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Heat stabilizer for processing soft transparent PVC (polyvinyl chloride) and preparation method of heat stabilizer

A heat stabilizer, soft and transparent technology, which is applied in the field of heat stabilizer for processing soft and transparent PVC and its preparation, can solve the problems of coloring and long-term heat stability cannot be taken into account, and achieves the reduction of initial coloring and zinc burning. Effect

Pending Publication Date: 2022-03-25
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the problems existing in the prior art, the object of the present invention is to provide a heat stabilizer for processing soft transparent PVC and a preparation method thereof, which solves the problem that the existing heat stabilizer technology is used for the initial coloring and long-term thermal stability of PVC processing. Technical issues that cannot be balanced with stability

Method used

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  • Heat stabilizer for processing soft transparent PVC (polyvinyl chloride) and preparation method of heat stabilizer
  • Heat stabilizer for processing soft transparent PVC (polyvinyl chloride) and preparation method of heat stabilizer
  • Heat stabilizer for processing soft transparent PVC (polyvinyl chloride) and preparation method of heat stabilizer

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preparation example Construction

[0036] The preparation method provided by the invention is used to process the thermal stabilizer of soft transparent PVC, comprises the following steps:

[0037] Step 1, mixing zinc oleate, amino metal organic framework compound, auxiliary heat stabilizer, lubricant, antioxidant and ultraviolet absorber to obtain the first mixture, heating the first mixture, wherein the heating temperature is 60-90 ℃;

[0038] Step 2, adding a plasticizer to the heated first mixture to obtain a second mixture, heating, stirring, and granulating the second mixture in sequence to obtain a heat stabilizer for processing soft transparent PVC, wherein the heated The temperature is 100-120°C, and the granulation is obtained by a granulator.

Embodiment 1

[0040] A heat stabilizer for processing soft transparent PVC, which consists of the following components in mass ratio: 30 parts of zinc oleate, 15 parts of amino metal organic framework compound, 10 parts of uracil, 5 parts of β-diketone, 10 parts of diisononyl cyclohexane 1,2-dicarboxylate, 4 parts of polyethylene wax (AC-6A), 1 part of antioxidant 618, and 1 part of UV531, wherein the amino metal organic framework compound contains a mass ratio of 1:1 organic ligand and metal salt, wherein the organic ligand is aminoterephthalic acid, aminonaphthalene dicarboxylic acid or 2-aminoimidazole;

[0041] 30 parts of zinc oleate, 15 parts of amino metal organic framework compound, 10 parts of uracil, 5 parts of β-diketone, 10 parts of diisononyl cyclohexane 1,2-dicarboxylate, polyethylene wax (AC- 6A) Mix 4 parts, 6181 parts of antioxidant and 1 part of UV531 to obtain the first mixture, heat the first mixture to 60°C, then add plasticizer to the heated first mixture to obtain the...

Embodiment 2

[0043]A heat stabilizer for processing soft transparent PVC, which consists of the following components in mass ratio: 25 parts of zinc oleate, 18 parts of amino metal organic framework compound, 10 parts of uracil, 5 parts of pentaerythritol, epoxy resin 10 parts of soybean oil, 6 parts of polyethylene wax (AC-6A), 1 part of antioxidant 1010, 1 part of UV326, wherein the amino metal organic framework compound contains an organic ligand and a metal salt with a mass ratio of 1:1, wherein, The organic ligand is aminoterephthalic acid, aminonaphthalene dicarboxylic acid or 2-aminoimidazole;

[0044] 30 parts of zinc oleate, 15 parts of amino metal organic framework compound, 10 parts of uracil, 5 parts of β-diketone, 10 parts of diisononyl cyclohexane 1,2-dicarboxylate, polyethylene wax (AC- 6A) Mix 4 parts, 6181 parts of antioxidant and 1 part of UV531 to obtain the first mixture, heat the first mixture to 90°C, then add plasticizer to the heated first mixture to obtain the seco...

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Abstract

The invention belongs to the technical field of PVC (polyvinyl chloride) heat stabilizers, particularly relates to a heat stabilizer for processing soft transparent PVC and a preparation method of the heat stabilizer, and can solve the technical problem that the existing heat stabilizer technology cannot give consideration to both initial coloring and long-term heat stability in PVC processing. The heat stabilizer for processing the soft transparent PVC is characterized by comprising the following raw materials: zinc oleate, an amino metal organic framework compound, an auxiliary heat stabilizer, a plasticizer, a lubricant, an antioxidant and an ultraviolet light absorber. Zinc oleate and an amino metal organic framework compound are used as main stabilizers, necessary auxiliary stabilizers are matched, and compared with traditional zinc stearate, the transparent PVC material has excellent transparency and initial coloring and is suitable for transparent PVC products.

Description

technical field [0001] The invention belongs to the technical field of PVC heat stabilizers, and in particular relates to a heat stabilizer for processing soft transparent PVC and a preparation method thereof. Background technique [0002] Common products of transparent PVC include plates, pipes, sheets and films. The hardness can be adjusted to meet the performance requirements of transparent cables, soft toys, stationery, food packaging films, artificial leather products, etc., and develop high transparency and low temperature. Soft PVC products are research hotspots in this field. When processing transparent PVC, heat stabilizers, plasticizers and lubricants should be added, among which heat stabilizers play a vital role in the initial coloring and long-term thermal stability of PVC products. [0003] The plasticizing and decomposition temperatures of PVC resin are very close, and its processing temperature is usually higher than 140°C, and it will decompose at about 100...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L87/00C08L91/00C08K5/098C08K5/3462C08K5/12
CPCC08L27/06C08L2201/08C08L87/00C08K5/098C08K5/3462C08K5/12C08L91/00
Inventor 宋莉芳霍慧文夏慧芸张文硕牛艳辉
Owner CHANGAN UNIV
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