Melt polycarbonate catalyst system
A polycarbonate, melt polymerization technology, applied in the field of polycarbonate preparation, can solve problems such as performance degradation
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[0011] The invention provides a kind of polycarbonate preparation method, this method comprises under melt polymerization reaction condition in molecular formula A x + MF 6 -x contacting a diaryloxy compound and a dihydric phenol compound in the presence of a compound of , optionally in the presence of a cocatalyst selected from tetraalkylammonium and tetraalkylphosphonium salts,
[0012] where A is an alkali metal or an alkaline earth metal;
[0013] M is a transition metal of group IVA or VA, or M is a p-block metal of IIIB, IVB or VB;
[0014] x is 1, 2 or 3.
[0015] In a preferred embodiment, A is selected from sodium, potassium, cesium, lithium, barium or calcium. In a further preferred embodiment, M is a metal cation selected from silicon, tin, germanium, zirconium, strontium, aluminum, niobium and titanium.
[0016] Particularly preferred catalysts include Na 2 SiF 6 、Na 2 SnF 6 、Cs 2 SiF 6 、Cs 2 SiF 6 、K 2 TiF 6 、Na 2 GeF 6 、Na 2 ZrF 6 、Na 2 SbF ...
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