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A kind of environment-friendly process method of producing motor gasoline from naphtha

A process method, the technology of gasoline for vehicles, which is applied in the field of coal chemical industry, can solve the problems of complex process and high energy consumption, and achieve the effects of good thermal stability, high yield and low sulfur content

Active Publication Date: 2022-04-15
弘润石化(潍坊)有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] When the above technology is used to increase the octane number of naphtha, the naphtha raw material often needs to be pretreated, and the fractions are divided into different fractions for separate treatment. Moreover, the prior art mostly uses precious metal catalysts to hydrogenate light distillates. Structural treatment, hydrocracking or catalytic reforming treatment of heavy distillate, has the disadvantages of complicated process and high energy consumption

Method used

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  • A kind of environment-friendly process method of producing motor gasoline from naphtha
  • A kind of environment-friendly process method of producing motor gasoline from naphtha
  • A kind of environment-friendly process method of producing motor gasoline from naphtha

Examples

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Effect test

preparation example 1

[0035] Preparation Example 1 WO 3 / ZrO 2 / Al 2 o 3 Preparation of Mg-doped Pt / Ni Bimetallic Catalyst Supported by Solid Strong Acid

[0036] Add 10g of ammonium metatungstate solution dropwise to 100mL mixed solution of 4g zirconium oxychloride and 2g aluminum isopropoxide under stirring, adjust the pH value of the solution to 9, heat to 80°C for 0.5h, then centrifuge at 3000r / min 10min, the solid precipitate was washed with deionized water, filtered, dried at 80°C for 2h, and calcined at 300°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier; dissolved in 0.6gH 2 PtCl 6 and 0.4g NiCl 2 Add 0.02g MgCl to 20mL aqueous solution 2 , after mixing well, add 5g WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier, 1000W ultrasonic dispersion for 0.5h, heated to 80°C for 1h, concentrated under reduced pressure to half of the original volume, filtered, and dried at 80°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid supported Mg-doped Pt / Ni bimet...

preparation example 2

[0037] Preparation Example 2 WO 3 / ZrO 2 / Al 2 o 3 Preparation of Mg-doped Pt / Ni Bimetallic Catalyst Supported by Solid Strong Acid

[0038] Add 10g of ammonium metatungstate solution dropwise to 100mL mixed solution of 7g of zirconium oxychloride and 3g of aluminum isopropoxide under stirring, adjust the pH value of the solution to 10, heat to 90°C for 1h, then centrifuge at 3000r / min for 10min , the solid precipitate was washed with deionized water, filtered, dried at 80°C for 2h, and calcined at 450°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier; dissolved in 1.4gH 2 PtCl 6 and 0.6g NiCl 2 Add 0.1g MgCl to 20mL aqueous solution 2 , after mixing well, add 5g WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier, 1000W ultrasonic dispersion for 1h, heated to 90°C for 2h, concentrated under reduced pressure to half of the original volume, filtered, and dried at 80°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid supported Mg-doped Pt / N...

preparation example 3

[0039] Preparation Example 3 WO 3 / ZrO 2 / Al 2 o 3 Preparation of Mg-doped Pt / Ni Bimetallic Catalyst Supported by Solid Strong Acid

[0040] Add 10g ammonium metatungstate solution dropwise to 100mL mixed solution of 5g zirconium oxychloride and 2.5g aluminum isopropoxide under stirring, adjust the pH value of the solution to 9.5, heat to 85°C for 1 hour, centrifuge at 3000r / min 10min, the solid precipitate was washed with deionized water, filtered, dried at 80°C for 2h, and calcined at 400°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier; dissolved in 0.8gH 2 PtCl 6 and 0.5g NiCl 2 Add 0.06g MgCl to 20mL aqueous solution 2, after mixing well, add 5g WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid carrier, 1000W ultrasonic dispersion for 1h, heated to 85°C for 1.5h, concentrated under reduced pressure to half of the original volume, filtered, and dried at 80°C for 2h to obtain WO 3 / ZrO 2 / Al 2 o 3 Solid strong acid supported Mg-doped Pt / Ni bimetall...

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Abstract

The invention provides an environment-friendly process for producing motor gasoline from naphtha, which belongs to the technical field of coal chemical industry. C 4‑ Component, C 5 / C 6 components and C 7+ component, where C 5 / C 6 Components undergo hydroisomerization reaction to obtain isoparaffin oil, C 7+ The components are reformed to obtain aromatic oil, and the C 4‑ After components, isoparaffin oil and aromatic oil are mixed evenly, motor gasoline is obtained. The present invention is an environmentally friendly process for producing ultra-low-sulfur, olefin-free, high-octane clean motor gasoline, which has the advantages of simple method, mild reaction conditions, low cost, and can significantly increase the octane value of motor gasoline, and has wide applications. prospect.

Description

technical field [0001] The invention relates to the technical field of coal chemical industry, in particular to an environmentally friendly process for producing motor gasoline from naphtha. Background technique [0002] Clean fuel production has always been one of the main tasks of refiners. However, with the shortage of oil resources and rising crude oil prices, how to use limited resources to maximize the production of products required by the market is a challenge for oil refiners. The main components in the gasoline pool are catalytically cracked gasoline, catalytically reformed gasoline, alkylated gasoline and C 5 / C 6 Isomerized gasoline. Except for catalytic cracking gasoline, which is obtained from heavier raw materials, the others are obtained by converting naphtha or light hydrocarbons. [0003] Coal-to-naphtha is divided into direct coal liquefaction naphtha and coal indirect liquefaction naphtha. Since a large number of mono- and di-olefins are produced dur...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G65/00C10L1/06B01J23/30B01J37/03B01J37/02B01J23/89B01J32/00B01J21/16B01J21/04B01J35/10
CPCC10G65/00C10L1/06B01J23/30B01J37/03B01J37/036B01J37/0201B01J23/8993B01J23/8966B01J21/16B01J21/04B01J23/002C10G2300/202C10G2400/30B01J2523/00B01J35/394B01J35/61B01J35/64B01J2523/31B01J2523/48B01J2523/69
Inventor 赵成阳刘建正姜鹏升李桂平房师峡赵垒刘国治陈辉
Owner 弘润石化(潍坊)有限责任公司
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