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Composite efficient phosphorus removal agent as well as preparation method and application thereof

A phosphorus removal agent and efficient technology, applied in chemical instruments and methods, sustainable biological treatment, water/sludge/sewage treatment, etc., can solve problems such as greater impact on biochemical systems, affecting water chroma, and low phosphorus removal efficiency , to achieve the effects of simple dosing system, easy precipitation and removal, and high phosphorus removal efficiency

Pending Publication Date: 2022-07-12
深圳泓沛环境科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) Complicated use: the phosphorus removal agent in the prior art cannot be directly added to the aerobic pool of the biochemical system, it needs to be diluted, and it needs to be dispensed on site, which is not convenient enough to use
[0006] (2) Low phosphorus removal efficiency: in the prior art, the phosphorus removal efficiency of using iron salt or aluminum salt alone is low
[0007] (3) Synchronous phosphorus removal has a greater impact on the biochemical system: chemical phosphorus removal agents in the prior art include polyferric sulfate, polyaluminum chloride, and polyaluminum ferric chloride. These agents are mainly used for post-position phosphorus removal. It is seldom used for simultaneous phosphorus removal. Therefore, a large amount of aluminum salt will deflocculate the sludge, affect the microbial activity, and have a great impact on the biochemical system. The reaction of inorganic salts and adsorbents with phosphorus is not complete, and there are many residual chemicals, which will affect the sewage treatment system. Degradation of COD and ammonia nitrogen
[0008] (4) The sewage does not meet the standard, which affects the chroma of the water and is highly corrosive to the equipment: although the ferric salt has a good phosphorus removal effect, it will reduce the pH of the sewage and increase the chroma of the sewage, which may make other indicators of the sewage unsatisfactory. Up to standard, and highly corrosive to equipment
[0009] (5) The effect of flocculation and sedimentation is poor: the effect of SS adsorption and capture of small particles in water is poor, and the sedimentation speed is slow

Method used

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  • Composite efficient phosphorus removal agent as well as preparation method and application thereof
  • Composite efficient phosphorus removal agent as well as preparation method and application thereof

Examples

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Effect test

Embodiment 1

[0032] A composite high-efficiency phosphorus removal agent provided by the embodiment of the present invention comprises the following components and the mass ratio of the components is: 85-93 parts of inorganic salt solution, 0.5-1 part of adsorbent, 6-14 parts of coagulation aid and scrap iron Chips 0.05 to 0.1 part. Wherein: the inorganic salt solution is composed of at least any three and sodium carbonate in ferric sulfate, ferrous sulfate, ferrous chloride, aluminum sulfate, calcium chloride, magnesium sulfate, and wherein the mol ratio of iron and aluminum is controlled at 3: 1 to 5:1. The adsorbent is composed of any one or more of bentonite, diatomite and montmorillonite. The coagulation aid is composed of any one or both of polydimethyldiallyl ammonium chloride and polyepichlorohydrin amine and cetyltrimethylammonium chloride. Scrap iron filings are added to the composite high-efficiency phosphorus removal agent.

[0033] The method for preparing a composite high-...

Embodiment 2

[0041] A composite high-efficiency phosphorus removal agent comprises the following components and their mass ratios are: 87 parts of an inorganic salt solution, 0.8 part of an adsorbent, 12.15 parts of a coagulant aid and 0.05 part of scrap iron filings.

[0042] Wherein: the mass ratio of inorganic salt solution is, 5 parts of iron sulfate, 25 parts of ferrous sulfate, 10 parts of aluminum sulfate, 1 part of calcium chloride, 0.5 part of sodium carbonate, 58.5 parts of water are obtained, wherein the mole of iron and aluminum is obtained. The ratio is controlled at 3 to 5:1;

[0043] The mass ratio of the adsorbent is 1 part of bentonite and 1 part of diatomite;

[0044] The mass ratio of the coagulant aid is: 0.5 part of cetyltrimethyl ammonium chloride, 15 parts of polydimethyldiallyl ammonium chloride, and 84.5 parts of water.

[0045] A preparation method of a composite high-efficiency phosphorus removal agent is as follows:

[0046] Step 1, preparation of inorganic sa...

Embodiment 3

[0053] A composite high-efficiency phosphorus removal agent, comprising the following components and the mass ratio of the components: 90 parts of inorganic salt solution, 0.6 part of adsorbent, 9.35 parts of coagulation aid and 0.05 part of scrap iron filings.

[0054] Wherein: the mass ratio of the inorganic salt solution is 5 parts of ferric sulfate, 20 parts of ferrous sulfate, 7 parts of ferrous chloride, 10 parts of aluminum sulfate, 1 part of calcium chloride, 0.5 parts of sodium carbonate, and 56.5 parts of water, wherein The molar ratio of iron to aluminum is controlled at 3 to 5:1;

[0055] The mass ratio of the adsorbent is 1 part of diatomaceous earth; the mass ratio of the coagulant is: 0.5 part of cetyltrimethyl ammonium chloride, 10 part of polydimethyldiallyl ammonium chloride parts, 5 parts of polyepichlorohydrin, and 84.5 parts of water.

[0056] A preparation method of a composite high-efficiency phosphorus removal agent is as follows:

[0057] Step 1, the...

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PUM

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Abstract

The invention belongs to the field, and discloses a composite efficient phosphorus removal agent, a preparation method and application, and the composite efficient phosphorus removal agent comprises the following components in parts by mass: 85-93 parts of an inorganic salt solution, 0.5-1 part of an adsorbent, 6-14 parts of a coagulant aid and 0.05-0.1 part of scrap iron. The efficient phosphorus removal agent prepared by the invention has the advantages of simplicity in use, high phosphorus removal efficiency, synchronous and post phosphorus removal, small influence on a biochemical system, no influence on the chromaticity of sewage, good flocculating settling effect and the like, and is widely applied to the field of sewage treatment.

Description

technical field [0001] The invention belongs to the field of sewage purification and treatment in the technical field of environmental protection, and in particular relates to a composite high-efficiency phosphorus removal agent, a preparation method and an application. Background technique [0002] Excessive phosphorus in water bodies can cause eutrophication of water bodies, endangering ecosystems and human health. In order to control water pollution, the vast majority of municipal sewage plants in my country currently implement the first-class A discharge standard of the Pollutant Discharge Standard for Urban Sewage Treatment Plants (GB 18918-2002), which requires that the total phosphorus in the effluent does not exceed 0.5mg / L. [0003] For phosphorus removal in sewage plants, biological phosphorus removal and chemical phosphorus removal are currently the most widely used methods of phosphorus removal. Biological phosphorus removal is affected by sewage inflow conditio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/00C02F1/28C02F1/52C02F1/54C02F1/56C02F101/10
CPCC02F1/00C02F1/281C02F1/56C02F1/54C02F1/5236C02F2101/105Y02W10/10
Inventor 李春艳邓斌
Owner 深圳泓沛环境科技有限公司
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