Method for concentrating mineral solid waste low-concentration occurrence rare and precious elements and co-producing high-grade aluminum-silicon raw materials

A high-grade, elemental technology, applied in the preparation/processing of silicon oxide, rare earth metal oxides/hydroxides, rare earth metal compounds, etc., can solve the problems of high-value utilization of silicon and aluminum, extraction interference, etc. Effectiveness of resource utilization and low-carbon eco-efficiency, avoiding acid leaching process, improving process energy efficiency and economy

Active Publication Date: 2022-04-12
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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  • Summary
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Usually, rare and precious elements associated with mineral solid waste are deeply embedded in the common crystal phase structure of solid waste such as silicon and aluminum, which interferes with its extraction and poses a challenge to the economics of the extraction process of rare and precious elements that already exist in low concentrations. Promote the transfer and release of heavy metals that are harmful to health and the environment in solid waste, and the high-value utilization of a large proportion of silicon and aluminum is also a long-term problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A method for concentrating rare and precious elements in low-concentration mineral solid waste and co-producing high-grade aluminum-silicon raw materials, comprising the following steps:

[0026] (1) At a temperature of 800°C and a pressure of 0.1 MPa, dissolve fly ash containing a total concentration of rare earths of 131 μg / g in sodium carbonate solution to activate the silicon-aluminum crystal phase in fly ash, fly ash and sodium carbonate The mass ratio is 1:1 to obtain a mixed solution containing sodium silicon aluminum salt;

[0027] (2) At normal temperature and under the condition of a pressure of 0.1MPa, add ammonium chloride to the mixed solution obtained in step (1), the mass ratio of ammonium chloride to the mixed solution is 0.01:1, and obtain a compound containing strong alkali silicon oxide, strong alkali Liquid phase products of carbonates and weak bases and strong salts, solid phase products and gas phase products of ammonia adsorbed on the surface of r...

Embodiment 2

[0031] Same as Example 1, the difference is: in step (1), the mass ratio of fly ash and sodium carbonate is 3:1, and the reaction conditions are temperature 900 ° C, pressure 0.1MPa; in step (2), ammonium chloride and The mass ratio of the mixed solution is 0.1:1, and the reaction conditions are a temperature of 25° C. and a pressure of 0.1 MPa.

[0032] The total extraction efficiency of rare earth is 78.7%, and the yield of silicon oxide is 41.9%.

Embodiment 3

[0034] Same as Example 1, except that the reaction conditions in step (2) are a temperature of 25° C. and a pressure of 8 MPa.

[0035] The total extraction efficiency of rare earth is 82.9%, and the yield of silicon oxide is 43.2%.

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Abstract

The invention discloses a method for concentrating mineral solid waste low-concentration occurrence rare and precious elements and co-producing high-grade aluminum-silicon raw materials. The invention relates to a method for concentrating low-concentration occurrence rare and precious elements in mineral solid waste and co-producing high-grade aluminum-silicon raw materials. The method comprises the following steps: deconstruction and activation of silicon and aluminum, hydrolysis matching of acid and alkaline salt, leaching of the rare and precious elements, co-production of the high-grade aluminum-silicon raw materials, carbon dioxide fixation and concentration of the rare and precious elements. According to the method, technical routes such as silicon-aluminum deconstruction, acid-alkali salt hydrolysis matching, precise rare and precious element release, high-grade aluminum-silicon raw material co-production and carbon dioxide cyclic fixation of the mining and metallurgy solid waste are specifically constructed, an acid leaching process is avoided, and the energy efficiency and economical efficiency of the process are improved; the method can promote the output of high-value and high-grade secondary mineral products of mining and metallurgy solid wastes, improve the resource utilization rate and the low-carbon ecological efficiency, provide a solution for environmental pollution and ecological damage of stockpiling solid wastes and tailings, and improve the technical research and development, integration, transformation and radiation transfer capabilities.

Description

technical field [0001] The invention relates to the technical field of environmental protection and ecology, in particular to a method for enriching rare and precious elements in low-concentration mineral solid waste and co-producing high-grade aluminum-silicon raw materials. Background technique [0002] The prominent problems in the mineral and metallurgical industry are high energy consumption, high carbon emissions, and high solid waste output. Among them, the output solid waste has many types, complex components, occupies a large amount of land, causes visual and environmental pollution, and is often simply used as a building and road construction auxiliary material with a large absorption capacity, with low economic value and utilization rate. The symbiosis and associated nature of minerals is the main reason for the complex composition of solid waste, among which there are many scattered rare and precious elements or key elements of technology that are of great signif...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/113C01F17/206C01F17/10
CPCY02P10/20
Inventor 曹晏
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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