methacrylate
Embodiment 2-9 and comparative Embodiment 1-2
[0154] Except for the acrylic resin emulsion and polyurethane resin emulsion shown in Table 5 below, in the same manner as in Example 1, and using Tables 6 to 8, surfacers and multilayer coating films were formed and evaluated. The results are shown in Table 5.
[0155] acrylic
[0156] *The values used as the basis for the calculation are shown in Table 10 and Table 11
[0157] Table 6
[0158] Resin 1
[0159] Table 7
[0160] resin type
[0161] Table 8
[0162] Melamine A
[0163] Table 9
[0164] ○
[0165] Example 1
[0166] Example 6
[0167] According to the method for forming a coating film of the present invention, a multilayer coating film having excellent surface smoothness can be formed while effectively avoiding phase mixing between the surfacer film and the primer film.
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