Preparation method of writable thermo-sensitive paper

A heat-sensitive paper and heat-sensitive technology, applied in special paper, papermaking, paper, etc., can solve the problems of reduced ink absorption ability and roughness, and achieve the effects of smooth paper feeding, high image definition, and good coloring ability

Active Publication Date: 2022-07-29
广东简彩纸业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] With the rapid development of social economy and science and technology, thermal paper has increasingly shown a wide range of uses and an important market position due to its excellent performance. It is necessary to continuously develop new varieties to meet the needs of different application fields and expand the thermal paper. consumption, and because the thermal paper is coated with a thermal coating, and in order to improve printing clarity and facilitate paper feeding, the surface smoothness of thermal paper is generally relatively high, which will inevitably make the capillary formed by the fiber gap on the paper surface The number and diameter of the thermal paper are reduced, the roughness is reduced, and the ink absorption ability is reduced. Therefore, the ink trace written on the thermal paper can be easily wiped off. Generally, thermal paper is not suitable for writing, and it is difficult to meet the needs of different application fields.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A preparation method of writable thermal paper, specifically by sequentially coating a pre-coating coating and a thermal coating on a base paper, wherein the base paper is thermal base paper, double-adhesive paper, writing paper, coated paper or white card Paper, the basis weight of paper is 100-200g / m 2 , the smoothness is greater than 30s, and the surface water absorption Cobb is less than 60g / m at 60s 2 ;in,

[0034] In parts by mass, the heat-sensitive coating comprises the following components:

[0035] 10 parts of heat-sensitive dye; 18 parts of heat-sensitive color developer; 9 parts of sensitizer; 28 parts of nano-silica; 12 parts of calcined kaolin; 7 parts of lubricant; 8 parts of polyvinyl alcohol; 0.5 part of dispersant; defoaming agent agent 0.5 powder; 1 part of wetting and leveling agent; coating weight 7g / m 2 ;

[0036] The dye is 2-(2-4-dimethylamino)-3-methyl-6-diethylaminofluoran;

[0037] The color developer is 2,4-dihydroxydiphenylsulfone or 4,...

Embodiment 2

[0048] A preparation method of writable thermal paper, specifically by sequentially coating a pre-coating coating and a thermal coating on a base paper, wherein the base paper is thermal base paper, double-adhesive paper, writing paper, coated paper or white card Paper, the basis weight of paper is 100-200g / m 2 , the smoothness is greater than 30s, and the surface water absorption Cobb is less than 60g / m at 60s 2 ;in,

[0049] In parts by mass, the heat-sensitive coating comprises the following components:

[0050] 10 parts of heat-sensitive dye; 18 parts of heat-sensitive color developer; 9 parts of sensitizer; 28 parts of nano-silica; 12 parts of calcined kaolin; 7 parts of lubricant; 8 parts of polyvinyl alcohol; 0.5 part of dispersant; defoaming agent agent 0.5 powder; 1 part of wetting and leveling agent; coating weight 7g / m 2 ;

[0051] The dye is 2-(2-4-dimethylamino)-3-methyl-6-diethylaminofluoran;

[0052] The color developer is 2,4-dihydroxydiphenylsulfone or 4,...

Embodiment 3

[0065] A preparation method of a writeable thermal paper, the same as in Example 2, the difference is that the preparation method of the nano-silica further comprises the following steps:

[0066] (3) Disperse the dried product obtained in step (2) in anhydrous toluene, add mercaptopropyltrimethoxysilane, heat up and reflux for 1-2h, separate the precipitate and wash with absolute ethanol, and dry to obtain The sulfhydrylation intermediate is prepared by adding the sulfhydrylation intermediate to methanol, adding hydrogen peroxide and concentrated sulfuric acid, stirring and reacting at room temperature for 2 hours, separating the precipitate, washing with absolute ethanol, and drying;

[0067] Wherein, the mass ratio of the dried product to the anhydrous toluene and mercaptopropyltrimethoxysilane is 1:0.3:8.7; the mass ratio of the thiolated intermediate to the methanol, hydrogen peroxide and concentrated sulfuric acid is 1 :7.9:32:0.48.

[0068] The PPS roughness tester was...

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Abstract

The invention discloses a preparation method of writable thermo-sensitive paper, and belongs to the technical field of preparation of special thermo-sensitive papers, the thermo-sensitive paper is prepared by sequentially coating a pre-coating layer and a thermo-sensitive coating layer on raw paper, and the thermo-sensitive coating layer comprises the following components in parts by mass: 8-11 parts of thermo-sensitive dye; 16 to 20 parts of a thermosensitive color developing agent; 8-13 parts of a sensitizer; 30 to 45 parts of filler; 6-10 parts of a lubricant; 6 to 10 parts of polyvinyl alcohol; 0.4 to 0.8 part of a dispersing agent; 0.4 to 0.8 powder of a defoaming agent; 0.8 to 1.3 parts of a wetting leveling agent; the filler comprises nano silicon dioxide; according to the invention, the functional ink absorption material is added into the thermosensitive coating, so that the writing function on the thermosensitive paper is successfully realized, the ink can be absorbed and dried by the writable thermosensitive paper within 2 seconds after writing, and the application field of the thermosensitive paper is expanded.

Description

technical field [0001] The invention relates to the technical field of preparation of special thermal paper, in particular to a preparation method of writable thermal paper. Background technique [0002] Thermal paper, also known as thermal fax paper, thermal recording paper, thermal copy paper, is a special kind of coated processed paper. "Coating", under the condition of heat, the heat-sensitive coating powder mixes to develop a color reaction to complete the printing. It has been widely used in the fields of communication, medical treatment, logistics, and supermarkets. [0003] For writing paper, it is generally required that the paper absorbs the ink quickly. After writing, the ink is mainly absorbed by the capillary action of the paper fiber. The low molecular weight binder and solvent pass through the small pores and the rough surface of the paper fiber at a relatively slow speed. Entering the inside of the paper, with the extension of time, the solvent content in th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H27/00D21H19/40D21H19/44D21H21/28D21H21/52D21H21/14D21H19/60D21H19/82D21H19/58D21H19/46D21H19/62B41M5/41B41M5/44C01B33/18B82Y30/00B82Y40/00
CPCD21H27/00D21H19/40D21H19/44D21H21/28D21H21/52D21H21/14D21H19/60D21H19/822D21H19/58D21H19/46D21H19/62B41M5/41B41M5/44C01B33/18B82Y30/00B82Y40/00
Inventor 叶旭峰林土珍叶建明
Owner 广东简彩纸业科技有限公司
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